ALBERT

Description: The availability of the micronutrient iron (Fe) in surface waters determines primary production, N2 fixation, and microbial community structure in large parts of the world's ocean, and thus it plays an important role in ocean carbon and nitrogen cycles. Eastern boundary upwelling systems and the connected oxygen minimum zones (OMZs) are typically associated with elevated concentrations of redox-sensitive trace metals (e.g., Fe, manganese (Mn), and cobalt (Co)), with shelf sediments typically forming a key source. Over the last 5 decades, an expansion and intensification of OMZs has been observed and this trend is likely to proceed. However, it is unclear how trace-metal (TM) distributions and transport are influenced by decreasing oxygen (O2) concentrations. Here we present dissolved (d; 0.2 µm) TM data collected at seven stations along a 50 km transect in the Mauritanian shelf region. We observed enhanced concentrations of Fe, Co, and Mn corresponding with low O2 concentrations (

Description: Natural radioactive tracer-based assessments of basin-scale submarine groundwater discharge (SGD) are well developed. However, SGD takes place in different modes and the flow and discharge mechanisms involved occur over a wide range of spatial and temporal scales. Quantifying SGD while discriminating its source functions therefore remains a major challenge. However, correctly identifying both the fluid source and composition is critical. When multiple sources of the tracer of interest are present, failure to adequately discriminate between them leads to inaccurate attribution and the resulting uncertainties will affect the reliability of SGD solute loading estimates. This lack of reliability then extends to the closure of local biogeochemical budgets, confusing measures aiming to mitigate pollution.Here, we report a multi-tracer study to identify the sources of SGD, distinguish its component parts and elucidate the mechanisms of their dispersion throughout the Ria Formosa – a seasonally hypersaline lagoon in Portugal. We combine radon budgets that determine the total SGD (meteoric + recirculated seawater) in the system with stable isotopes in water (δ2H, δ18O), to specifically identify SGD source functions and characterize active hydrological pathways in the catchment. Using this approach, SGD in the Ria Formosa could be separated into two modes, a net meteoric water input and another involving no net water transfer, i.e., originating in lagoon water re-circulated through permeable sediments. The former SGD mode is present occasionally on a multi-annual timescale, while the latter is a dominant feature of the system. In the absence of meteoric SGD inputs, seawater recirculation through beach sediments occurs at a rate of  ∼  1.4  ×  106 m3 day−1. This implies that the entire tidal-averaged volume of the lagoon is filtered through local sandy sediments within 100 days ( ∼  3.5 times a year), driving an estimated nitrogen (N) load of  ∼  350 Ton N yr−1 into the system as NO3−. Land-borne SGD could add a further  ∼  61 Ton N yr−1 to the lagoon. The former source is autochthonous, continuous and responsible for a large fraction (59 %) of the estimated total N inputs into the system via non-point sources, while the latter is an occasional allochthonous source capable of driving new production in the system.

Description: Submarine groundwater discharge (SGD) has been implicated as a significant source of nutrients and potentially harmful substances to the coastal sea. Although the number of reported SGD sites has increased recently, their stratigraphical architecture and aquifer geometry are rarely investigated in detail. This study analyses a multifaceted dataset of offshore seismic sub-bottom profiles, multibeam and side-scan sonar images of the seafloor, radon measurements of seawater and groundwater, and onshore ground-penetrating radar and refraction seismic profiles in order to establish the detailed stratigraphical architecture of a high-latitude SGD site, which is connected to the Late-Pleistocene First Salpausselkä ice-marginal formation on the Hanko Peninsula in Finland. The studied location is characterized by a sandy beach, a sandy shore platform that extends 100–250 m seaward sloping gently to ca. 4 m water depth, and a steep slope to ca. 17 m water depth within ca. 50 m distance. The onshore radar and offshore seismic profiles are correlated based on unconformities, following the allostratigraphical approach. The aquifer is hosted in the distal sand-dominated part of a subaqueous ice-contact fan. It is interpreted that coarse sand interbeds and lenses in the distal fan deposits, and, potentially, sandy couplet layers in the overlying glaciolacustrine rhythmite, provide conduits for localized groundwater flow. The SGD takes place predominantly through pockmarks on the seafloor, which are documented on the shore platform slope by multibeam and side-scan sonar images. Elevated radon-222 activity concentrations measured 1 m above seafloor confirm SGD from two pockmarks in fine sand sediments, whereas there was no discharge from a third pockmark that was covered with a thin organic-rich mud layer. The thorough understanding of the local stratigraphy and the geometry and composition of the aquifer that have been acquired in this study are crucial for successful hydrogeological modelling and flux studies at the SGD site.

Description: Submarine groundwater discharge (SGD) has been implicated as a significant source of nutrients and other potentially harmful substances to coastal sea. Although the number of reported SGD sites has increased recently, their stratigraphical architecture and aquifer geometry are rarely investigated in detail. This study analyses a multifaceted dataset of offshore seismic sub-bottom profiles, multibeam and sidescan sonar images of the seafloor, radon measurements of seawater and groundwater, and onshore ground-penetrating radar and refraction seismic profiles in order to reconstruct the detailed stratigraphical architecture of a high-latitude SGD site, which is connected to the Late-Pleistocene First Salpausselkä ice-marginal formation on the Hanko Peninsula in Finland. The studied location is characterized by a sandy beach, a sandy shore platform that extends 100–250  m seaward sloping gently to ca. 4 m water depth, and a steep slope to ca. 17 m water depth within ca. 50 m distance. The onshore radar and offshore seismic profiles are correlated based on unconformities, following the allostratigraphical approach. The aquifer is hosted in the distal sand-dominated part of an ice-contact subaqueous fan foreset. It is interpreted that gravel and coarse sand interbeds and lenses in the distal foreset, and, potentially, coarse couplet layers in the overlying glaciolacustrine rhythmite, provide conduits for localized groundwater flow. The SGD takes place predominantly through pockmarks on the seafloor, which are documented on the shore platform slope by multibeam and sidescan sonar images. Elevated radon-222 activity concentrations measured 1 m above seafloor confirm SGD from two pockmarks with fine sand surface sediment, whereas there was no discharge from a third pockmark that was covered with a thin organic-rich mud layer. The thorough understanding of the local stratigraphy and the geometry and composition of the aquifer that have been acquired in this study are crucial for successful hydrogeological modeling and flux studies at the SGD site.

Description: Submarine groundwater discharge (SGD) has been implicated as a significant source of nutrients and other potentially harmful substances to coastal sea. Although the number of reported SGD sites has increased recently, their stratigraphical architecture and aquifer geometry are rarely investigated in detail. This study analyses a multifaceted dataset of offshore seismic sub-bottom profiles, multibeam and sidescan sonar images of the seafloor, radon measurements of seawater and groundwater, and onshore ground-penetrating radar and refraction seismic profiles in order to reconstruct the detailed stratigraphical architecture of a high-latitude SGD site, which is connected to the Late-Pleistocene First Salpausselkä ice-marginal formation on the Hanko Peninsula in Finland. The studied location is characterized by a sandy beach, a sandy shore platform that extends 100–250m seaward sloping gently to ca. 4m water depth, and a steep slope to ca. 17m water depth within ca. 50m distance. The onshore radar and offshore seismic profiles are correlated based on unconformities, following the allostratigraphical approach. The aquifer is hosted in the distal sand-dominated part of an ice-contact subaqueous fan foreset. It is interpreted that gravel and coarse sand interbeds and lenses in the distal foreset, and, potentially, coarse couplet layers in the overlying glaciolacustrine rhythmite, provide conduits for localized groundwater flow. The SGD takes place predominantly through pockmarks on the seafloor, which are documented on the shore platform slope by multibeam and sidescan sonar images. Elevated radon-222 activity concentrations measured 1m above seafloor confirm SGD from two pockmarks with fine sand surface sediment, whereas there was no discharge from a third pockmark that was covered with a thin organic-rich mud layer. The thorough understanding of the local stratigraphy and the geometry and composition of the aquifer that have been acquired in this study are crucial for successful hydrogeological modeling and flux studies at the SGD site.

Description: The availability of the micronutrient iron (Fe) in surface waters determines primary production, N2 fixation and microbial community structure in large parts of the world's ocean, and thus plays an important role in ocean carbon and nitrogen cycles. Eastern boundary upwelling systems and the connected oxygen minimum zones (OMZs) are typically associated with elevated concentrations of redox-sensitive trace metals (e.g. Fe, manganese (Mn) and cobalt (Co)), with shelf sediments typically forming a key source. Over the last five decades, an expansion and intensification of OMZs has been observed and this trend is likely to proceed. However, it is unclear how trace metal (TM) distributions and transport are influenced by decreasing oxygen (O2) concentrations. Here we present dissolved (d;  0.2 μm) TM data collected at 7 stations along a 50 km transect in the Mauritanian shelf region. We observed enhanced concentrations of Fe, Co and Mn corresponding with low O2 concentrations (