ALBERT

Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Paleoceanography and Paleoclimatology 33 (2018): 1013-1034, doi:10.1029/2018PA003408.

Description: The chemical composition of benthic foraminifera from marine sediment cores provides information on how glacial subsurface water properties differed from modern, but separating the influence of changes in the origin and end‐member properties of subsurface water from changes in flows and mixing is challenging. Spatial gaps in coverage of glacial data add to the uncertainty. Here we present new data from cores collected from the Demerara Rise in the western tropical North Atlantic, including cores from the modern tropical phosphate maximum at Antarctic Intermediate Water (AAIW) depths. The results suggest lower phosphate concentration and higher carbonate saturation state within the phosphate maximum than modern despite similar carbon isotope values, consistent with less accumulation of respired nutrients and carbon, and reduced air‐sea gas exchange in source waters to the region. An inversion of new and published glacial data confirms these inferences and further suggests that lower preformed nutrients in AAIW, and partial replacement of this still relatively high‐nutrient AAIW with nutrient‐depleted, carbonate‐rich waters sourced from the region of the modern‐day northern subtropics, also contributed to the observed changes. The results suggest that glacial preformed and remineralized phosphate were lower throughout the upper Atlantic, but deep phosphate concentration was higher. The inversion, which relies on the fidelity of the paleoceanographic data, suggests that the partial replacement of North Atlantic sourced deep water by Southern Ocean Water was largely responsible for the apparent deep North Atlantic phosphate increase, rather than greater remineralization.

Description: National Science Foundation (NSF) Grant Numbers: OCE‐0750880, OCE‐1335191, OCE‐1558341, OCE‐1536380; Woods Hole Oceanographic Institution (WHOI) Grant Numbers: 27007592, 27000808

Description: During the past decades Mg/Ca ratios have been increasingly used in order to calculate past temperature variations independent from faunal assemblages. Especially in the Fram Strait, the main pathway of heat flux to the Arctic, new temperature estimation tools are urgently needed to better understand past complex interaction of different water masses and the extent of Atlantic Water advection to the Arctic Ocean. The Holocene section of a sediment core from the western Svalbard margin has been studied at high-resolution for benthic proxy indicators to reconstruct deepwater sources and mixing in the Arctic Gateway since the last ca 10,000 years. Benthic stable isotope values and sortable silt mean grain size data are compared to a first, preliminary data set of Mg/Ca paleotemperatures established from the benthic foraminifer species Cibicidoides wuellerstorfi in the eastern Fram Strait. When compared to planktic proxy indicators, this reconstruction of past bottom water temperatures at a northernmost site allows to estimate the linkage between deepwater inflow and AW advection within the West Spitsbergen Current. Furthermore, benthic Mg/Ca temperatures can help unravelling the local impact (e.g., by brine-enriched waters) from general trends in bottom water circulation. Short-lived decreases in benthic carbon isotope values seem to correlate to cold surface water events in the area such as the 8.2 ka event. Similarly, decreases in benthic carbon isotope values in the Nordic Seas around 8 ka have been assigned to decreased bottom water ventilation possibly due to an entrainment of relatively fresh water into the thermohaline system (Bauch et al., 2001). While sluggish bottom current speeds have been found for the 8.2 ka event north of our site on the Yermak Plateau (Hass, 2002), during colder events on the Western Svalbard margin sediment data seem to anticorrelate to benthic carbon isotope data either suggesting a rather unexpected increase in bottom current velocity or an impact of brine-enriched winter waters from the fjord/trough system which might have generated increased lateral coarser-grained sediment injections (Sarnthein et al., 2003). A Late Holocene trend towards significantly higher benthic oxygen isotopes may be either related to a cooling or increasing salinity in bottom waters. Higher salinity of bottom waters may be again caused by dense water formation during winter sea-ice formation in southern and western Svalbard fjords (e.g., Quadfasel et al., 1988; Rudels et al., 2005). Bauch, H. A., H. Erlenkeuser, R. F. Spielhagen, U. Struck, J. Matthiessen, J. Thiede, and J. Heinemeier (2001a), A multiproxy reconstruction of the evolution of deep and surface waters in the subarctic Nordic seas over the last 30,000 yr, Quaternary Science Reviews, 20(4), 659-678. Hass, H. C. (2002), A method to reduce the influence of ice-rafted debris on a grain size record from northern Fram Strait, Polar Research, 21(2), 299-306. Quadfasel, D., B. Rudels, and K. Kurz (1988), Outflow of dense water from a Svalbard fjord into the Fram Strait, Deep Sea Research Part A. Oceanographic Research Papers, 35(7), 1143-1150. Rudels, B., G. Bjork, J. Nilsson, P. Winsor, I. Lake, and C. Nohr (2005), The interaction between waters from the Arctic Ocean and the Nordic Seas north of Fram Strait and along the East Greenland Current: results from the Arctic Ocean-02 Oden expedition, Journal of Marine Systems, 55(1-2), 1-30. Sarnthein, M., S. van Krefeldt, H. Erlenkeuser, P. M. Grootes, M. Kucera, U. Pflaumann, and M. Schulz (2003), Centennial-to-millennial-scale periodicities of Holocene climate and sediment injections off the western Barents shelf, 75◦N, Boreas, 32, 447-461.