ALBERT

Description: Horizontal and vertical variability of water vapor is omnipresent in the tropics, but its interaction with cloudiness poses challenges for weather and climate models. In this study we compare airborne lidar measurements from a summer and a winter field campaign in the tropical Atlantic with high-resolution simulations to analyze the water vapor distributions in the trade wind regime, its covariation with cloudiness, and their representation in simulations. Across model grid spacing from 300 m to 2.5 km, the simulations show good skill in reproducing the water vapor distribution in the trades as measured by the lidar. An exception to this is a pronounced moist model bias at the top of the shallow cumulus layer in the dry winter season which is accompanied by a humidity gradient that is too weak at the inversion near the cloud top. The model's underestimation of water vapor variability in the cloud and subcloud layer occurs in both seasons but is less pronounced than the moist model bias at the inversion. Despite the model's insensitivity to resolution from hecto- to kilometer scale for the distribution of water vapor, cloud fraction decreases strongly with increasing model resolution and is not converged at hectometer grid spacing. The observed cloud deepening with increasing water vapor path is captured well across model resolution, but the concurrent transition from cloud-free to low cloud fraction is better represented at hectometer resolution. In particular, in the wet summer season the simulations with kilometer-scale resolution overestimate the observed cloud fraction near the inversion but lack condensate near the observed cloud base. This illustrates how a model's ability to properly capture the water vapor distribution does not necessarily translate into an adequate representation of shallow cumulus clouds that live at the tail of the water vapor distribution.

Description: We evaluated how ranges of four endemic and non-endemic aquatic ostracode species changed in response to long-term (glacial–interglacial cycles) and abrupt climate fluctuations during the last 155 kyr in the northern Neotropical region. We employed two complementary approaches, fossil records and species distribution models (SDMs). Fossil assemblages were obtained from sediment cores PI-1, PI-2, PI-6 and Petén-Itzá 22-VIII-99 from the Petén Itzá Scientific Drilling Project, Lake Petén Itzá, Guatemala. To obtain a spatially resolved pattern of (past) species distribution, a downscaling cascade is employed. SDMs were reconstructed for the last interglacial (∼120 ka), the last glacial maximum (∼22 ka) and the middle Holocene (∼6 ka). During glacial and interglacial cycles and marine isotope stages (MISs), modelled paleo-distributions and paleo-records show the nearly continuous presence of endemic and non-endemic species in the region, suggesting negligible effects of long-term climate variations on aquatic niche stability. During periods of abrupt ecological disruption such as Heinrich Stadial 1 (HS1), endemic species were resilient, remaining within their current areas of distribution. Non-endemic species, however, proved to be more sensitive. Modelled paleo-distributions suggest that the geographic range of non-endemic species changed, moving southward into Central America. Due to the uncertainties involved in the downscaling from the global numerical to the highly resolved regional geospatial statistical modelling, results can be seen as a benchmark for future studies using similar approaches. Given relatively moderate temperature decreases in Lake Petén Itzá waters (∼5 ∘C) and the persistence of some aquatic ecosystems even during periods of severe drying in HS1, our data suggest (1) the existence of micro-refugia and/or (2) continuous interaction between central metapopulations and surrounding populations, enabling aquatic taxa to survive climate fluctuations in the northern Neotropical region.

Description: Chemical composition, size distributions, and degree of oligomerization of secondary organic aerosol (SOA) from α-pinene (C10H16) ozonolysis were investigated for low-temperature conditions (223 K). Two types of experiments were performed using two simulation chambers at the Karlsruhe Institute of Technology: the Aerosol Preparation and Characterization (APC) chamber, and the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) chamber. Experiment type 1 simulated SOA formation at upper tropospheric conditions: SOA was generated in the AIDA chamber directly at 223 K at 61 % relative humidity (RH; experiment termed “cold humid”, CH) and for comparison at 6 % RH (experiment termed “cold dry”, CD) conditions. Experiment type 2 simulated SOA uplifting: SOA was formed in the APC chamber at room temperature (296 K) and  40 %) of adducts (molecules with more than 10 carbon atoms) of α-pinene oxidation products were observed. For type 2 experiments with higher α-pinene concentrations and warm SOA formation temperature (296 K), larger particles (∼ 500 nm dva) with smaller mass fractions of adducts (

Description: Secondary organic aerosol (SOA) formation has been investigated as a function of temperature and humidity for the ozone-initiated reaction of the two monoterpenes α-pinene (243–313 K) and limonene (253–313 K) using the 84.5 m3 aerosol chamber AIDA. This paper gives an overview of the measurements done and presents parameters specifically useful for aerosol yield calculations. The ozonolysis reaction, selected oxidation products and subsequent aerosol formation were followed using several analytical techniques for both gas and condensed phase characterisation. The effective densities of the SOA were determined by comparing mass and volume size distributions to (1.25±0.10) g cm−3 for α-pinene and (1.3±0.2) g cm−3 for limonene. The detailed aerosol dynamics code COSIMA-SOA proved to be essential for a comprehensive evaluation of the experimental results and for providing parameterisations directly applicable within atmospheric models. The COSIMA-assisted analysis succeeded to reproduce the observed time evolutions of SOA total mass, number and size distributions by adjusting the following properties of two oxidation product proxies: individual yield parameters (αi), partitioning coefficients (Ki), vapour pressures (pi) and effective accommodation coefficients (γi). For these properties temperature dependences were derived and parameterised. Vapour pressures and partitioning coefficients followed classical Clausius-Clapeyron temperature dependences. From this relationship enthalpies of vaporisation were derived for the two more and less volatile product proxies of α-pinene: (59±8) kJ mol−1 and (24±9) kJ mol−1, and limonene: (55±14) kJ mol−1 and (25±12) kJ mol−1. The more volatile proxy components had a notably low enthalpy of vaporisation while the less volatile proxy components gave enthalpies of vaporisation comparable with those of typical products from α-pinene oxidation, e.g. pinonaldehyde and pinonic acid.

Description: This paper presents the results of mass spectrometric investigations of the OH-initiated oxidative aging of α-pinene SOA under simulated tropospheric conditions at the large aerosol chamber facility AIDA, Karlsruhe Institute of Technology. In particular, the OH-initiated oxidation of pure pinic and pinonic acid, two well-known oxidation products of α-pinene, was investigated. Two complementary analytical techniques were used, on-line atmospheric pressure chemical ionization/mass spectrometry (APCI/MS) and filter sampling followed by liquid chromatography/mass spectrometry (LC/ESI-MS). The results show that 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA), a very low volatile α-pinene SOA product and a tracer compound for terpene SOA, is formed from the oxidation of pinonic acid and that this oxidation takes place in the gas phase. This finding is confirmed by temperature-dependent aging experiments on whole SOA formed from α-pinene, in which the yield of MBTCA scales with the pinonic acid fraction in the gas phase. Based on the results, several feasible gas-phase radical mechanisms are discussed to explain the formation of MBTCA from OH-initiated pinonic acid oxidation.

Description: The aim of this study was to investigate oxidation of SOA formed from ozonolysis of α-pinene and limonene by hydroxyl radicals. This paper focuses on changes of particle volatility, using a Volatility Tandem DMA (VTDMA) set-up, in order to explain and elucidate the mechanism behind atmospheric ageing of the organic aerosol. The experiments were conducted at the AIDA chamber facility of Karlsruhe Institute of Technology (KIT) in Karlsruhe and at the SAPHIR chamber of Forchungzentrum Jülich (FZJ) in Jülich. A fresh SOA was produced from ozonolysis of α-pinene or limonene and then aged by enhanced OH exposure. As an OH radical source in the AIDA-chamber the ozonolysis of tetramethylethylene (TME) was used while in the SAPHIR-chamber the OH was produced by natural light photochemistry. A general feature is that SOA produced from ozonolysis of α-pinene and limonene initially was rather volatile and becomes less volatile with time in the ozonolysis part of the experiment. Inducing OH chemistry or adding a new portion of precursors made the SOA more volatile due to addition of new semi-volatile material to the aged aerosol. The effect of OH chemistry was less pronounced in high concentration and low temperature experiments when lower relative amounts of semi-volatile material were available in the gas phase. Conclusions drawn from the changes in volatility were confirmed by comparison with the measured and modelled chemical composition of the aerosol phase. Three quantified products from the α-pinene oxidation; pinonic acid, pinic acid and methylbutanetricarboxylic acid (MBTCA) were used to probe the processes influencing aerosol volatility. A major conclusion from the work is that the OH induced ageing can be attributed to gas phase oxidation of products produced in the primary SOA formation process and that there was no indication on significant bulk or surface reactions. The presented results, thus, strongly emphasise the importance of gas phase oxidation of semi- or intermediate-volatile organic compounds (SVOC and IVOC) for atmospheric aerosol ageing.

Description: The aim of this study was to investigate oxidation of SOA formed from ozonolysis of α-pinene and limonene by hydroxyl radicals. This paper focuses on changes of particle volatility, using a Volatility Tandem DMA (VTDMA) set-up, in order to explain and elucidate the mechanism behind atmospheric ageing of the organic aerosol. The experiments were conducted at the AIDA chamber facility of KIT in Karlsruhe and at the SAPHIR chamber of FZJ in Jülich. A fresh SOA was produced from ozonolysis of α-pinene or limonene and then aged by enhanced OH exposure. As an OH-radical source in the AIDA-chamber the ozonolysis of tetramethylethylene (TME) was used while in the SAPHIR-chamber the OH was produced by natural light photochemistry. A general feature is that SOA produced from ozonolysis of α-pinene and limonene initially were rather volatile and becomes less volatile with time in the ozonolysis part of the experiment. Inducing OH chemistry or adding a new portion of precursors made the SOA more volatile due to addition of new semi-volatile material to the aged aerosol. The effect of OH chemistry was less pronounced in high concentration and low temperature experiments when lower relative amounts of semi-volatile material were available in the gas phase. Conclusions drawn from the changes in volatility were confirmed by comparison with the measured and modelled chemical composition of the aerosol phase. Three quantified products from the α-pinene oxidation; pinonic acid, pinic acid and methylbutanetricarboxylic acid (MBTCA) were used to probe the processes influencing aerosol volatility. A major conclusion from the work is that the OH induced ageing can be attributed to gas phase oxidation of products produced in the primary SOA formation process and that there was no indication on significant bulk or surface reactions. The presented results, thus, strongly emphasise the importance of gas phase oxidation of semi- or intermediate-volatile organic compounds (SVOC and IVOC) for atmospheric aerosol ageing processing.

Description: To investigate initial sea-ice growth in open water, we carried out an ice-tank study with three different setups: grease ice grew in experiments with waves and in experiments with a current and wind, while nilas formed in a quiescent experimental setup. In this paper we focus on the differences in bulk salinity, solid fraction and thickness between these two ice types. We find that the bulk salinity of the grease-ice layer remains almost constant until the ice starts to consolidate. In contrast, the bulk salinity of nilas is in the first hours of ice formation well described by a linear decrease of 2.1 g kg−1 h−1 independent of air temperature. Such rapid decrease in bulk salinity can be understood qualitatively in the light of a Rayleigh number, the maximum of which is reached while the nilas is still less than 1 cm thick. Comparing three different methods to measure solid fraction in grease ice based on (a) salt conservation, (b) mass conservation and (c) energy conservation, we find that the method based on salt conservation does not give reliable results if the salinity of the interstitial water is approximated as being equal to the salinity of the upper water layer. Instead the increase in salinity of the interstitial water during grease-ice formation must be taken into account. We find that the solid fraction of grease ice is relatively constant with values of 0.25, whereas it increases to values as high as 0.5 as soon as the grease ice consolidates at its surface. In contrast, the solid fraction of nilas increases continuously in the first hours of ice formation. The ice thickness is found to be twice as large in the first 24 h of ice formation in the setup with a current and wind compared to the other two setups, since the wind keeps parts of the water surface ice free. The development of the ice thickness can be reproduced well with simple, one dimensional models given only the air temperature or the ice surface temperature.

Description: We investigate initial sea-ice growth in an ice-tank study by freezing an NaCl solution of about 29 g kg−1 in three different setups: grease ice grew in experiments with waves and in experiments with a current and wind, while nilas formed in a quiescent experimental setup. In this paper we focus on the differences in bulk salinity, solid fraction and thickness between these two ice types. The bulk salinity of the grease-ice layer in our experiments remained almost constant until the ice began to consolidate. In contrast, the initial bulk-salinity evolution of the nilas is well described by a linear decrease of about 2.1 g kg−1 h−1 independent of air temperature. This rapid decrease can be qualitatively understood by considering a Rayleigh number that became maximum while the nilas was still less than 1 cm thick. Comparing three different methods to measure solid fraction in grease ice based on (a) salt conservation, (b) mass conservation and (c) energy conservation, we find that the method based on salt conservation does not give reliable results if the salinity of the interstitial water is approximated as being equal to the salinity of the underlying water. Instead the increase in salinity of the interstitial water during grease-ice formation must be taken into account. In our experiments, the solid fraction of grease ice was relatively constant with values of 0.25, whereas it increased to values as high as 0.50 as soon as the grease ice consolidated at its surface. In contrast, the solid fraction of the nilas increased continuously in the first hours of ice formation and reached an average value of 0.55 after 4.5 h. The spatially averaged ice thickness was twice as large in the first 24 h of ice formation in the setup with a current and wind compared to the other two setups, since the wind kept parts of the water surface ice free and therefore allowed for a higher heat loss from the water. The development of the ice thickness can be reproduced well with simple, one dimensional models that only require air temperature or ice surface temperature as input.

Description: The analysis and management of flood risk commonly focuses on surface water floods, because these types are often associated with high economic losses due to damage to buildings and settlements. The rising groundwater as a secondary effect of these floods induces additional damage, particularly in the basements of buildings. Mostly, these losses remain underestimated, because they are difficult to assess, especially for the entire building stock of flood-prone urban areas. For this purpose an appropriate methodology has been developed and lead to a groundwater damage simulation model named GRUWAD. The overall methodology combines various engineering and geoinformatic methods to calculate major damage processes by high groundwater levels. It considers a classification of buildings by building types, synthetic depth-damage functions for groundwater inundation as well as the results of a groundwater-flow model. The modular structure of this procedure can be adapted in the level of detail. Hence, the model allows damage calculations from the local to the regional scale. Among others it can be used to prepare risk maps, for ex-ante analysis of future risks, and to simulate the effects of mitigation measures. Therefore, the model is a multifarious tool for determining urban resilience with respect to high groundwater levels.