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  • 1
    Publication Date: 2013-03-22
    Description: Oxygen isotope ratios of olivine have become a widely used tool for the study of magmatic systems, especially in the interpretation of source heterogeneities in mantle plume–derived ocean island basalts. The underlying assumption is that fresh minerals provide a better guide to magma 18 O than bulk rock analyses and that olivine is also likely to be a major phenocryst phase in primitive magmas. However, distinctions between source compositions and the effects of subsequent magma evolution have not always been thoroughly scrutinized. For the Azores samples investigated here, we can demonstrate that the 18 O variation (+4.84 to +5.25 Vienna standard mean ocean water) observed in the olivine phenocryst population is closely linked to evolution in the host magmas during ascent to the surface. We observe a linear, positive correlation between forsterite (Fo) content and 18 O in all of the individual island lava suites. This forces us to conclude that the low oxygen isotope ratios result from combined assimilation and fractional crystallization processes, the assimilant being hydrothermally (temperature 〉 250 °C) altered, lower oceanic crust. Linear regression of the measured 18 O olivine values to Fo 89 suggests a homogeneous mantle source with 18 O = +5.2 ± 0.1.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 2
    Publication Date: 2018
    Description: 〈span〉ORIGINAL ARTICLE: 2018, v. 46, no. 11, p. 〈strong〉〈a href="https://pubs.geoscienceworld.org/article.aspx?volume=&page="〉947–950〈span〉〈/span〉〈/a〉〈/strong〉, 〈a href="https://doi.org/10.1130/G45359.1"〉https://doi.org/10.1130/G45359.1〈/a〉. First published 27 September 2018.〈/span〉
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 3
    Publication Date: 2018
    Description: 〈span〉〈div〉Abstract〈/div〉Island arcs provide insights into the origin and recycling of continental crust, but questions remain concerning source metasomatism, the depth of differentiation, the potential role of amphibole fractionation, and the time scales involved. Basaltic andesites on Batan Island (Philippines) contain ≥150 Ma peridotite fragments encased in hornblendite and gabbroic rinds produced via melt-rock reaction. The peridotites have some of the lightest δ〈sup〉7〈/sup〉Li and δ〈sup〉57〈/sup〉Fe values yet measured in mantle rocks. These values are too fractionated to have been created solely by equilibrium partial melting and thus require a combination of melt depletion and slab fluid addition and may be derived from diffusion-modified melt channel wall rocks. Stable isotope signals are easily modified by diffusive equilibration between peridotite and host magma, so the preservation of light δ〈sup〉7〈/sup〉Li and δ〈sup〉57〈/sup〉Fe here suggests magma ascent rates of ∼10 km yr〈sup〉−1〈/sup〉. We show that melt–wall rock reactions at ∼25–30 km depth led to the crystallization of amphibole (± plagioclase) followed by gabbroic fractionation at ∼7 km depth. The former provides a location and mechanism for the “cryptic” amphibole fractionation observed in these and perhaps many other arc lavas and may obviate the requirement for delamination of cumulates.〈/span〉
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
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  • 4
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    Geological Society of America (GSA)
    In: Geology
    Publication Date: 2014-01-28
    Description: How the Earth’s earliest crust was formed and when present-day plate tectonics (i.e., subduction) and life commenced remain fundamental questions in Earth sciences. Whereas the bulk composition of the crust is similar to that of rocks generated in subduction settings, it does not necessarily follow that melting and crust formation require subduction. Many workers suggest that subduction may have only commenced toward the end of the Archean or later. Here we observe that both the stratigraphy and geochemistry of rocks found in Quebec, Canada, that have been variously argued to be 4.4 or 3.8 Ga in age, closely match those from the modern-day Izu-Bonin-Mariana forearc. We suggest that this geochemical stratigraphy might provide a more robust test of ancient tectonic setting than individual chemical or isotopic signatures in rocks or detrital minerals. If correct, the match suggests that at least some form of subduction may have been operating as early as the Hadean or Eoarchean. This could have provided an ideal location for the development of first life.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 5
    Publication Date: 2017-01-21
    Description: Volcanic sequences on ocean islands record the temporal evolution of underlying magmatic systems and provide insights into how silicic crust is produced away from convergent margins. Assimilation has often been suspected to contribute, but the detection of such a process and its evolving maturity during migration across a mantle plume is less well documented. Here we present new major and trace element and Sr-Nd-Pb-U-Th-Ra-Pa isotope data that facilitate comparison of basanite to phonolite evolution on Tenerife (Canary Islands) with that shown by published data from La Palma. On both islands, ( 230 Th/ 238 U) ratios decrease with differentiation from parental magmas with 230 Th excess toward different, silicic contaminants in secular equilibrium. On La Palma, this is inferred to reflect assimilation of small amounts of mafic wall rock. On Tenerife, both ( 230 Th/ 238 U) and ( 231 Pa/ 235 U) ratios decrease toward 1 with increasing differentiation, and this is accompanied by a subtle increase in Pb isotope ratios. At the same time, ( 226 Ra/ 230 Th) ratios change from 〉1 to 〈1 (a hitherto unreported magnitude). The Tenerife assimilant is thus constrained to be a partial melt of syenite formed in equilibrium with residual feldspar. The differences reflect a primarily deeper, more mafic magma system beneath La Palma during its late shield-building stage, whereas recent magmatic evolution at Tenerife occurs primarily at lower temperatures in small, shallower magma systems formed during its post–basaltic shield stage. Differentiation takes millennia or less.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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