ALBERT

Description: As construction and building material, natural stone has a great potential to promote the commercial activities of certain European regions. Such is the case of Castilla y León in Spain, where many different rocks, ranging from sedimentary to metamorphic and igneous, are commercialized for building purposes. However, to be able to compete in a market subject to an economic crisis, highly exacerbated in the construction sector, and to compete with the lower prices offered by emerging countries, the issue would be to make the Spanish offer more attractive. Here we propose a complete characterization of rocks regarding their radiological properties, which are related to their mineralogy and geochemistry. Rocks emit natural radioactivity and the presence of Rn and its decay products in dwellings has become an important issue in North America and Europe owing to its relationship with the carcinogenic effects of this gas. Although most of the rocks studied are within the European Norm 112 for Radiology Protection I values accepted in the Euratom Basic Safety Standards Directive (accepted value I≤1; average for sedimentary rock: I=0.22, SD 0.14; average for metamorphic rocks: I=0.70, SD 0.48; average for igneous rock: I=0.86, SD 0.22), the inclusion of a proper radiological characterization in the list of characteristics would guarantee quality and safety in their use in comparison with products lacking this information. Some natural stones have been demonized for the potential exhalation of natural radioactivity and the different parameters used should be addressed in a more systematic way.

Description: As construction and building material, natural stone has a great potential to promote the commercial activities of certain European regions. Such is the case of Castilla y León in Spain, where many different rocks, ranging from sedimentary to metamorphic and igneous, are commercialized for building purposes. However, to be able to compete in a market subject to an economic crisis, highly exacerbated in the construction sector, and to compete with the lower prices offered by emerging countries, the issue would be to make the Spanish offer more attractive. Here we propose a complete characterization of rocks regarding their radiological properties, which are related to their mineralogy and geochemistry. Rocks emit natural radioactivity, and the presence of Rn and its decay products in dwellings has become an important issue in North America and Europe owing to its relationship with the carcinogenic effects of this gas. Although most of the studied rocks comply with the I parameter proposed in the European Norm 112 for Radiological Protection (accepted value I ≤ 1; average for sedimentary rock: I = 0.22, SD 0.14; average for metamorphic rocks: I = 0.70, SD 0.48; average for igneous rock: I = 0.86, SD 0.22), the inclusion of a proper radiological characterization in the list of characteristics would guarantee quality and safety in their use in comparison with products lacking this information. Some natural stones have been demonized for the potential exhalation of natural radioactivity, and the different parameters used should be addressed in a more systematic way.

Description: In the area of Trujillo (Extremadura, Spain) we have found a variety of striking bluish and secondary yellow granites outcropping within the Plasenzuela pluton. They are all quarried under different names and are characterized by leucocratic minerals in which a bluish phosphate is dispersed throughout the rock. Their physical and mechanical properties make these granites a perfect option for most applications as ornamental rocks. Within the pluton the radiological background is fairly homogeneous, with no significant differences between the gamma ray fluxes of the different facies. U (6.4 ± 0.51 ppm), Th (2.9 ± 0.47 ppm) and K2O (4.32 ± 0.26%) contents determined in the laboratory by gamma-ray spectrometry from representative samples are in good accordance with fast in situ measurements carried out with the same technique and also with conventional chemical analysis. Estimated activities for K-40, Ra-226 and Th-232 were, on average, 1022 ± 36 Bq kg−1, 84 ± 9 Bq kg−1 and 6.8 ± 1.6 Bq kg−1. On the basis of these results, the I index of EU technical document 112 was determined, with an average result of 0.66 ± 0.03. This suggests that the rock can be used with no restrictions for all types of construction purposes. Striking differences were observed between the blue facies and the yellow facies in radon exhalation tests from crushed material (0.03 Bq kg−1 vs. 0.20 Bq kg−1). Since both granites have similar uranium contents (6.3 ppm and 6.5 ppm, respectively), these results can probably be explained in terms of important differences in the mineralogical distribution of this chemical element, radon emanation being enhanced in the yellow facies. However, due to the ordinary use as ornamental stone, the yellow facies does not present a radiological risk in terms of excess effective dose due to internal exposure to radon.

Description: The Montesinho Natural Park (MNP), with an area of about 750 km2, is one of the largest protected areas in Portugal. Since its inauguration as a natural park in 1979, geological and geomorphological aspects have not been taken into consideration in its nature conservation policies. Over the last few years, this deficit has been compensated with an assessment of its geomorphological heritage. The assessment was made possible due to a research project on the geological heritage of the natural parks of north-eastern Portugal.The assessment method propagated herein proposes a clear definition of three types of geomorphosites: Single places, geomorphological areas or panoramic viewpoints. Further, it proposes as two-staged approach to assessment with inventory compilation followed by quantification of value. Inventory compilation, for example, involves the identification and qualitative assessment of potential geomorphosites and, therefore, the selection and characterization of geomorphosites. The quantification stage includes the numerical assessment of sites and their final ranking. The values are numerically assessed using selected criteria. The implementation of this approach in the MNP led to the identification of 154 potential geomorphosites, of which only 26 were selected after the qualitative assessment or characterisation process. The numerical assessment of the sites and their ranking allowed a final selection of 13 sites for public use.

Description: Carboniferous siliciclastic and silicic magmatic rocks from the Santa Susana–São Cristovão and Cabrela regions contain valuable information regarding the timing of synorogenic processes in SW Iberia. In this region of the Ossa-Morena Zone (OMZ), late Carboniferous terrigenous strata (i.e., the Santa Susana Formation) unconformably overlie early Carboniferous marine siliciclastic deposits alternating with volcanic rocks (i.e., the Toca da Moura volcano-sedimentary complex). Lying below this intra-Carboniferous unconformity, the Toca da Moura volcano-sedimentary complex is intruded and overlain by the Baleizão porphyry. Original sensitive high-resolution ion microprobe (SHRIMP) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb zircon are presented in this paper, providing chronostratigraphic and provenance constraints since available geochronological information is scarce and only biostratigraphic ages are currently available for the Santa Susana–São Cristovão region. Our findings and the currently available detrital zircon ages from Paleozoic terranes of SW Iberia (Pulo do Lobo Zone – PLZ – South Portuguese Zone – SPZ – and OMZ) were jointly analyzed using the K–S test and multidimensional scaling (MDS) diagrams to investigate provenance. The marine deposition is constrained to the age range of ca. 335–331 Ma (Visean) by new U–Pb data for silicic tuffs from the Toca da Moura and Cabrela volcano-sedimentary complexes. The Baleizão porphyry, intrusive in the Toca da Moura volcano-sedimentary complex, yielded a crystallization age of ca. 318 Ma (Bashkirian), providing the minimum age for the overlying intra-Carboniferous unconformity. A comparison of detrital zircon populations from siliciclastic rocks of the Cabrela and Toca de Moura volcano-sedimentary complexes of the OMZ suggests that they are derived from distinct sources more closely associated with the SPZ and PLZ than the OMZ. Above the intra-Carboniferous unconformity, the Santa Susana Formation is the result of the recycling of distinct sources located either on the Laurussian side (SPZ and PLZ) or Gondwanan side (OMZ) of the Rheic suture zone. The best estimate of the crystallization age of a granite cobble which was found in a conglomerate from the Santa Susana Formation yielded ca. 303 Ma (Kasimovian–Gzhelian), representing the maximum depositional age for the terrestrial strata. The intra-Carboniferous unconformity seems to represent a stratigraphic gap of approximately 12–14 Myr, providing evidence of the rapid post-accretion and collision uplift of the Variscan orogenic belt in SW Iberia (i.e., the OMZ, PLZ, and SPZ).

Description: Isoprene-derived secondary organic aerosol (iSOA) is a significant contributor to organic carbon (OC) in some forested regions, such as tropical rainforests and the Southeastern US. However, its contribution to organic aerosol in urban areas that have high levels of anthropogenic pollutants is poorly understood. In this study, we examined the formation of anthropogenically influenced iSOA during summer in Beijing, China. Local isoprene emissions and high levels of anthropogenic pollutants, in particular NOx and particulate SO42-, led to the formation of iSOA under both high- and low-NO oxidation conditions, with significant heterogeneous transformations of isoprene-derived oxidation products to particulate organosulfates (OSs) and nitrooxy-organosulfates (NOSs). Ultra-high-performance liquid chromatography coupled to high-resolution mass spectrometry was combined with a rapid automated data processing technique to quantify 31 proposed iSOA tracers in offline PM2.5 filter extracts. The co-elution of the inorganic ions in the extracts caused matrix effects that impacted two authentic standards differently. The average concentration of iSOA OSs and NOSs was 82.5 ng m−3, which was around 3 times higher than the observed concentrations of their oxygenated precursors (2-methyltetrols and 2-methylglyceric acid). OS formation was dependant on both photochemistry and the sulfate available for reactive uptake, as shown by a strong correlation with the product of ozone (O3) and particulate sulfate (SO42-). A greater proportion of high-NO OS products were observed in Beijing compared with previous studies in less polluted environments. The iSOA-derived OSs and NOSs represented 0.62 % of the oxidized organic aerosol measured by aerosol mass spectrometry on average, but this increased to ∼3 % on certain days. These results indicate for the first time that iSOA formation in urban Beijing is strongly controlled by anthropogenic emissions and results in extensive conversion to OS products from heterogenous reactions.

Description: In this paper we evaluate new retrievals of the deuterium content of water vapor from the Aqua Atmospheric InfraRed Sounder (AIRS), with aircraft measurements of HDO and H2O from the ObseRvations of Aerosols above Clouds and their intEractionS (ORACLES) field mission. Single-footprint AIRS radiances are processed with an optimal estimation algorithm that provides vertical profiles of the HDO∕H2O ratio, characterized uncertainties and instrument operators (i.e., averaging kernel matrix). These retrievals are compared to vertical profiles of the HDO∕H2O ratio from the Oregon State University Water Isotope Spectrometer for Precipitation and Entrainment Research (WISPER) on the ORACLES NASA P-3B Orion aircraft. Measurements were taken over the southeastern Atlantic Ocean from 31 August to 25 September 2016. HDO∕H2O is commonly reported in δD notation, which is the fractional deviation of the HDO∕H2O ratio from the standard reference ratio. For collocated measurements, the satellite instrument operator (averaging kernels and a priori constraint) is applied to the aircraft profile measurements. We find that AIRS δD bias relative to the aircraft is well within the estimated measurement uncertainty. In the lower troposphere, 1000 to 800 hPa, AIRS δD bias is −6.6 ‰ and the root-mean-square (rms) deviation is 20.9 ‰, consistent with the calculated uncertainty of 19.1 ‰. In the mid-troposphere, 800 to 500 hPa, AIRS δD bias is −6.8 ‰ and rms 44.9 ‰, comparable to the calculated uncertainty of 25.8 ‰.

Description: In this work we analyze the ionograms obtained by the recent digisonde installed in Santa Maria (29.7∘ S, 53.7∘ W, dip angle = −37∘), Brazil, to calculate the monthly averages of the F2 layer critical frequency (foF2), its peak height (hmF2), and the E-region critical frequency (foE) acquired during geomagnetically quiet days from September 2017 to August 2018. The monthly averages are compared to the 2016 version of the International Reference Ionosphere (IRI) model predictions in order to study its performance close to the center of the South America Magnetic Anomaly (SAMA), which is a region particularly important for high-frequency (HF) ground-to-satellite navigation signals. The foF2 estimated with the Consultative Committee International Radio (CCIR) and International Union of Radio Science (URSI) options makes good predictions throughout the year, whereas, for hmF2, it is recommended to use the SHU-2015 option instead of the other available options (AMTB2013 and BSE-1979). The IRI-2016 model outputs for foE and the observations presented very good agreement.

Description: The project MarParCloud (Marine biological production, organic aerosol Particles and marine Clouds: a process chain) aims to improve our understanding of the genesis, modification and impact of marine organic matter (OM) from its biological production, to its export to marine aerosol particles and, finally, to its ability to act as ice-nucleating particles (INPs) and cloud condensation nuclei (CCN). A field campaign at the Cape Verde Atmospheric Observatory (CVAO) in the tropics in September–October 2017 formed the core of this project that was jointly performed with the project MARSU (MARine atmospheric Science Unravelled). A suite of chemical, physical, biological and meteorological techniques was applied, and comprehensive measurements of bulk water, the sea surface microlayer (SML), cloud water and ambient aerosol particles collected at a ground-based and a mountain station took place. Key variables comprised the chemical characterization of the atmospherically relevant OM components in the ocean and the atmosphere as well as measurements of INPs and CCN. Moreover, bacterial cell counts, mercury species and trace gases were analyzed. To interpret the results, the measurements were accompanied by various auxiliary parameters such as air mass back-trajectory analysis, vertical atmospheric profile analysis, cloud observations and pigment measurements in seawater. Additional modeling studies supported the experimental analysis. During the campaign, the CVAO exhibited marine air masses with low and partly moderate dust influences. The marine boundary layer was well mixed as indicated by an almost uniform particle number size distribution within the boundary layer. Lipid biomarkers were present in the aerosol particles in typical concentrations of marine background conditions. Accumulation- and coarse-mode particles served as CCN and were efficiently transferred to the cloud water. The ascent of ocean-derived compounds, such as sea salt and sugar-like compounds, to the cloud level, as derived from chemical analysis and atmospheric transfer modeling results, denotes an influence of marine emissions on cloud formation. Organic nitrogen compounds (free amino acids) were enriched by several orders of magnitude in submicron aerosol particles and in cloud water compared to seawater. However, INP measurements also indicated a significant contribution of other non-marine sources to the local INP concentration, as (biologically active) INPs were mainly present in supermicron aerosol particles that are not suggested to undergo strong enrichment during ocean–atmosphere transfer. In addition, the number of CCN at the supersaturation of 0.30 % was about 2.5 times higher during dust periods compared to marine periods. Lipids, sugar-like compounds, UV-absorbing (UV: ultraviolet) humic-like substances and low-molecular-weight neutral components were important organic compounds in the seawater, and highly surface-active lipids were enriched within the SML. The selective enrichment of specific organic compounds in the SML needs to be studied in further detail and implemented in an OM source function for emission modeling to better understand transfer patterns, the mechanisms of marine OM transformation in the atmosphere and the role of additional sources. In summary, when looking at particulate mass, we see oceanic compounds transferred to the atmospheric aerosol and to the cloud level, while from a perspective of particle number concentrations, sea spray aerosol (i.e., primary marine aerosol) contributions to both CCN and INPs are rather limited.

Description: With the mining of polymetallic nodules from the deep-sea seafloor once more evoking commercial interest, decisions must be taken on how to most efficiently regulate and monitor physical and community disturbance in these remote ecosystems. Image-based approaches allow non-destructive assessment of the abundance of larger fauna to be derived from survey data, with repeat surveys of areas possible to allow time series data collection. At the time of writing, key underwater imaging platforms commonly used to map seafloor fauna abundances are autonomous underwater vehicles (AUVs), remotely operated vehicles (ROVs) and towed camera “ocean floor observation systems” (OFOSs). These systems are highly customisable, with cameras, illumination sources and deployment protocols changing rapidly, even during a survey cruise. In this study, eight image datasets were collected from a discrete area of polymetallic-nodule-rich seafloor by an AUV and several OFOSs deployed at various altitudes above the seafloor. A fauna identification catalogue was used by five annotators to estimate the abundances of 20 fauna categories from the different datasets. Results show that, for many categories of megafauna, differences in image resolution greatly influenced the estimations of fauna abundance determined by the annotators. This is an important finding for the development of future monitoring legislation for these areas. When and if commercial exploitation of these marine resources commences, robust and verifiable standards which incorporate developing technological advances in camera-based monitoring surveys should be key to developing appropriate management regulations for these regions.