ALBERT

Description: Highlights • Data set of Br and Cl emissions from 29 large CAVA eruptions (VEI 〉 5). • Melt inclusions are strongly enriched in chlorine and bromine compared to their respective matrix glasses. • Fluid partitioning is 4 to 68 times more efficient for Br than for Cl. • Subducted calcareous sediments are the major control on the arc-magmatic bromine contents. • Average CAVA eruption would add 368% EESC of recent annual loading to stratosphere. Abstract Large explosive volcanic eruptions inject gases, aerosols, and fine ashes into the stratosphere, potentially influencing climate and atmosphere composition on a global scale. Although the potential climate effect of chlorine (Cl) and bromine (Br) injections into the stratosphere is known, the global mass fluxes are poorly constrained. In this study we focus on the magmatic degassing systematics and budgets of Br and Cl, and on constraining the major sources of Br in a subduction setting. We therefore present a regional time series of Br and Cl emissions from 29 highly explosive eruptions throughout the Central American Volcanic Arc (CAVA), covering the last 200 ka, and a range of magmatic compositions and eruption magnitudes. We have measured Br and Cl in matrix glasses and melt inclusions using synchrotron radiation micro X-ray fluorescence spectrometry (SR micro-XRF) and electron microprobe, respectively. Melt inclusions of the CAVA tephras generally have higher Br (0.9 to 17.9 ppm) and Cl (770 to 3800 ppm) contents than the matrix glasses (0.39 to 1.5 ppm Br, 600 to 2800 ppm Cl). Moreover, the difference between maximum and minimum concentrations observed in melt inclusions of a given sample ranges between 9 and 90% of the maximum observed concentration for Br, and between 2 and 40% for Cl. Such intra-sample variations arise from variable pre-eruptive degassing of these halogens into a magmatic fluid phase. The relative loss of Br from the melt is 4 to 68 times higher than that of Cl. The masses of Br (2–1100 kt) and Cl (0.1 to 800 Mt) emitted by the eruptions generate instantaneous additions to the stratosphere potentially amounting to ∼6–5600% of the present-day stratospheric annual global loading of Equivalent Effective Stratospheric Chlorine. As the size of the stratospheric impact is primarily a function of eruption magnitude, we use magnitude-frequency relationships to estimate that eruptions adding ∼10% to resident EESC loading would occur every 〈40 years while every ∼200 years an eruption would double the EESC loading. Comparing the variations in Br and Cl concentrations and particularly minimum Cl/Br ratios in melt inclusions with geochemical trace-element proxies (e.g. U/La, Ba/Th) and lead-isotope compositions, which change along the arc in response to changing subduction conditions, we suggest that subducted calcareous sediment is a major source of magmatic Br but also infer an important role of fluids expelled from serpentinized subducted mantle. Extrapolation of CAVA volcanic Br emissions to the global subduction system thus needs to consider variations in the nature of subducted lithologies.

Description: Climatic consequences of the Young Toba Tuff (YTT) eruption about 73 ka are a crucial argument in the current discussion about the fate of modern humans, especially in Africa and Asia. Earth system model (ESM) simulations of the YTT eruption are used to investigate its regional climate impacts, in particular focusing on areas relevant to human evolutionary issues during that time. Uncertainties concerning the stratospheric sulphur emission for the YTT eruption are addressed by comparing ESM simulations of a 100 times Pinatubo-like eruption as an upper and a 3 times Pinatubo-like (Tambora) eruption as a lower estimate. Information about transient changes in vegetation types after the YTT eruption are obtained by forcing an offline dynamical global vegetation model with the climate anomalies simulated by the ESM under both glacial and interglacial background climate conditions. The simulated temperature changes in those areas that were inhabited by humans suggest thermal discomfort, but not a real challenge for survival. Precipitation is reduced in all regions during the first two years but recovers quickly thereafter. Some catchments in these regions (Ganges/Brahmaputra, Nile), experience an over-compensation in precipitation during the third to fifth post-eruption years which is also reflected in anomalously strong river runoffs. Change in vegetation composition may have created the biggest pressure on humans, who had to adapt to more open space with fewer trees and more grasses for some decades especially in the African regions. The strongest environmental impacts of the YTT eruption are simulated under interglacial background conditions suggesting that the climate effects of the YTT eruption did not impact humans on a major scale and for a period long enough to have dramatic consequences for their survival.