Publication Date:
2023-02-21
Description:
In this experimental study, we documented the formation of strongly ultrabasic and ultracalcic melts through the interaction of melilititic and basanitic melts with calcite. Three strongly to moderately SiO2-undersaturated volcanic rocks from the Bohemian Massif (central Europe) were mixed with 10, 30, and 50 wt% CaCO3 and melted at 1100, 1200, and 1300 °C at 2 kbar to evaluate the maximum amount of carbonate that can be assimilated by natural ultrabasic melts at shallow depths. Experiments revealed a surprisingly complete dissolution of the CaCO3, only rarely reaching carbonate saturation, with typical liquidus phases represented by olivine, spinel, melilite, and clinopyroxene. Only in the runs with the most SiO2-undersaturated compositions did abundant monticellite form instead of clinopyroxene. For all starting mixtures, strongly ultrabasic (SiO2 down to 15.6 wt%), lime-rich (CaO up to 43.6 wt%), ultracalcic (CaO/Al2O3 up to ~27) melt compositions were produced at 1200 and 1300 °C, with up to ~25 wt% dissolved CO2. When present, quenched olivine showed much higher forsterite content (Fo95–97) than olivine in the natural samples (Fo79–85). The two major results of this study are (1) silicate-carbonatite melt compositions do not necessarily imply the existence of carbonatitic components in the mantle, because they are also produced during limestone assimilation, and (2) Fo-rich olivines cannot be used to infer any primitive character of the melt nor high potential temperature (Tp).
Description:
PRIN 2017 Project 20177BX42Z_005 and Ateneo La Sapienza grants (2019–2020)
Description:
Published
Description:
476–480
Description:
4V. Processi pre-eruttivi
Description:
JCR Journal
Keywords:
carbonatite
;
experimental petrology
;
ultrabasic melts
;
limestone assimilation
;
04.08. Volcanology
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
article
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