ALBERT

Description: 〈span〉The Sentinel Bluffs Member is the youngest unit of the Grande Ronde Basalt, having typical physical characteristics of most large-volume Columbia River Basalt Group (CRBG) sheet flows. These flows have been studied for over 50 years, resulting in numerous scientific publications from academic institutions, federal and state regional mapping projects, more detailed mapping associated with the U.S. Department of Energy’s (USDOE) Hanford Site (southeastern Washington State), and borehole investigations focused in part on petroleum exploration in the Columbia Basin. The compositional heterogeneity of individual flows, although small, has been interpreted by many workers as being the result of magma chamber processes (e.g., Wright et al., 1973; Wright and Swanson, 1980; Mangan et al., 1986; Hooper, 2000; Reidel, 2005) combined in places with surficial mixing as the flows are emplaced (e.g., Reidel and Tolan, 2013). Sawlan (2018) argues instead that flow heterogeneity in the Sentinel Bluffs Member is largely the result of previously unrecognized chemical alteration of basalt in contact with aquifers, accompanied by significant mass loss (up to 50%). The fact that nearly all CRBG lava flows are in contact with the confined aquifer system, even those in the anticlinal ridges, suggests that such alteration, if it existed, could be widespread.The ramifications of widespread, hitherto undocumented alteration are compelling, in part because of the ambiguity such alteration would place on previous interpretations that rely on high-quality chemical data. Such data could be queried as problematic or invalid in a variety of studies that focus, for example, on chemostratigraphic correlations (e.g., Reidel, 2005; Conrey and Wolff, 2010; Vye-Brown et al., 2013; Martin et al., 2013; Wells et al., 2009) or on petrogenesis and evolution of the basalts (e.g., Davis et al., 2017; Blake et al., 2010; Martin, 1989; Wolff et al., 2008; Wolff and Ramos, 2013; Ramos et al., 2005, 2009, 2013; Tollstrup et al., 2002; Hooper, 1984; Hooper and Hawkesworth, 1993; Rodriguez and Sen, 2013; Thordarson and Self, 1998), as well as in paleomagnetic studies where the results are extremely sensitive to alteration especially in the case of iron minerals (e.g., magnetite, hematite) and rely on compositional data for flow identification (e.g., Wells et al., 1989; Hagstrum et al., 2010).Consideration and scrutiny of the Sawlan (2018) study is both timely and relevant to workers on the CRBG, but it is also pertinent to workers on other basalt provinces where aquifers are present (e.g., Hawaii, the Snake River Plain [Idaho], and the Oregon High Lava Plains). We therefore embrace debate on the potential role of these aquifers in modifying primary magmatic compositions. It is our contention that careful sample collection of the CRBG has generated largely unaltered chemical compositions, and that the alteration hypothesis of Sawlan (2018) is incorrect due to flawed methodology. As a contribution to this debate, we (1) examine long-established procedures and sampling techniques that have allowed workers to avoid significant alteration when collecting and analyzing CRBG flows; (2) describe data collection of the Sentinel Bluffs Member and chemical variations that have been attributed to both magmatic processes and secondary alteration; and (3) discuss the concerns we have on the rationale and analytical methodology that form the basis for Sawlan’s (2018) conclusions that compositional variations in the Sentinel Bluff Member are the result of chemical alteration from basalt-water interaction.〈/span〉

Description: 〈span〉New analyses of U-Pb ages along with previously published analyses of detrital zircons from sandstones in the foreland of the Marathon orogen in west Texas have significant implications regarding provenance. The most prominent concentrations of U-Pb ages are at 1200–1000, 700–500, and 500–290 Ma. The accreted Coahuila terrane in the Marathon hinterland and nearby terranes with Gondwanan (Amazonia) affinity include Paleozoic volcanic and plutonic rocks, as well as Precambrian basement rocks. Late Paleozoic Las Delicias arc rocks have ages of 331–270 Ma. Detrital zircons from Upper Jurassic and Lower Cretaceous sandstones, which were deposited in local basins around the Coahuila terrane, provide a record of detritus available from proximal sources within Coahuila, including important peaks at 1040, 562, 422, 414, 373, and 282 Ma. Components of the detrital-zircon populations in the Marathon foreland have unique matches with primary and/or detrital sources in the Coahuila terrane. Although some components of the Marathon populations also have age matches in Laurentia (Appalachians), others do not; however, all components of the Marathon populations have potential sources in Coahuila. Analyses of ε〉Hf〈sub〉t〈/sub〉 show generally more negative values in Amazonia than in Laurentia, and εHf〈sub〉t〈/sub〉 values for Marathon sandstones have distributions similar to those in Amazonia. Therefore, the Coahuila terrane provides a provenance for all of the detrital-zircon ages in the Marathon foreland, requiring no mixing from other sources.〈/span〉

Description: 〈span〉Various styles of ore deposits may form from a single magmatic-hydrothermal system. Identification of a possible genetic link between different ore types in a region is not only of critical importance for a better understanding of the magmatic-hydrothermal processes, but can also help in successful mineral exploration. Both iron oxide-apatite (IOA) and iron skarn deposits are closely associated with intrusive rocks of intermediate to felsic in composition, but whether these two ore types can form from the same magmatic intrusion remains poorly understood. In this study, we present a comparative study between a newly identified subsurface IOA ore body located at the apex of a diorite porphyry and the iron skarn ore bodies located immediately above it in the Jinniu volcanic basin of the Daye district, Middle-Lower Yangtze River metallogenetic belt (MLYRMB), eastern China in order to highlight a genetic link between these two styles of mineralization. The IOA ores are dominated by Ti-rich magnetite with variable amounts of fluorapatite, diopside, and actinolite. This mineralogical assemblage is distinctly different from the iron skarn ores, which consist mainly of Ti-depleted magnetite and subordinate pre-ore garnet and diopside, and post-ore quartz, chlorite, calcite, and pyrite. In addition, magnetite from the IOA ores is characterized by well-developed ilmenite lamellae and has high concentrations of Ni, V, Co, and Ga, consistent with high temperature crystallization, whereas magnetite grains from the iron skarn ores usually exhibit oscillatory growth zones and contain much lower Ni, V, Co, and Ga, indicating their formation under relatively low temperatures. Titanite and fluorapatite from the IOA ores have U-Pb ages of 132.5 ± 2.4 Ma to 128.4 ± 3.0 Ma, which match a titanite U-Pb age for the associated iron skarn ores (132.3 ± 2.0 Ma), and are consistent with zircon U-Pb ages for the ore-hosting diorite porphyry (130.4 ± 0.7 Ma to 130.3 ± 0.5 Ma). This age consistency supports a possible genetic link among the diorite porphyry, IOA ores, and iron skarn ores. We propose that the IOA and skarn ores are the products of two consecutive mineralization stages of the same magmatic-hydrothermal system, involving a high-temperature, hypersaline fluid coexisting with the diorite porphyry magma during emplacement and a subsequent low temperature, diluted hydrothermal fluid. Other IOA and iron skarn deposits of similar ages (130 Ma) are found in a series of volcanic basins in the MLYRMB, which forms one of the world’s largest IOA metallogenic belts. The close association of the two ore styles identified at Daye provides a useful exploration guide for IOA and iron skarn deposits both on a local and regional scale.〈/span〉

Description: 〈span〉The late Ludlow Lau Event was a severe biotic crisis in the Silurian, characterized by resurgent microbial facies and faunal turnover rates otherwise only documented during the "big five" mass extinctions. This asynchronous late Silurian marine extinction event preceded an associated positive carbon isotope excursion (CIE), the Lau CIE, although a mechanism for this temporal offset remains poorly constrained. Here, we report thallium isotope data from locally reducing late Ludlow strata within the Baltic Basin to document the earliest onset of global marine deoxygenation. The initial expansion of anoxia coincided with the onset of the extinction and therefore preceded the Lau CIE. Additionally, sulfur isotope data record a large positive excursion parallel to the Lau CIE, interpreted to indicate an increase in pyrite burial associated with the widely documented CIE. This suggests a possible global expansion of euxinia (anoxic and sulfidic water column) following deoxygenation. These data are the most direct proxy evidence of paleoredox conditions linking the known extinction to the Lau CIE through the progressive expansion of anoxia, and most likely euxinia, across portions of the late Silurian oceans.〈/span〉

Description: 〈span〉Microbially induced sedimentary structures (MISS) are reportedly widespread in the Early Triassic and their occurrence is attributed to either the extinction of marine grazers (allowing mat preservation) during the Permo-Triassic mass extinction or the suppression of grazing due to harsh, oxygen-poor conditions in its aftermath. Here we report on the abundant occurrence of MISS in the Lower Triassic Blind Fiord Formation of the Sverdrup Basin, Arctic Canada. Sedimentological analysis shows that mid-shelf settings were dominated by deposition from cohesive sand-mud flows that produced heterolithic, rippled sandstone facies that pass down dip into laminated siltstones and ultimately basinal mudrocks. The absence of storm beds and any other “event beds” points to an unusual climatic regime of humid, quiet conditions characterized by near continuous run off. Geochemical proxies for oxygenation (Mo/Al, Th/U, and pyrite framboid analysis) indicate that lower dysoxic conditions prevailed in the basin for much of the Early Triassic. The resultant lack of bioturbation allowed the development and preservation of MISS, including wrinkle structures and bubble textures. The microbial mats responsible for these structures are envisaged to have thrived, on sandy substrates, within the photic zone, in oxygen-poor conditions. The dysoxic history was punctuated by better-oxygenated phases, which coincide with the loss of MISS. Thus, Permo-Triassic boundary and Griesbachian mudrocks from the deepest-water settings have common benthos and a well-developed, tiered burrow profile dominated by 〈span〉Phycosiphon〈/span〉. The presence of the intense burrowing in the earliest Triassic contradicts the notion that bioturbation was severely suppressed at this time due to extinction losses at the end of the Permian. The notion that Early Triassic MISS preservation was caused by the extinction of mat grazers is not tenable.〈/span〉

Description: 〈span〉The largest extinction in Earth history, in the latest Permian, was followed throughout most of the Early Triassic by a prolonged period of ecologic recovery. What factors delayed biotic recovery are still under debate and partly revolve around impacts of global warming on primary marine productivity. We examined N isotope records from the Festningen section on Spitsbergen, Arctic Norway, to examine changes in nutrient availability through the Early to Middle Triassic along the northern margin of Pangea. Our results show progressive decline in N availability throughout the Griesbachian, leading to severe nutrient limitations through the remainder of the Early Triassic, until returning to a highly productive continental margin in Middle Triassic time. These results are consistent with other studies from northern and western Pangea and thus show regional nutrient limitations occurred in what should have been the main zone of marine primary productivity. Such nutrient limitation likely stressed primary production and consequently contributed to prolonged marine recovery. We suggest this was driven by high ocean temperatures depressing the marine nutricline.〈/span〉

Description: 〈span〉Oxidation of particulate organic carbon (POC) during fluvial transit releases CO〈sub〉2〈/sub〉 to the atmosphere and can influence global climate. Field data show large POC oxidation fluxes in lowland rivers; however, it is unclear if POC losses occur predominantly during in-river transport, where POC is in continual motion within an aerated environment, or during transient storage in floodplains, which may be anoxic. Determination of the locus of POC oxidation in lowland rivers is needed to develop process-based models to predict POC losses, constrain carbon budgets, and unravel links between climate and erosion. However, sediment exchange between rivers and floodplains makes differentiating POC oxidation during in-river transport from oxidation during floodplain storage difficult. Here, we isolated in-river POC oxidation using flume experiments transporting petrogenic and biospheric POC without floodplain storage. Our experiments showed solid phase POC losses of 0%–10% over ~10〈sup〉3〈/sup〉 km of fluvial transport, compared to ~7% to 〉50% losses observed in rivers over similar distances. The production of dissolved organic carbon (DOC) and dissolved rhenium (a proxy for petrogenic POC oxidation) was consistent with small POC losses, and replicate experiments in static water tanks gave similar results. Our results show that fluvial sediment transport, particle abrasion, and turbulent mixing have a minimal role on POC oxidation, and they suggest that POC losses may accrue primarily in floodplain storage.〈/span〉

Description: 〈span〉Plume-modified orogeny involves the interaction between a mantle plume and subducting oceanic lithosphere at accretionary margins. We propose that a plume can also be involved in collisional orogeny and accounts for the late Paleozoic geological relations in Central Asia. Continental collision between the Tarim and Central Tianshan–Yili blocks at the end Carboniferous resulted in an orogeny lacking continental-type (ultra)high-pressure [(U)HP] rocks and significant syncollision surface erosion and uplift, features normally characteristic of continent-continent interactions. Their absence from the Tianshan region corresponded with the arrival of a mantle plume beneath the northern Tarim. Elemental and isotopic data reveal an increasing influence of the mantle plume on magmatic petrogenesis from ca. 300 to 280 Ma, immediately after collision at 310–300 Ma. The rising mantle plume interrupted the normal succession of collisional orogenic events, destroying the deeply subducted continental crust and hence preventing slab break-off–induced continental rebound. Plume-modified continental collision thus limited continental (U)HP rock exhumation and associated surface uplift.〈/span〉

Description: 〈span〉The tectonic affinity of the terranes and microcontinents within the Central Asian Orogenic Belt (CAOB) remains controversial. The Altai-Mongolian terrane (AMT), as a representative tectonic unit in the Mongolian collage, plays a vital role in reconstructing evolution history of the CAOB. The well-preserved early Paleozoic sedimentary sequence covering in this terrane could be considered as a fingerprint to track its provenance and tectonic affinity. Here, we present new whole-rock geochemistry, detrital zircon U-Pb dating, and Hf isotopic analysis for the metasedimentary rocks from the Mongolian Altai in order to shed new light on the tectonic affinity of the AMT. The youngest detrital zircon ages and the regional intrusions constrain the depositional time of the Mongolian Altai sequence to between Late Silurian and Early Devonian, which is consistent with the Habahe group in the western Chinese Altai. The features of whole-rock geochemistry and the cumulative distribution curves of the detrital zircon age spectra indicate that the Mongolian Altai sequence was probably deposited in an active continental setting during early Paleozoic. The zircon age spectra of our samples are all characterized by a main age group in the early Cambrian (peak at 541 Ma, 522 Ma, 506 Ma and 496 Ma, respectively), subdominant age populations during the Tonian, as well as rare older zircons. The nearby Lake Zone of Ikh-Mongol Arc most likely provided plenty of early Paleozoic materials, the subdominant Neoproterozoic detrital zircons could be supplied by the felsic intrusions along the western margin of the Tuva-Mongol microcontinent, and the sparse older zircons may be derived from its basement material. The Precambrian age distribution of the AMT is quite similar to both the Tarim and Siberia cratons, but the Siberia Craton displays a closer resemblance in Hf isotopic composition with the AMT. Thus, we believe that the Siberia Craton contains a closer tectonic affinity with the AMT, and that the Tuva-Mongol microcontinent possibly rifted from the western margin of this craton after the Tonian. To the south of the AMT, recent studies indicated the Yili and Central Tianshan blocks in the Kazakhstan collage of the western CAOB likely have a closer affinity with Gondwana. Therefore, the microcontinents in the CAOB most likely derived bilaterally from both the Siberia Craton and the Gondwana supercontinent. Moreover, our Hf isotopic compositions indicate two significant continental growth events in the Tonian and early Paleozoic, respectively.〈/span〉

Description: 〈span〉The Neoarchean crust-mantle interaction and crustal evolution of the North China craton are controversial and are instructive of the processes of continental crust growth and cratonic evolution. We present here a systematic study of the petrology, geochemistry, and geochronology of Neoarchean granitoids from the eastern North China craton to elucidate their petrogenesis and tectonic setting. The rocks were collected from the Jielingkou, Anziling, and Qinhuangdao plutons, and an amphibole-monzoporphyry dike in the Qinhuangdao pluton. Samples from the Jielingkou pluton, consisting dominantly of monzodiorite and diorite with minor monzonite and granodiorite, contain 52.2−64.4 wt% SiO〈sub〉2〈/sub〉, 2.46−4.52 wt% MgO (Mg# = 0.41−0.54), 3.76−5.77 wt% Na〈sub〉2〈/sub〉O, and K〈sub〉2〈/sub〉O/Na〈sub〉2〈/sub〉O ratios of 0.29−0.71. The Anziling pluton samples, comprising syenite and monzonite, display slightly higher SiO〈sub〉2〈/sub〉 (60.9−66.7 wt%) and K〈sub〉2〈/sub〉O/Na〈sub〉2〈/sub〉O ratios (0.70−1.11), but lower MgO (1.54−2.33 wt%) and Mg# (0.40−0.47) values, compared to the Jielingkou rocks. The Qinhuangdao pluton samples, consisting mainly of granite and minor syenite and granodiorite, with some diorite and monzoporphyry dikes, are characterized by the highest SiO〈sub〉2〈/sub〉 values (75.7−76.9 wt%) and K〈sub〉2〈/sub〉O/Na〈sub〉2〈/sub〉O ratios (0.73−1.41) and lowest MgO content (0.14−0.32 wt%) among the studied samples. The amphibole-monzoporphyry dike has intermediate SiO〈sub〉2〈/sub〉 (56.3 wt%), high MgO (3.79 wt%), Na〈sub〉2〈/sub〉O (5.55 wt%), and Mg# (0.45), and low K〈sub〉2〈/sub〉O/Na〈sub〉2〈/sub〉O ratio (0.66). Zircon U-Pb laser-ablation−inductively coupled plasma−mass spectrometry dating showed that all plutons have a ca. 2.5 Ga crystallization age. Zircon crystals have mildly positive ε〈sub〉Hf(〈/sub〉〈span〉t〈/span〉〈sub〉)〈/sub〉 values (+0.24 to +5.45) and a depleted mantle model age (T〈sub〉DM1〈/sub〉) of ca. 2.7 Ga. We interpret the granitoid rocks as sanukitoid-related, Closepet-type granites, potassium-rich adakites, and potassium-rich granitoid rocks that crystallized in the late Neoarchean (2.5 Ga) and were derived from partial melting of mantle peridotite that was metasomatized with the addition of slab melt, including both thickened alkali-rich juvenile lower crust and juvenile metamorphosed tonalitic rocks. Mantle plume activity ca. 2.7 Ga is thought to have been responsible for the early Neoarchean tectono-thermal event in the eastern North China craton. This activity resulted in a major crustal accretion period in the craton, with subordinate crustal reworking at its margins. A steep subduction regime between ca. 2.55 Ga and ca. 2.48 Ga led to the remelting of older crustal material, with subordinate crustal accretion by magma upwelling from a depleted mantle source resulting in late Neoarchean underplating. This crustal reworking and underplating resulted in the widespread ca. 2.5 Ga plutons in the eastern North China craton. Continental crust growth in the North China craton thus occurred in multiple stages, in response to mantle plume activity, as well as protracted subduction-related granitoid magmatism during the Neoarchean.〈/span〉