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  • 1
    Publication Date: 2011-10-01
    Description: We characterize oxygen isotope zoning within single titanite crystals from the Carthage-Colton mylonite zone (CCMZ), Adirondack Mountains (New York State, United States), by ion microprobe. Smooth gradients of {delta}18O, up to 0.6{per thousand} over 90 {micro}m, resulted from diffusive exchange of oxygen during cooling from peak metamorphic temperatures of 650-700 {degrees}C. Modeling of the observed profile indicates punctuated cooling rates of 30-60 {degrees}C/m.y. along the CCMZ, set within long periods of much slower cooling. These results indicate a previously unrecognized period of rapid cooling along the CCMZ that is interpreted to result from the post-Ottawan collapse of the Grenville mountain belt and exhumation of the central Adirondack Highlands at ca. 1050 Ma.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 2
    Publication Date: 2011-12-01
    Description: The thermal, mechanical, and chemical evolution of a sedimentary basin exerts important controls on porosity and permeability of reservoir rocks. Oxygen isotope ratios of individual diagenetic cements record evidence of this history, but cannot be analyzed accurately by conventional techniques. Recent improvements for in situ analysis by ion microprobe provide high precision and accuracy at a scale of 5-10 m. In combination with cathodoluminescence imaging, in situ analysis of {delta}18O (quartz) from the Cambrian Mount Simon Sandstone in the Illinois Basin (USA) reveals gradients within single overgrowths of as much as 7.7{per thousand}/50 m. While the inner portions of overgrowths remain approximately constant in {delta}18O across the basin, the {delta}18O of the rim becomes lower with depth. These data suggest that overgrowths formed during burial and heating, possibly with minimal changes in {delta}18O of pore fluids. If {delta}18O(H2O) = -3{per thousand}, the highest temperature calculated for the rim of an overgrowth is 107 {degrees}C at a paleodepth of 3.5 km. The variability both in average {delta}18O of overgrowths and patterns from individual overgrowths corresponds with a geotherm of 30 {degrees}C/km, and there is no evidence of quartz precipitation from higher temperature hydrothermal fluids.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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