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  • 1
    Publication Date: 2015-03-04
    Description: We have developed an enhanced analytical procedure to measure organic acids and methyl esters in fine aerosol with much greater specificity and sensitivity than previously available. This capability is important because of these species and their low concentrations, even in highly polluted atmospheres like Beijing, China. The procedure first separates the acids and esters from the other organic compounds with anion-exchange solid- phase extraction (SPE), then, quantifies them by gas chromatography coupled with mass spectrometry. This allows us to accurately quantify the C4-C11 dicarboxylic and the C8-C30 monocarboxylic acids. Then the acids are separated from the esters on an aminopropyl SPE cartridge, whose weak retention isolates and enriches the acids from esters prevents the fatty acids and dimethyl phthalate from being overestimated. The resulting correlations between the aliphatic acids and fatty acid methyl esters (FAMEs) suggest that FAMEs had sources similar to those of the carboxylic acids, or were formed by esterifying carboxylic acids, or that aliphatic acids were formed by hydrolyzing FAMEs. In all, 17 aromatic acids were identified and quantified using this procedure coupled with gas chromatography-tandem mass spectrometry, including the five polycyclic aromatic hydrocarbon (PAH) acids 2-naphthoic, biphenyl-4-carboxylic, 9-oxo-9H-fluorene-1-carboxylic, biphenyl-4,4´-dicarboxylic, and phenanthrene-1-carboxylic acid, plus 1,8-naphthalic anhydride. Correlations between the PAH-acids and the dicarboxylic and aromatic acids indicated that the first three acids and 1,8-naphthalic anhydride were mainly secondary, the last two mainly primary.
    Electronic ISSN: 1867-8610
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 2
    Publication Date: 2013-12-13
    Description: Coastal diatoms are often exposed to macronutrient (N and P) and Fe enrichment. However, how these exposures influence on Fe biogeochemical cycle and then on diatom interspecific competition is unknown. In this study, two non-toxic coastal diatoms, Skeletonema costatum and Thalassosira weissflogii were exposed to N, P, and Fe enrichment for four-day. The growth of algae was co-controlled by macronutrient and Fe species (Fe (III)-EDTA, Fe(OH)3, dissolved, colloidal, and particulate Fe from culture medium). The influence of Fe species on algal cell density was more significant than macronutrient. When S. costatum coexisted with T. weissflogii, their cell density ratios were ranged between 5.57–7.03 times, indicating that S. costatum was more competitive than T. weissflogii. There were not significant correlation between cell density ratio and iron requirement, including iron adsorption and absorption per cell, iron adsorption and absorption by all algal cells. As Fe complexing ligands, algal exudates can promote diatom growth itself and such promotion on S. costatum was more obvious than that on T. weissflogii. Iron species was a key determinant on interspecific competition of coastal diatom, and the degree of bioavailability was described as follows: dissolved iron from own exudates 〉 colloidal iron from own exudates 〉 particulate iron from own exudates 〉 particulate iron from another algal exudates 〉 colloidal iron from another algal exudates 〉 dissolved iron from another algal exudates 〉 Fe (III)-EDTA〉 Fe (OH)3.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 3
    Publication Date: 2014-09-19
    Description: High-resolution ocean color observation offers an opportunity to investigate the oceanic small-scale processes. In this study, The Medium Resolution Imaging Spectrometer (MERIS) daily 300 m data are used to study small-scale processes in the western South China Sea. It is indicated that the cyclonic eddies with horizontal scales of the order of 10 km are frequently observed during upwelling season of each year over 2004–2009. These small-scale eddies are generated in the vicinity of the southern front of the cold tongue, and then propagate eastward with a speed of approximately 12 cm s−1. This propagation speed is consistent with the velocity of the western boundary current. As a result, the small-scale eddies keep rotating high levels of the phytoplankton away from the coastal areas, resulting in the accumulation of phytoplankton in the interior of the eddies. The generation of the small-scale eddies may be associated with strengthening of the relative movement between the rotation speed of the anticylconic mesoscale eddies and the offshore transport. With the increases of the normalized rotation speed of the anticyclonic mesoscale eddies relative to the offshore transport, the offshore current become meander under the impacts of the anticyclonic mesoscale eddies. The meandered cold tongue and instability front may stimulate the generation of the small-scale eddies. Unidirectional uniform wind along cold tongue may also contribute to the formation of the small-scale eddies.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 4
    Publication Date: 2014-05-28
    Description: A hydrochemical and isotopic study was conducted in Subei Lake Basin, northwestern China, to identify the origin and geochemical evolution of groundwater. Water samples were collected, major ions and stable isotopes (δ18O, δ D) were analyzed. In terms of hydrogeological conditions in study area, groundwater can be classified into three types: the Quaternary groundwater, the shallow Cretaceous groundwater, the deep Cretaceous groundwater. Piper diagram and correlation analysis were used to reveal the hydrochemical characteristics of water resources. The dominant water type of lake water was Na-Cl type, which was controlled by strong evaporation and recharge from overland flow and groundwater; the predominant hydrochemical types for groundwater were Ca-HCO3, Na-HCO3, and mixed Ca · Na · Mg-HCO3 types, the groundwater chemistry is mainly controlled by dissolution/precipitation of anhydrite, gypsum, halite and calcite. The dedolomitization and cation exchange are also important factors. Rock weathering is confirmed to play a leading role in the mechanisms responsible for the chemical compositions of groundwater. The stable isotopic values of oxygen and hydrogen in groundwater are close to the local meteoric water line, showing that groundwater is of meteoric origin. The deep Cretaceous groundwater is depleted in heavy isotopes, compared to shallow Cretaceous groundwater. The hydrogen and oxygen isotopes signatures in deep Cretaceous groundwater may show a paleorecharge effect that the deep Cretaceous groundwater was recharged during a geologic period when the climate was wetter and colder than today. Due to strong evaporation effect and dry climatic conditions, heavy isotopes are more enriched in lake water than groundwater. The hydrochemical and isotopic information of utmost importance has been provided to decision-makers by the present study so that a sustainable water resources management policy could be designed for the Ordos energy base.
    Print ISSN: 1812-2108
    Electronic ISSN: 1812-2116
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 5
    Publication Date: 2015-01-28
    Description: A series of changes in groundwater systems caused by groundwater exploitation in energy base have been of great concern to hydrogeologists. The research aims to identify the origin and geochemical evolution of groundwater in the Subei Lake basin under the influence of human activities. Water samples were collected, and major ions and stable isotopes (δ18O, δD) were analyzed. In terms of hydrogeological conditions and the analytical results of hydrochemical data, groundwater can be classified into three types: the Quaternary groundwater, the shallow Cretaceous groundwater and the deep Cretaceous groundwater. Piper diagram and correlation analysis were used to reveal the hydrochemical characteristics of water resources. The dominant water type of the lake water was Cl-Na type, which was in accordance with hydrochemical characteristics of inland salt lakes; the predominant hydrochemical types for groundwater were HCO3–Ca, HCO3–Na and mixed HCO3–Ca–Na–Mg types. The groundwater chemistry is mainly controlled by dissolution/precipitation of anhydrite, gypsum, halite and calcite. The dedolomitization and cation exchange are also important factors. Rock weathering is confirmed to play a leading role in the mechanisms responsible for the chemical composition of groundwater. The stable isotopic values of oxygen and hydrogen in groundwater are close to the local meteoric water line, indicating that groundwater is of modern local meteoric origin. Unlike significant differences in isotopic values between shallow groundwater and deep groundwater in the Habor Lake basin, shallow Cretaceous groundwater and deep Cretaceous groundwater have similar isotopic characteristics in the Subei Lake basin. Due to the evaporation effect and dry climatic conditions, heavy isotopes are more enriched in lake water than in groundwater. The low slope of the regression line of δ18O and δD in lake water could be ascribed to a combination of mixing and evaporation under conditions of low humidity. Comparison of the regression line for δ18O and δD showed that lake water in the Subei Lake basin contains more heavily isotopic composition than that in the Habor Lake basin, indicating that lake water in the discharge area has undergone stronger evaporation than lake water in the recharge area. Hydrochemical and isotopic information of utmost importance has been provided to decision makers by the present study so that a sustainable groundwater management strategy can be designed for the Ordos energy base.
    Print ISSN: 1027-5606
    Electronic ISSN: 1607-7938
    Topics: Geography , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 2015-12-10
    Description: An anthropogenic emission inventory for Asia is developed for the years 2008 and 2010 to support the Model Inter-Comparison Study for Asia (MICS-Asia) and the Task Force on Hemispheric Transport of Air Pollution (TF HTAP) projects by a mosaic of up-to-date regional emission inventories. Emissions are estimated for all major anthropogenic sources in 30 countries and regions in Asia. We conducted detailed comparisons of different regional emission inventories and incorporated the best-available ones for each region into the mosaic inventory at a uniform spatial and temporal resolution. We estimate the total Asian emissions of ten species in 2010 as follows: 51.3 Tg SO2, 52.1 Tg NOx, 336.6 Tg CO, 67.0 Tg NMVOC (non-methane volatile organic compounds), 28.8 Tg NH3, 31.7 Tg PM10, 22.7 Tg PM2.5, 3.5 Tg BC, 8.3 Tg OC and 17.3 Pg CO2. Emissions from China and India dominate the emissions of Asia for most of the species. We also estimated Asian emissions in 2006 using the same methodology of MIX. The relative change rates of Asian emissions for the period of 2006–2010 are estimated as follows: −8.0 % for SO2, +19 % for NOx, +4 % for CO, +15 % for NMVOC, +2 % for NH3, −3 % for PM10, −2 % for PM2.5, +6 % for BC, +2 % for OC and +20 % for CO2. Model-ready speciated NMVOC emissions for SAPRC-99 and CB05 mechanisms were developed following a profile-assignment approach. Monthly gridded emissions at a spatial resolution of 0.25° × 0.25° are developed and can be accessed from http://www.meicmodel.org/dataset-mix.
    Electronic ISSN: 1680-7375
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2015-10-26
    Description: Rapid increases in pollutant emissions in conjunction with stagnant meteorological conditions result in haze pollution in China. Recent frequent haze in China has attracted worldwide attention. Here we show a relationship between the haze events and Tibetan Plateau (TP)'s environment and climate changes. Based on observational data taken over recent decades, we identify central-eastern China (CEC) as a climatological large-scale "susceptible region" of frequent haze, which is harbored by the TP with its impact on mid-latitude westerly winds. The observational and modeling studies demonstrate that the interannual variations in the thermal forcing of TP are positively correlated with the incidences of wintertime haze over CEC. Further analysis indicates that the TP-climate warming induced changes in atmospheric circulation driving frequent haze events in CEC. The frequent haze occurrences in CEC are consistent with decreasing winter monsoon winds, intensifying downward air flows and increasing atmospheric stability in the lower troposphere over the CEC in association with upstream plateau's thermal anomalies. Therefore, variations of haze in China are related to mechanical and thermal forcing by the TP. Our results also suggest that implications of the large TP-topography for environment and climate changes should be taken into account for air pollution mitigation policies in China.
    Electronic ISSN: 1680-7375
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 8
    Publication Date: 2015-09-07
    Description: We present a new method to quantify NOx emissions and corresponding atmospheric lifetimes from OMI NO2 observations together with ECMWF wind fields without further model input for sources located in polluted background. NO2 patterns under calm wind conditions are used as proxy for the spatial patterns of NOx emissions, and the effective atmospheric NOx lifetime is determined from the change of spatial patterns measured at larger wind speeds. Emissions are subsequently derived from the NO2 mass above background integrated around the source of interest. Lifetimes and emissions are estimated for 17 power plants and 53 cities located in non-mountainous regions across China and the US. The derived lifetimes for non-mountainous sites are 3.8 ± 1.0 h on average with ranges of 1.8 to 7.5 h. The derived NOx emissions show generally good agreement with bottom-up inventories for power plants and cities. Global inventory significantly underestimated NOx emissions in Chinese cities, most likely due to uncertainties associated with downscaling approaches.
    Electronic ISSN: 1680-7375
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2015-07-09
    Description: This paper, which focuses on emissions from China's coal-fired power plants during 1990–2010, is the second in a series of papers that aims to develop high-resolution emission inventory for China. This is the first time that emissions from China's coal-fired power plants were estimated at unit level for a 20 year period. This inventory is constructed from a unit-based database compiled in this study, named the China coal-fired Power plant Emissions Database (CPED), which includes detailed information on the technologies, activity data, operation situation, emission factors, and locations of individual units and supplements with aggregated data where unit-based information is not available. Between 1990 and 2010, compared to a 479 % growth in coal consumption, emissions from China's coal-fired power plants increased by 56, 335 and 442 % for SO2, NOx and CO2, respectively, and decreased by 23 % for PM2.5. Driven by the accelerated economy growth, large power plants were constructed throughout the country after 2000, resulting in dramatic growth in emissions. Growth trend of emissions has been effective curbed since 2005 due to strengthened emission control measures including the installation of flue-gas desulfurization (FGD) systems and the optimization of the generation fleet mix by promoting large units and decommissioning small ones. Compared to previous emission inventories, CPED significantly improved the spatial resolution and temporal profile of power plant emission inventory in China by extensive use of underlying data at unit level. The new inventory developed in this study will enable a close examination for temporal and spatial variations of power plant emissions in China and will help to improve the performances of chemical transport models by providing more accurate emission data.
    Electronic ISSN: 1680-7375
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2015-11-03
    Description: We found that ambient and laboratory-generated secondary organic aerosols (SOA) form substantial amounts of OH radicals upon interaction with liquid water, which can be explained by the decomposition of organic hydroperoxides. The molar OH yield from SOA formed by ozonolysis of terpenes (α-pinene, β-pinene, limonene) is ~ 0.1 % upon extraction with pure water and increases to ~ 1.5 % in the presence of Fe2+ ions due to Fenton-like reactions. Our findings imply that the chemical reactivity and aging of SOA particles is strongly enhanced upon interaction with water and iron. In cloud droplets under dark conditions, SOA decomposition can compete with the classical H2O2 Fenton reaction as the source of OH radicals. Also in the human respiratory tract, the inhalation and deposition of SOA particles may lead to a substantial release of OH radicals, which may contribute to oxidative stress and play an important role in the adverse health effects of atmospheric aerosols.
    Electronic ISSN: 1680-7375
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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