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  • 1
    Publication Date: 2017-05-17
    Description: Experimental studies have shown that temperature, pressure, sulfur fugacity (fS2), and oxygen fugacity (fO2) influence the Fe content of sphalerite. We present compositional in situ data on sphalerite from submarine volcanic-hosted massive sulfide (VHMS) ores of hydrothermal vents from different plate tectonic settings and with variable host-rock compositions. Sphalerite from sediment-hosted vents has systematically higher S contents and Fe/Zn ratios than those of the sediment-starved vents, reflecting an influence of fS2 and fO2 on Fe partitioning between fluid and sphalerite. The Fe/Zn ratios of sphalerite from sediment-starved vent systems apparently increase systematically with the fluid temperatures of the corresponding vents. We conclude that the composition of sphalerite can be used to (1) distinguish between sediment-hosted and sediment-starved hydrothermal processes, and (2) estimate minimum fluid temperatures of sphalerite precipitation from inactive sediment-starved hydrothermal vent sites and fossil VHMS deposits.
    Type: Article , PeerReviewed
    Format: text
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  • 2
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    GSA, Geological Society of America
    In:  Geology, 39 (12). pp. 1155-1158.
    Publication Date: 2017-05-18
    Description: The possibility of mining seafl oor massive sulfide deposits has stirred debate about the sustainable use of this new resource and whether commercial development is worth the risk. Among the outstanding questions is how many deposits might be accessible to deep-sea mining. More than 300 sites of high-temperature hydrothermal venting have been identifi ed since the discovery of black smokers, but signifi cant massive sulfide accumulation has been found at only 165 of these sites. Estimates of the total number of vent fields and associated mineral deposits, based on plume studies and deposit occurrence models, range from 500 to 5000. We have used new deposit occurrence data from 10,000 km of ridge, arc, and backarc spreading centers to estimate the amount of massive sulfide in the easily accessible neovolcanic zones of the global oceans. The total accumulation in these areas is estimated to be on the order of 6 × 108 tonnes, containing ~3 × 107 tonnes of copper and zinc. This is similar to the total discovered copper and zinc in Cenozoic massive sulfi de deposits mined on land but is insuffi cient to satisfy a growing global demand for these metals.
    Type: Article , PeerReviewed
    Format: text
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