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  • 1
    Publication Date: 2010-01-01
    Description: A regional climate model is used to evaluate dry deposition of ozone over the North East Atlantic. Results are presented for a deposition scheme accounting for turbulent and chemical enhancement of oceanic ozone deposition and a second non-chemical, parameterised gaseous dry deposition scheme. The first deposition scheme was constrained to account for sea-surface ozone-iodide reactions and the sensitivity of modelled ozone concentrations to oceanic iodide concentration was investigated. Simulations were also performed using nominal reaction rate derived fromin-situozone deposition measurements and using a preliminary representation of organic chemistry. Results show insensitivity of ambient ozone concentrations modelled by the chemical-enhanced scheme to oceanic iodide concentrations, and iodide reactions alone cannot account for observed deposition velocities. Consequently, we suggest a missing chemical sink due to reactions of ozone with organic matter at the air-sea interface. Ozone loss rates are estimated to be in the range of 0.5–6 ppb per day. A potentially significant ozone-driven flux of iodine to the atmosphere is estimated to be in the range of 2.5–500 M moleccm−2  s−1, leading to a mixing-layer enhancement of organo-iodine concentrations of 0.1–22.0 ppt, with an average increase in the N.E. Atlantic of around 4 ppt per day.
    Print ISSN: 1687-9309
    Electronic ISSN: 1687-9317
    Topics: Geosciences , Physics
    Published by Hindawi
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  • 2
    Publication Date: 2011-01-01
    Description: Aerosol light scattering measurements were carried out using a TSI 3563 Nephelometer at the Mace Head Atmospheric Research Station, on the west coast of Ireland from year 2001–2010. A strong seasonal trend in the aerosol light scattering coefficient at 550 nm (), for clean marine air masses, is observed with a high value, [average (geometric mean)] of 35.3 Mm−1(29.5 Mm−1), in January and a low value of 13.7 Mm−1(10.2 Mm−1), in July. This near threefold increase in the value during the winter season is because of the large contribution of wind-speed generated sea-salt particles in the marine boundary layer. A high positive correlation coefficient of 0.82 was found between the percentage occurrence of relatively large Ångström exponent (Å) values (〉1.2) and the percentage occurrence of lower values (5–15 Mm−1) in the summer season. and wind-speed have a high positive correlation coefficient of 0.88 whereas Å and wind-speed have a negative correlation coefficient of −0.89. Å values during the summer months indicate the dominance of sub-m particles thus indicating the contribution of non-sea-salt sulphate and organics towards the as these species show an enhanced concentration during the summer months.
    Print ISSN: 1687-9309
    Electronic ISSN: 1687-9317
    Topics: Geosciences , Physics
    Published by Hindawi
    Location Call Number Expected Availability
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