ALBERT

Description: Diamond is essentially impermeable and unreactive under many conditions, and tiny mineral inclusions within natural diamonds can faithfully preserve information on the chemical and physical conditions during diamond growth. The stable isotope ratios of carbon, nitrogen, oxygen, and sulfur in diamonds and their mineral inclusions have been used to constrain models of diamond formation, but interpretations of the data have differed dramatically. The crux of the controversy lies in the interpretation of the carbon isotope ratios of eclogite-suite diamonds, which range well outside those expected for typical mantle materials such as peridotites, basalts, and carbonatites. Proposed explanations for these anomalous carbon isotope ratios include derivation from primordial mantle inhomogeneities, fractionated mantle fluids, and subducted biogenic carbon. Working with samples from three continents, we have analyzed the carbon isotope compositions of eclogite-suite diamonds and the oxygen isotope composition of their mineral inclusions, primarily by ion microprobe methods. We have discovered a previously unrecognized, remarkably consistent anticorrelation between these two isotopic systems, in that virtually all diamonds with anomalously low carbon isotope ratios have silicate inclusions with anomalously high oxygen isotope ratios. This is a fundamental observation that can only be explained by formation of eclogite-suite diamonds through subduction of seafloor altered basalt, admixed with marine biogenic carbon, into the field of diamond stability.

Description: The Salamanca Formation of the San Jorge Basin (Patagonia, Argentina) preserves critical records of Southern Hemisphere Paleocene biotas, but its age remains poorly resolved, with estimates ranging from Late Cretaceous to middle Paleocene. We report a multi-disciplinary geochronologic study of the Salamanca Formation and overlying Río Chico Group in the western part of the basin. New constraints include (1) an 40 Ar/ 39 Ar age determination of 67.31 ± 0.55 Ma from a basalt flow underlying the Salamanca Formation, (2) micropaleontological results indicating an early Danian age for the base of the Salamanca Formation, (3) laser ablation HR-MC-ICP-MS (high resolution-multi collector-inductively coupled plasma-mass spectrometry) U-Pb ages and a high-resolution TIMS (thermal ionization mass spectrometry) age of 61.984 ± 0.041(0.074)[0.100] Ma for zircons from volcanic ash beds in the Peñas Coloradas Formation (Río Chico Group), and (4) paleomagnetic results indicating that the Salamanca Formation in this area is entirely of normal polarity, with reversals occurring in the Río Chico Group. Placing these new age constraints in the context of a sequence stratigraphic model for the basin, we correlate the Salamanca Formation in the study area to Chrons C29n and C28n, with the Banco Negro Inferior (BNI), a mature widespread fossiliferous paleosol unit at the top of the Salamanca Formation, corresponding to the top of Chron C28n. The diverse paleobotanical assemblages from this area are here assigned to C28n (64.67–63.49 Ma), ~2–3 million years older than previously thought, adding to growing evidence for rapid Southern Hemisphere floral recovery after the Cretaceous-Paleogene extinction. Important Peligran and " Carodnia " zone vertebrate fossil assemblages from coastal BNI and Peñas Coloradas exposures are likely older than previously thought and correlate to the early Torrejonian and early Tiffanian North American Land Mammal Ages, respectively.

Description: The Kikiktat volcanics (new name) of the northeastern Brooks Range of Arctic Alaska are exceptionally well-preserved Neoproterozoic continental tholeiites. This volcanic suite includes high-temperature picritic compositions, making them an excellent probe of mantle composition and temperature underlying the northern margin of Laurentia during the breakup of Rodinia. Detrital zircons from a volcaniclastic sample directly overlying basaltic flows of the Kikiktat volcanics were dated at 719.47 ± 0.29 Ma by U-Pb chemical abrasion–thermal ionization mass spectrometry. This age suggests that the Kikiktat volcanics are an extension of the Franklin large igneous province. Petrogenetic modeling indicates a simple crystallization sequence of olivine -〉 plagioclase -〉 clinopyroxene, recording anhydrous low-pressure fractionation of a picritic parental melt. The composition of this parental liquid requires melting of harzburgite in the spinel stability field, while temperature estimates of the primary melt indicate elevated mantle potential temperatures. In contrast to the ca. 720 Ma Natkusiak basalts of Victoria Island, the Kikiktat volcanics have very low Ti concentrations, consistent with melting of harzburgitic mantle possibly by thermal conduction of an underlying plume. These data are consistent with Neoproterozoic to early Paleozoic tectonic reconstructions that restore the North Slope of Arctic Alaska to the northeastern margin of Laurentia and not directly adjacent to Victoria Island.

Description: U-Pb zircon data from the uppermost Cottons Breccia, representing the Marinoan glacial-postglacial transition on King Island, Tasmania, provide the first direct age constraint on the Cryogenian-Ediacaran boundary in Australia. Zircons in four samples from the topmost meter of the Cottons Breccia, dated by sensitive high-resolution ion microprobe, exhibit two modes ca. 660 Ma and ca. 635 Ma. The younger component predominates in the uppermost sample, a possibly volcanolithic dolomitic sandstone, apparently lacking glacially transported debris, in the transition to cap carbonate. Chemical abrasion–thermal ionization mass spectrometry (CA-TIMS) U-Pb dating of euhedral zircons from that sample yields a weighted-mean age of 636.41 ± 0.45 Ma. Equivalence to published TIMS ash bed dates from Cryogenian-Ediacaran transitional strata in Namibia (635.51 ± 0.82 Ma, within glacial deposit) and China (635.23 ± 0.84 Ma, 2 m above glacial deposit) supports correlation of those strata to the Australian type sections and globally synchronous deglaciation at the end of the Cryogenian Period.

Description: While most oceanic volcanism is associated with the passive rise of hot mantle beneath the spreading axes of mid-ocean ridges (MOR), volcanism occurring off-axis reflects intraplate upper-mantle dynamics and composition, yet is poorly understood. Off the south East Pacific Rise (SEPR), volcanism along the Pukapuka, Hotu-Matua, and Sojourn ridges has been attributed to various mechanisms, but none can reconcile its spatial, temporal, and geochemical characteristics. Our three-dimensional numerical models show that asthenospheric shear can excite upwelling and decompression melting at the tip of low-viscosity fingers that are propelled eastward by vigorous sublithospheric flow. This shear-driven upwelling is able to sustain intraplate volcanism that progresses toward the MOR, spreads laterally close to the axis, and weakly continues on the opposite plate. These predictions can explain the anomalously fast eastward progression of volcanism, and its spatial distribution near the SEPR. Moreover, for a heterogeneous mantle source involving a fertile component, the predicted systematics of volcanism can explain the geochemical trend along Pukapuka and the enriched anomaly of SEPR mid-oceanic ridge basalt at 16°–20.5°S. Our study highlights the role of horizontal asthenospheric flow and mantle heterogeneity in producing linear chains of intraplate volcanism independent of a (deep-rooted) buoyancy source.

Description: Management and restoration of the Mississippi River deltaic plain (southern United States) and associated wetlands require a quantitative understanding of sediment delivery during large flood events, past and present. Here, we investigate the sedimentary fingerprint of the 2011 Mississippi River flood across the Louisiana coast (Atchafalaya Delta, Terrebonne, Barataria, and Mississippi River Delta basins) to assess spatial patterns of sedimentation and to identify key indicators of sediment provenance. The sediment deposited in wetlands during the 2011 flood was distinguished from earlier deposits based on biological characteristics, primarily absence of plant roots and increased presence of centric (planktonic) diatoms indicative of riverine origin. By comparison, the lithological (bulk density, organic matter content, and grain size) and chemical (stable carbon isotopes of bulk organic matter) properties of flood sediments were nearly identical to the underlying deposit. Flood sediment deposition was greatest in wetlands near the Atchafalaya and Mississippi Rivers and accounted for a substantial portion (37% to 85%) of the annual accretion measured at nearby monitoring stations. The amount of sediment delivered to those basins (1.1–1.6 g cm –2 ) was comparable to that reported previously for hurricane sedimentation along the Louisiana coast (0.8–2.1 g cm –2 ). Our findings not only provide insight into how large-scale river floods influence wetland sedimentation, they lay the groundwork for identifying previous flood events in the stratigraphic record.

Description: Speleothems are important paleoclimate archives. Researchers typically compile measurements of stable isotopic ratios dated using high precision U-Th radiometric techniques to reconstruct regional and global climate. Magnetic material incorporated within speleothems can provide an independent means of connecting large-scale climatic changes with their impact on more localized processes in soils overlying cave systems. Under certain environmental conditions, pedogenic processes can produce magnetite nanoparticles. Enhancement of pedogenic magnetite in soil profiles depends strongly on local precipitation. Pedogenic magnetite can be subsequently transferred via drip-waters into underlying cave-systems and incorporated into speleothems as they grow. Here, we employ high-resolution magnetic methods to analyze a well-dated stalagmite from Buckeye Creek Cave, West Virginia (USA), and find that changes in magnetite concentration follow both changes in stable isotopes measured in the same stalagmite and global climate proxies. We interpret the changes in magnetite concentration as reflecting variations in local pedogenic processes, controlled by changes in regional precipitation. This record demonstrates how magnetic measurements on speleothems can constrain interpretations of speleothem climate proxies.

Description: The need to accurately document the spatiotemporal distribution of earthquake-generated strong ground motions is essential for evaluating the seismic vulnerability of sites of critical infrastructure. Understanding the threshold for maximum earthquake-induced ground motions at such sites provides valuable information to seismologists, earthquake engineers, local agencies, and policymakers when determining ground motion hazards of seismically sensitive infrastructures. In this context, fragile geologic features such as precariously balanced rocks (PBRs) serve as negative evidence for earthquake-induced ground motions and provide important physical constraints on the upper limits of ground motions. The three-dimensional (3D) shape of a PBR is a critical factor in determining its static stability and thus susceptibility to toppling during strong ground shaking events. Furthermore, the geomorphic settings of PBRs provide important controls on PBR exhumation histories that are interpreted from surface exposure dating methods. In this paper, we present PBRslenderness, a MATLAB-based program that evaluates the two-dimensional (2D) static stabilities of PBRs from unconstrained digital photographs. The program’s graphical user interface allows users to interactively digitize a PBR and calculates the 2D geometric parameters that define its static stability. A reproducibility study showed that our 2D calculations compare well against their counterparts that were computed in 3D (R 2 = 0.77–0.98 for 22 samples). A sensitivity study for single-user and multiuser digitization routines further confirmed the reproducibility of PBRslenderness estimates (coefficients of variation c v = 4.3%–6.5% for 100 runs; R 2 = 0.87–0.99 for 20 PBRs). We used PBRslenderness to analyze 261 PBRs in a low-seismicity setting to investigate the local geomorphic controls on PBR stability and preservation. PBRslenderness showed that a PBR’s shape strongly controls its static stability and that there is no relationship between a PBR’s stability and its geomorphic location in a drainage basin. However, the geomorphic settings of PBRs control their preservation potential by restricting their formation to hillslope gradients 〈40° and the upper reaches of drainage basins. Such examples of our program’s utility have led to its use in archival efforts of PBRs in southern California and Nevada, USA.

Description: The mid-lithospheric discontinuity (MLD) is a seemingly sharp decrease in seismic velocity at depths internal to the lithosphere and appears to be a pervasive feature beneath continental interiors. Its presence within cratons, which have remained relatively stable since formation, suggests that the MLD may result from processes associated with continent formation. We use P- to S-wave receiver functions to interrogate seismic anisotropy across the MLD within the ca. 1.35–1.55 Ga Granite-Rhyolite Province of the central United States. Our analysis reveals strong evidence for sharp changes in the orientation of anisotropy across multiple MLDs, with an approximately north to northwest fast orientation of anisotropy in the upper lithosphere. The consistency of this signature over a large region suggests that the observed anisotropy is a relic of North American craton formation. In addition, the presence of several distinct anisotropic layers within the cratonic lithosphere supports models for craton formation via stacked subducted slabs or a series of underthrusting events.