ALBERT

Description: Surface albedo is an essential variable to determine the Earth's surface energy budget, in particular for snow-covered areas where it is involved in one of the most powerful positive feedback loops of the climate system. In situ measurements of broadband and spectral albedo are therefore common. However they are subject to several artefacts. Here we investigate the sensitivity of spectral albedo measurements to surface slope, and we propose simple correction algorithms to retrieve the intrinsic albedo of a slope from measurements, as if it were flat. For this, we first derive the analytical equations relating albedo measured on a slope to intrinsic direct and diffuse albedo, the apportionment between diffuse and direct incoming radiation, and slope inclination and aspect. The theory accounts for two main slope effects. First, the slope affects the proportion of solar radiation intercepted by the surface relative to that intercepted by the upward-looking, horizontal, sensor. Second, the upward- and downward-looking sensors receive reduced radiation from the sky and the surface respectively and increased radiation from neighbouring terrain. Using this theory, we show that (i) slope has a significant effect on albedo (over 0.01) from as little as a ≈1∘ inclination, causing distortions of the albedo spectral shape; (ii) the first-order slope effect is sufficient to fully explain measured albedo up to ≈15∘, which we designate “small-slope approximation”; and (iii) for larger slopes, the theory depends on the neighbouring slope geometry and land cover, leading to much more complex equations. Next, we derive four correction methods from the small-slope approximation, to be used depending on whether (1) the slope inclination and orientation are known or not, (2) the snow surface is free of impurities or dirty, and (3) a single or a time series of albedo measurements is available. The methods applied to observations taken in the Alps on terrain with up to nearly 20∘ slopes prove the ability to recover intrinsic albedo with a typical accuracy of 0.03 or better. From this study, we derive two main recommendations for future field campaigns: first, sloping terrain requires more attention because it reduces the measurement accuracy of albedo even for almost invisible slopes (1–2∘). Second, while the correction of the slope effect is possible, it requires additional information such as the spectral diffuse and direction partitioning and if possible the actual slope inclination and aspect, especially when the absence of impurities can not be assumed.

Description: Most models simulating snow albedo assume a flat and smooth surface, neglecting surface roughness. However, the presence of macroscopic roughness leads to a systematic decrease in albedo due to two effects: (1) photons are trapped in concavities (multiple reflection effect) and (2) when the sun is low, the roughness sides facing the sun experience an overall decrease in the local incidence angle relative to a smooth surface, promoting higher absorption, whilst the other sides have weak contributions because of the increased incidence angle or because they are shadowed (called the effective-angle effect here). This paper aims to quantify the impact of surface roughness on albedo and to assess the respective role of these two effects, with (1) observations over varying amounts of surface roughness and (2) simulations using the new rough surface ray-tracing (RSRT) model, based on a Monte Carlo method for photon transport calculation. The observations include spectral albedo (400–1050 nm) over manually created roughness surfaces with multiple geometrical characteristics. Measurements highlight that even a low fraction of surface roughness features (7 % of the surface) causes an albedo decrease of 0.02 at 1000 nm when the solar zenith angle (θs) is larger than 50∘. For higher fractions (13 %, 27 % and 63 %), and when the roughness orientation is perpendicular to the sun, the decrease is of 0.03–0.04 at 700 nm and of 0.06–0.10 at 1000 nm. The impact is 20 % lower when roughness orientation is parallel to the sun. The observations are subsequently compared to RSRT simulations. Accounting for surface roughness improves the model observation agreement by a factor of 2 at 700 and 1000 nm (errors of 0.03 and 0.04, respectively) compared to simulations considering a flat smooth surface. The model is used to explore the albedo sensitivity to surface roughness with varying snow properties and illumination conditions. Both multiple reflections and the effective-angle effect have a greater impact with low specific surface area (SSA;

Description: For the last 25 years, CO-PDD (Cézeaux-Aulnat-Opme-puy de Dôme) has evolved to become a full instrumented platform for atmospheric research. It has received credentials as a national observing platform in France and is internationally recognized as a global station in the GAW (Global Atmosphere Watch) network. It is a reference site of European and national research infrastructures ACTRIS (Aerosol Cloud and Trace gases Research Infrastructure) and ICOS (Integrated Carbon Observing System). The site located on top of the puy de Dôme mountain (1465 m a.s.l.) is completed by additional sites located at lower altitudes and adding the vertical dimension to the atmospheric observations: Opme (660 m a.s.l.), Cézeaux (410 m), and Aulnat (330 m). The integration of different sites offers a unique combination of in situ and remote sensing measurements capturing and documenting the variability of particulate and gaseous atmospheric composition, but also the optical, biochemical, and physical properties of aerosol particles, clouds, and precipitations. Given its location far away from any major emission sources, its altitude, and the mountain orography, the puy de Dôme station is ideally located to sample different air masses in the boundary layer or in the free troposphere depending on time of day and seasons. It is also an ideal place to study cloud properties with frequent presence of clouds at the top in fall and winter. As a result of the natural conditions prevailing at the site and of the very exhaustive instrumental deployment, scientific studies at the puy de Dôme strongly contribute to improving knowledge in atmospheric sciences, including the characterization of trends and variability, the understanding of complex and interconnected processes (microphysical, chemical, biological, chemical and dynamical), and the provision of reference information for climate/chemistry models. In this context, CO-PDD is a pilot site to conduct instrumental development inside its wind tunnel for testing liquid and ice cloud probes in natural conditions, or in situ systems to collect aerosol and cloud. This paper reviews 25 years (1995–2020) of atmospheric observation at the station and related scientific research contributing to atmospheric and climate science.

Description: Aerosol particles are essential constituents of the Earth's atmosphere, impacting the earth radiation balance directly by scattering and absorbing solar radiation, and indirectly by acting as cloud condensation nuclei. In contrast to most greenhouse gases, aerosol particles have short atmospheric residence times, resulting in a highly heterogeneous distribution in space and time. There is a clear need to document this variability at regional scale through observations involving, in particular, the in situ near-surface segment of the atmospheric observation system. This paper will provide the widest effort so far to document variability of climate-relevant in situ aerosol properties (namely wavelength dependent particle light scattering and absorption coefficients, particle number concentration and particle number size distribution) from all sites connected to the Global Atmosphere Watch network. High-quality data from almost 90 stations worldwide have been collected and controlled for quality and are reported for a reference year in 2017, providing a very extended and robust view of the variability of these variables worldwide. The range of variability observed worldwide for light scattering and absorption coefficients, single-scattering albedo, and particle number concentration are presented together with preliminary information on their long-term trends and comparison with model simulation for the different stations. The scope of the present paper is also to provide the necessary suite of information, including data provision procedures, quality control and analysis, data policy, and usage of the ground-based aerosol measurement network. It delivers to users of the World Data Centre on Aerosol, the required confidence in data products in the form of a fully characterized value chain, including uncertainty estimation and requirements for contributing to the global climate monitoring system.

Description: Snow albedo schemes in regional climate models often lack a sophisticated radiation penetration scheme and generally compute only a broadband albedo. Here, we present the Spectral-to-NarrOWBand ALbedo module (SNOWBAL, version 1.2) to couple effectively a spectral albedo model with a narrowband radiation scheme. Specifically, the Two-streAm Radiative TransfEr in Snow model (TARTES) is coupled with the European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecast System (IFS), cycle 33R1, atmospheric radiation scheme based on the Rapid Radiation Transfer Model, which is embedded in the Regional Atmospheric Climate Model version 2.3p2 (RACMO2). This coupling allows to explicitly account for the effect of clouds, water vapor, snow impurities and snow metamorphism on albedo. Firstly, we present a narrowband albedo method to project the spectral albedos of TARTES onto the 14 spectral bands of the IFS shortwave radiation scheme using a representative wavelength (RW) for each band. Using TARTES and spectral downwelling surface irradiance derived with the DIScrete Ordinate Radiative Transfer atmospheric model, we show that RWs primarily depend on the solar zenith angle (SZA), cloud content and water vapor. Secondly, we compare the TARTES narrowband albedo, using offline RACMO2 results for south Greenland, with the broadband albedo parameterizations of Gardner and Sharp (2010), currently implemented in RACMO2, and the multi-layered parameterization of Kuipers Munneke et al. (2011, PKM). The actual absence of radiation penetration in RACMO2 leads on average to a higher albedo compared with TARTES narrowband albedo. Furthermore, large differences between the TARTES narrowband albedo and PKM and RACMO2 are observed for high SZA and clear-sky conditions, and after melt events when the snowpack is very inhomogeneous. This highlights the importance of accounting for spectral albedo and radiation penetration to simulate the energy budget of the Greenland ice sheet.

Description: This study aims to report and characterise the frequent new particle formation (NPF) events observed at the Maïdo observatory, Réunion, a Southern Hemisphere site located at 2150 m (a.s.l.) and surrounded by the Indian Ocean. From May 2014 to December 2015, continuous aerosol measurements were made using both a differential mobility particle sizer (DMPS) and an air ion spectrometer (AIS) to characterise the NPF events down to the lowest particle-size scale. Carbon monoxide (CO) and black carbon (BC) concentrations were monitored, as well as meteorological parameters, in order to identify the conditions that were favourable to the occurrence of nucleation in this specific environment. We point out that the annual NPF frequency average (65 %) is one of the highest reported so far. Monthly averages show a bimodal variation in the NPF frequency, with a maximum observed during transition periods (autumn and spring). A high yearly median particle growth rate (GR) of 15.16 nm h−1 is also measured showing a bimodal seasonal variation with maxima observed in July and November. Yearly medians of 2 and 12 nm particle formation rates (J2 and J12) are 0.858 and 0.508 cm−3 s−1, respectively, with a seasonal variation showing a maximum during winter, that correspond to low temperature and RH typical of the dry season, but also to high BC concentrations. We show that the condensation sink exceeds a threshold value (1.04×10−3 s−1) with a similar seasonal variation than the one of the NPF event frequency, suggesting that the occurrence of the NPF process might be determined by the availability of condensable vapours, which are likely to be transported together with pre-existing particles from lower altitudes.

Description: In the present paper, we expose how we boosted the performance of a commercial condensation particle counter (CPC) model TSI 3010 to detect particles as small as 1.5 nm while preserving the robustness and reliability of the original instrument. The TSI 3010 was selected because of our deep knowledge of its internal workings and its large incorporated butanol reservoir that allows continuous operation for several hours without refill, which is well suited to airborne operation. Aside from this, it is still pretty easy to buy instruments from the TSI 3010 family from companies that specialize in used scientific instrument retail. The CPC described in this study is called B3010 hereafter, where the “B” stands for boosted. We provide an evaluation of its performances down to 1 nm using standard calibration methods and comparisons with ultrafine CPCs (TSI 3025 and TSI 3776), as well as with its original version. One important application of the B3010 is for high-altitude measurement stations and airborne studies, the instrument's detection efficiency was quantified for various inlet flow rates and pressures.

Description: The occurrence of frequent aerosol nucleation and growth events in the Arctic during summertime may impact the region's climate through increasing the number of cloud condensation nuclei in the Arctic atmosphere. Measurements of aerosol size distributions and aerosol composition were taken during the summers of 2015 and 2016 at Eureka and Alert on Ellesmere Island in Nunavut, Canada. These results provide a better understanding of the frequency and spatial extent of elevated Aitken mode aerosol concentrations as well as of the composition and sources of aerosol mass during particle growth. Frequent appearances of small particles followed by growth occurred throughout the summer. These particle growth events were observed beginning in June with the melting of the sea ice rather than with the polar sunrise, which strongly suggests that influence from the marine boundary layer was the primary cause of the events. Correlated particle growth events at the two sites, separated by 480 km, indicate conditions existing over large scales play a key role in determining the timing and the characteristics of the events. In addition, aerosol mass spectrometry measurements were used to analyze the size-resolved chemical composition of aerosols during two selected growth events. It was found that particles with diameters between 50 and 80 nm (physical diameter) during these growth events were predominately organic with only a small sulfate contribution. The oxidation of the organics also changed with particle size, with the fraction of organic acids increasing with diameter from 80 to 400 nm. The growth events at Eureka were observed most often when the temperature inversion between the sea and the measurement site (at 610 m a.s.l.) was non-existent or weak, presumably creating conditions with low aerosol condensation sink and allowing fresh marine emissions to be mixed upward to the observatory's altitude. While the nature of the gaseous precursors responsible for the growth events is still poorly understood, oxidation of dimethyl sulfide alone to produce particle-phase sulfate or methanesulfonic acid was inconsistent with the measured aerosol composition, suggesting the importance of other gas-phase organic compounds condensing for particle growth.

Description: The microwave radiometers (MWRs) on board the European Remote Sensing Satellites 1 and 2 (ERS-1 and ERS-2) and Envisat provide a continuous time series of brightness temperature observations between 1991 and 2012. Here we report on a new total column water vapour (TCWV) and wet tropospheric correction (WTC) dataset that builds on this time series. We use a one-dimensional variational approach to derive TCWV from MWR observations and ERA-Interim background information. A particular focus of this study lies on the intercalibration of the three different instruments, which is performed using constraints on liquid water path (LWP) and TCWV. Comparing our MWR-derived time series of TCWV against TCWV derived from Global Navigation Satellite System (GNSS) we find that the MWR-derived TCWV time series is stable over time. However, observations potentially affected by precipitation show a degraded performance compared to precipitation-free observations in terms of the accuracy of retrieved TCWV. An analysis of WTC shows further that the retrieved WTC is superior to purely ERA-Interim-derived WTC for all satellites and for the entire time series. Even compared to the European Space Agency's (ESA) operational WTC retrievals, which incorporate in addition to MWR additional observational data, the here-described dataset shows improvements in particular for the mid-latitudes and for the two earlier satellites, ERS-1 and ERS-2. The dataset is publicly available under doi:10.5676/DWD_EMIR/V001 (Bennartz et al., 2016).

Description: In this study we characterized the performance of three new particle counters able to detect particles smaller than 3 nm during the Helsinki condensation particle counter (CPC) workshop in summer 2016: the Aerosol Dynamics Inc. (ADI; Berkeley, USA) versatile water condensation particle counter (vWCPC), TSI 3777 nano enhancer (TSI Inc., Shoreview, USA) and modified and boosted TSI 3010-type CPC from Université Blaise Pascal called a B3010. The performance of all CPCs was first measured with charged tungsten oxide test particles at temperature settings which resulted in supersaturation low enough to not detect any ions produced by a radioactive source. Due to similar measured detection efficiencies, additional comparison between the 3777 and vWCPC were conducted using electrically neutral tungsten oxide test particles and with positively charged tetradodecylammonium bromide. Furthermore, the detection efficiencies of the 3777 and vWCPC were measured with boosted temperature settings yielding supersaturation which was at the onset of homogeneous nucleation for the 3777 or confined within the range of liquid water for the ADI vWCPC. Finally, CPC-specific tests were conducted to probe the response of the 3777 to various inlet flow relative humidities, of the B3010 to various inlet flow rates and of the vWCPC to various particle concentrations. For the 3777 and vWCPC the measured 50 % detection diameters (d50s) were in the range of 1.3–2.4 nm for the tungsten oxide particles, depending on the particle charging state and CPC temperature settings, between 2.5 and 3.3 nm for the organic test aerosol, and in the range of 3.2–3.4 nm for tungsten oxide for the B3010.