ALBERT

Description: Ecological and taxonomic study of the mollusk-rich fauna of the Golfe d’Arguin, North Mauritania, investigates the various environmental influences affecting this tropical shelf. The upwelling of nutrient-rich waters leads to a highly productive environment under tropical conditions. The resulting mixed carbonate-siliciclastic sediment contains a large portion of calcareous components produced by heterotrophic organisms— e.g., mollusks, foraminifers, worms, barnacles—that are reworked on the open shelf. On the basis of mollusk assemblages, six taphocoenoses are defined, all being characterized by a mixed fauna of tropical (e.g., Tellina densestriata), subtropical (e.g., Macoma cumana) and temperate (e.g., Spisula subtruncata) species. Differences between the assemblages are related to the medium—grain size ranging from mud to gravel—that results from local hydrodynamic conditions and water depth. Among carbonate grains, Donax burnupi shells are very abundant in the swellexposed, northern part of the Golfe d’Arguin and reflect the tropical to subtropical, high-energy, and high-nutrient waters. Mollusk assemblages are demonstrated to be a sensitive tool for deciphering complex environmental conditions in sedimentary archives.

Description: Volcanic ash layers preserved within the geologic record represent precise time markers that correlate disparate depositional environments and enable the investigation of synchronous and/or asynchronous behaviors in Earth system and archaeological sciences. However, it is generally assumed that only exceptionally powerful events, such as supereruptions (≥450 km3 of ejecta as dense-rock equivalent; recurrence interval of ∼105 yr), distribute ash broadly enough to have an impact on human society, or allow us to address geologic, climatic, and cultural questions on an intercontinental scale. Here we use geochemical, age, and morphological evidence to show that the Alaskan White River Ash (eastern lobe; A.D. 833–850) correlates to the “AD860B” ash (A.D. 846–848) found in Greenland and northern Europe. These occurrences represent the distribution of an ash over 7000 km, linking marine, terrestrial, and ice-core records. Our results indicate that tephra from more moderate-size eruptions, with recurrence intervals of ∼100 yr, can have substantially greater distributions than previously thought, with direct implications for volcanic dispersal studies, correlation of widely distributed proxy records, and volcanic hazard assessment.

Description: North Atlantic climate is very sensitive to overturning in the Greenland-Iceland-Norwegian (GIN) Seas, overflow of deep water into the North Atlantic via the Greenland-Iceland-Scotland Ridge, and compensating northward flow of warm surface water. Physical models suggest that, in the absence of such overturning, oceanic heat transport to the Northern Hemisphere is reduced by as much as 50%, open North Atlantic sea-surface temperatures are as much as 6 °C lower, and the winter sea-ice limit migrates as far south as 45°N. Although simulations of the equilibrium climate state for the Last Glacial Maximum (LGM) suggest the absence of GIN Seas overflow, tests of these model results have been hampered by ambiguity in sedimentary proxies. Here we present a bottom-water neodymium (Nd) isotope record from the Rockall Trough to investigate changes in the sources of circulating waters over the past 43 k.y. Today and throughout most of the Holocene, water from the GIN Seas, along with water from the North Atlantic Current (NAC) entrained during overflow, sets the bottom-water Nd isotope composition of the Rockall Trough to ∼–10. Our results suggest the persistence of this scenario back into the LGM and beyond to mid-Marine Isotope Stage 3. Periodic radiogenic excursions punctuate the record at times of meltwater events, implying either continued GIN Seas overflow without NAC entrainment, or millennial-scale interruptions in the overflow and shoaling of Southern Source Water. We conclude that overflow was at least intermittently present during the LGM, if not continuous, and that the GIN Seas have remained a source of deep water to the North Atlantic during the last glacial cycle.

Description: Rhythmic bedding is a prominent feature of North American and European Upper Cretaceous pelagic carbonate sequences deposited in epicontinental and continental-edge settings. Such bedding rhythms can result from variations in carbonate productivity, terrigenous dilution, redox conditions, or bottom currents. Each type of bedding cycle is expressed differently in the stratigraphic record but probably was caused by climatic cycles that are linked to variations in the Earth's orbital characteristics (Milankovitch cycles). Thus, pelagic carbonates of Cretaceous age acted as particularly sensitive recorders of orbitally induced changes in climate. Documentation of these bedding rhythms will permit detailed chronostratigraphic and lithostratigraphic correlations and will further illuminate depositional processes in Upper Cretaceous carbonate sequences.

Description: Logs collected while drilling measured density in situ, through the accretionary prism and decollement zone of the northern Barbados Ridge. Consolidation tests relate void ratio (derived from density) to effective stress and predict a fluid pressure profile, assuming that the upper 100 m of the prism is at a hydrostatic pressure gradient. The calculated fluid pressure curve rises to 〉90% of lithostatic below thrusts in the prism, presumably due to the increase in overburden and lateral tectonic loading. Thin (0.5–2.0 m) intervals of anomalously low density and resistivity in the logs through the basal decollement zone suggest dilation and perhaps hydrofracturing. A peak in hydraulic head in the upper half of the decollement zone requires lateral influx of fluid, a conclusion consistent with previous geochemical studies. Although the calculated fluid-pressure profile is model dependent, its inherent character ties to major structural features.

Description: Gold colloids occur in black smoker fluids from the Niua South hydrothermal vent field, Lau Basin (South Pacific Ocean), confirming the long-standing hypothesis that gold may undergo colloidal transport in hydrothermal fluids. Six black smoker vents, varying in temperature from 250 °C to 325 °C, were sampled; the 325 °C vent was boiling at the time of sampling and the 250 °C fluids were diffusely venting. Native gold particles ranging from 〈50 nm to 2 μm were identified in 4 of the fluid samples and were also observed to precipitate on the sampler during collection from the boiling vent. Total gold concentrations (dissolved and particulate) in the fluid samples range from 1.6 to 5.4 nM in the high-temperature, focused flow vents. Although the gold concentrations in the focused flow fluids are relatively high, they are lower than potential solubilities prior to boiling and indicate that precipitation was boiling induced, with sulfide lost upon boiling to exsolution and metal sulfide formation. Gold concentrations reach 26.7 nM in the 250 °C diffuse flow sample, and abundant native gold particles were also found in the fluids and associated sulfide chimney and are interpreted to be a product of colloid accumulation and growth following initial precipitation upon boiling. These results indicate that colloid-driven precipitation as a result of boiling, the persistence of colloids after boiling, and the accumulation of colloids in diffuse flow fluids are important mechanisms for the enrichment of gold in seafloor hydrothermal systems.

Description: Central American arc volcanism shows strong regional trends in lava chemistry that result from differing slab contributions to arc melting. However, the mechanism that transfers slab-derived trace elements into the mantle wedge remains largely unknown. By using a dynamic model for mantle flow and fluid release, we model the fate of three different slab-fluid sources: sediment, ocean crust, and serpentinized mantle. In the open subarc system, sediments lose almost all their highly fluid mobile elements by ∼50 km depth, so other fluid sources are necessary to explain the slab signal in arc-lava compositions. The well-documented transition from lavas with a strong geochemical slab signature (i.e., high Ba/La ratios) found in Nicaragua to lavas with a weaker slab signature (i.e., low Ba/La ratios) erupted in Costa Rica seems easiest to produce by a higher fraction of serpentine-hosted fluids released from the deeply faulted, highly serpentinized lithosphere subducting beneath Nicaragua than from the less deeply faulted, thicker, amphibolitic oceanic-crust and oceanic-plateau lithosphere subducting beneath Costa Rica.

Description: Logs collected while drilling measured density in situ, through the accretionary prism and decollement zone of the northern Barbados Ridge. Consolidation tests relate void ratio (derived from density) to effective stress and predict a fluid pressure profile, assuming that the upper 100 m of the prism is at a hydrostatic pressure gradient. The calculated fluid pressure curve rises to 〉90% of lithostatic below thrusts in the prism, presumably due to the increase in overburden and lateral tectonic loading. Thin (0.5–2.0 m) intervals of anomalously low density and resistivity in the logs through the basal decollement zone suggest dilation and perhaps hydrofracturing. A peak in hydraulic head in the upper half of the decollement zone requires lateral influx of fluid, a conclusion consistent with previous geochemical studies. Although the calculated fluid-pressure profile is model dependent, its inherent character ties to major structural features.

Description: The interrelation between deformation styles and behavior of fluids in accretionary prisms is under debate, particularly the possibility that overpressuring within the basal decollement may enable mechanical decoupling of the prism from the subducting material. Anisotropy of magnetic susceptibility (AMS) data from sediments spanning the basal decollement of the Barbados accretionary prism show a striking progression across this structure that strongly supports the hypothesis that it is markedly overpressured. In the accretionary prism, above the decollement, the minimum AMS axes are subhorizontal and oriented nearly east-west, whereas the maximum AMS axes are oriented nearly north-south and shallowly inclined. At the top of the decollement, the minimum AMS axes orientations abruptly change to nearly vertical; this orientation is maintained throughout the decollement and in the underthrust sediments below. The AMS orientations in the prism sediments above the decollement are consistent with lateral shortening due to regional tectonic stress, as the minimum axes generally parallel the convergence vector of the subducting South American plate and the maximum axes are trench-parallel. Because the orientations of the AMS axes in deformed sediments usually parallel the orientations of the principal strains, the AMS results indicate that the incremental strain state in the Barbados prism is one dominated by subhorizontal shortening. In contrast, the AMS axes within and below the decollement are consistent with a strain state dominated by vertical shortening (compaction). This abrupt change in AMS orientations at the top of the decollement at Site 948 is a direct manifestation of mechanical decoupling of the off-scraped prism sediments from the underthrust sediments. The decoupling horizon occurs at the top of the decollement zone, coinciding with the location of flowing, high-pressure fluids.

Description: A new analysis of Deep Sea Drilling Project (DSDP) Leg 84 data demonstrates that the dominant process controlling the Guatemala margin tectonic evolution since ca. 25 Ma is subduction-erosion. Data from benthic foraminifera, assemblages from upper-slope DSDP Sites 568, 569, and 570 indicate long-term, progressive subsidence from upper to middle bathyal depths (600–1000 m) ca. 19 Ma to modern abyssal depths (〉2000 m). Rapid subsidence migrated landward starting at the Oligocene-Miocene boundary time under the current middle slope, where it increased sharply ca. 19 Ma, reached the current upper slope by ca. 15 Ma, and arrived at the uppermost slope ca. 2 Ma. Subsidence indicates crustal thinning by basal tectonic erosion of mass from the underside of the upper plate. Under the assumption that, in the Miocene, the morphology of the forearc was similar to that of today, landward migration of the trench was at a rate of 0.8–0.9 km/m.y. This linear rate corresponds to a tectonic erosion rate of the submerged forearc of 11.3–13.1 km3·m.y.−1·km−1. The evolution of arc magmatism and superfast spreading at the East Pacific Rise since early Miocene time may have caused slab shallowing and tectonic erosion that readjusted the forearc geometry.