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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Fex–Cu100−x alloys (40≤x≤90) prepared by ball milling nominally pure (99%) Fe and Cu powders and warm compacted (at ∼300 °C) were investigated by differential scanning calorimetry, scanning electron microscopy, x-ray diffraction, and magnetic susceptibility measurements. Both fcc and bcc diffraction peaks (indicative of pure Fe and Cu) showed that the mixtures were still two phase even after milling for 400 h, and that they were comprised of 6–10 nm diameter grains. Surprisingly, however, calorimetric measurements indicate the presence of a large endothermic peak for these nanocrystalline composites on heating near 600 °C and an exothermic peak near 400 °C on cooling. Magnetic measurements show that these materials are ferromagnetic at room temperature and remain so (with decreasing saturation magnetization) up to near the Curie point of α-Fe, 770 °C. However, near 600 °C on heating (and also near 400 °C on cooling), the magnetic susceptibility indicates the existence of a magnetic phase change. High-temperature x-ray diffraction data show these effects are due to the oxidation of Fe to form magnetite which subsequently decomposes into wustite. The thermal hysteresis observed in the magnetic and thermal data is due to the sluggishness of the latter transformation. Furthermore, heating to temperatures in excess of 600 °C results in the dissolution of Cu into the iron oxides which does not reprecipitate on cooling. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2012-01-01
    Description: The minimum speed for just-suspension,Njs, of porous palm shell-activated carbon (PSAC) particles has been determined in a 15 cm diameter cylindrical tank using a 6-curved blade (6CB) impeller, compared to a 6-blade downpumping mixed-flow (6MFD) impeller and a Rushton turbine (6DT). The particles size ranged from 0.75–1.00 mm, 1.00–1.40 mm, and 1.40–2.36 mm with concentrations between 0 and 5% by weight. The 6CB being a radial impeller performed similarly to 6DT in terms of speed and power requirement at just-suspension, and particles distribution on the base. The 6MFD, with power requirement 100% to 200% less than the radial impellers, was the most efficient for suspending the particles, as usually reported for the range of solid concentrations used here. Specific power per unit mass for all three impellers showed reduction towards minima as the concentration of particles increased. The geometric factor,S, values agreed reasonably with published data, when the particle density was adjusted taking into account water filling the pores of the submerged activated carbon. This result means that Zwietering’s equation can be used to predict suspension for porous particles with adjustment to the particle density.Svalues for curved-blade impellers are presented for the first time.
    Print ISSN: 1687-806X
    Electronic ISSN: 1687-8078
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Hindawi
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