ALBERT

Description: Due to iron’s role in oceanic primary production, there has been great interest in quantifying the importance of Fe in regions where concentrations are very low and macronutrients, nitrate and phosphate, are available. Measurements of filterable (i.e., 〈0.4 μm) Fe concentrations in streams from Taylor Valley, McMurdo Dry Valleys, Antarctica, suggest that coastal-zone stream Fe input to the Southern Ocean could potentially play an important role in primary production in nearshore regions. Filterable Fe (fFe) data from streams in the McMurdo Dry Valleys were used to represent glacier meltwater that flows through ice-free landscape with the potential of transporting Fe to the Antarctic coastal zone. Estimates of potential fFe flux to the Antarctic Peninsula region using our mean fFe concentration of 10.6 µg L –1 combined with an estimate of ice-free area for the Antarctic Peninsula result in an fFe flux of 1.2 x 10 7 g yr –1 . Although small compared to iceberg and aeolian Fe fluxes, future stream input to the Southern Ocean could increase due to glacier retreat and melting, thus increasing the fFe flux from glacier meltwater streams.

Description: The Isthmus of Panama comprises a lithologically diverse andesitic oceanic arc of Late Cretaceous to Holocene age; it has large spatial variation in rainfall, displays a large range of physical erosion rates, and, therefore, is an ideal location to examine silicate weathering in the tropics. We use a multiyear data set of river chemistry for a 450 km transect across the Cordillera Central of west-central Panama to investigate controls on chemical weathering in tropical small mountainous rivers. Sea-salt corrected cation weathering yields (Ca sil + Mg sil + Na + K) range over more than an order in magnitude from 3.1 to 31.7 t/km 2 /yr, while silicate weathering yields (Ca sil + Mg sil + Na + K + Si) range from 6.9 to 69.5 t/km 2 /yr. Watershed lithology is the primary control on riverine chemistry, but landscape topographic character and land cover and/or land use also influence solute delivery potential. Strong statistical links of small mountainous river chemical weathering fluxes with rainfall and physical weathering rates attest to the importance of runoff and erosion in maintaining elevated bedrock weathering rates. CO 2 consumption ranges from 155 x 10 3 mol/km 2 /yr to 1566 x 10 3 mol/km 2 /yr, in the upper range of global rates, leading us to suggest that andesite terrains should be considered separately when calculating removal of CO 2 from the atmosphere via silicate weathering.

Description: Water tracks are zones of high soil moisture that route water downslope over the ice table in polar environments. We present physical, hydrological, and geochemical evidence collected in Taylor Valley, McMurdo Dry Valleys, Antarctica, which suggests that previously unexplored water tracks are a significant component of this cold desert land system and constitute the major flow path in a cryptic hydrological system. Geological, geochemical, and hydrological analyses show that the water tracks are generated by a combination of infiltration from melting snowpacks, melting of pore ice at the ice table beneath the water tracks, and melting of buried segregation ice formed during winter freezing. The water tracks are enriched in solutes derived from chemical weathering of sediments as well as from dissolution of soil salts. The water tracks empty into ice-covered lakes, such as Lake Hoare, resulting in the interfingering of shallow groundwater solutions and glacier-derived stream water, adding complexity to the geochemical profile. Approximately four orders of magnitude less water is delivered to Lake Hoare by any given water track than is delivered by surface runoff from stream flow; however, the solute delivery to Lake Hoare by water tracks equals or may exceed the mass of solutes delivered from stream flow, making water tracks significant geochemical pathways. Additionally, solute transport is two orders of magnitude faster in water tracks than in adjacent dry or damp soil, making water tracks "salt superhighways" in the Antarctic cold desert. Accordingly, water tracks represent a new geological pathway that distributes water, energy, and nutrients in Antarctic Dry Valley, cold desert, soil ecosystems, providing hydrological and geochemical connectivity at the hillslope scale.

Description: Chemical analyses from 71 watersheds across an ~450 km transect in west-central Panama provide insight into controls on weathering and rates of chemical denudation and CO 2 consumption across an igneous arc terrain in the tropics. Stream and river compositions across this region of Panama are generally dilute, having a total dissolved solute value = 118 ± 91 mg/L, with bicarbonate and silica being the predominant dissolved species. Solute, stable isotope, and radiogenic isotope compositions are consistent with dissolution of igneous rocks present in Panama by meteoric precipitation, with geochemical signatures of rivers largely acquired in their upstream regions. Comparison of a headwater basin with its entire watershed observed considerably more runoff production from the high-elevation upstream portion of the catchment than in its much more spatially extensive downstream region. Rock alteration profiles document that weathering proceeds primarily by dissolution of feldspar and pyroxene, with base cations effectively leached in the following sequence: Na 〉 Ca 〉 Mg 〉 K. Control on water chemistry by bedrock lithology is indicated through a linking of elevated ([Na + K]/[Ca + Mg]) ratios in waters to a high proportion of catchment area silicic bedrock and low ratios to mafic bedrock. Sr-isotope ratios are dominated by basement-derived Sr, with only very minor, if any, contribution from other sources. Cation weathering of Ca sil + Mg sil + Na + K spans about an order in magnitude, from 3 to 32 tons/km 2 /yr. Strong positive correlations of chemical denudation and CO 2 consumption are observed with precipitation, mean watershed elevation, extent of land surface forest cover, and physical erosion rate.

Description: We document the age and extent of late Quaternary glaciofluvial processes in Garwood Valley, McMurdo Dry Valleys, Antarctica, using mapping, stratigraphy, geochronology, and geochemical analysis of sedimentary and ice deposits. Geomorphic and stratigraphic evidence indicates damming of the valley at its Ross Sea outlet by the expanded Ross Sea ice sheet during the Last Glacial Maximum. Damming resulted in development of a proglacial lake in Garwood Valley that persisted from late Pleistocene to mid-Holocene time, and in the formation of a multilevel delta complex that overlies intact, supraglacial till and buried glacier ice detached from the Ross Sea ice sheet. Radiocarbon dating of delta deposits and inferred relationships between paleolake level and Ross Sea ice sheet grounding line positions indicate that the Ross Sea ice sheet advanced north of Garwood Valley at ca. 21.5 ka and retreated south of the valley between 7.3 and 5.5 ka. Buried ice remaining in Garwood Valley has a similar geochemical fingerprint to grounded Ross Sea ice sheet material elsewhere in the southern Dry Valleys. The sedimentary sequence in Garwood Valley preserves evidence of glaciofluvial interactions and climate-driven hydrological activity from the end of the Pleistocene through the mid-Holocene, making it an unusually complete record of climate activity and paleoenvironmental conditions from the terrestrial Antarctic.