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  • Copernicus  (13)
  • 157, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U. S. Department of Energy  (1)
  • National Academy of Sciences  (1)
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  • 1
    Publication Date: 2015-08-12
    Description: Global ocean acidification is caused primarily by the ocean’s uptake of CO2 as a consequence of increasing atmospheric CO2 levels. We present observations of the oceanic decrease in pH at the basin scale (50°S–36°N) for the Atlantic Ocean over two decades (1993–2013). Changes in pH associated with the uptake of...
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 2
    Publication Date: 2014-01-27
    Description: Significant changes in the overturning circulation of the Mediterranean Sea has been observed during the last few decades, the most prominent phenomena being the Eastern Mediterranean Transient (EMT) in the early 1990s and the Western Mediterranean Transition (WMT) during the mid-2000s. During both of these events unusually large amounts of deep water were formed, and in the case of the EMT, the deep water formation area shifted from the Adriatic to the Aegean Sea. Here we synthesize a unique collection of transient tracer (CFC-12, SF6 and tritium) data from nine cruises conducted between 1987 and 2011 and use these data to determine temporal variability of Mediterranean ventilation. We also discuss biases and technical problems with transient tracer-based ages arising from their different input histories over time; particularly in the case of time-dependent ventilation. We observe a period of low ventilation in the deep eastern (Levantine) basin after it was ventilated by the EMT so that the age of the deep water is increasing with time. In the Ionian Sea, on the other hand, we see evidence of increased ventilation after year 2001, indicating the restarted deep water formation in the Adriatic Sea. This is also reflected in the increasing age of the Cretan Sea deep water and decreasing age of Adriatic Sea deep water since the end of the 1980s. In the western Mediterranean deep basin we see the massive input of recently ventilated waters during the WMT. This signal is not yet apparent in the Tyrrhenian Sea, where the ventilation seems to be fairly constant since the EMT. Also the western Alboran Sea does not show any temporal trends in ventilation.
    Print ISSN: 1812-0784
    Electronic ISSN: 1812-0792
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 3
    Publication Date: 2013-08-20
    Description: The Mediterranean Sea has a fast overturning circulation and the deep water masses are well ventilated in comparison to the deep waters of the world ocean. Significant changes in the overturning circulation has been observed during the last few decades, the most prominent phenomena being the Eastern Mediterranean Transient (EMT) in the early 1990s and the Western Mediterranean Transit (WMT) near the mid of the decade following. During both of these events unusually large amounts of deep water were formed, and in the case of the EMT, the deep water formation area shifted from the Adriatic to the Aegean Sea. This variability is important to understand and to monitor, because ventilation is the main process to propagate surface perturbations, such as uptake of anthropogenic CO2, into the ocean interior. Here we synthesize a unique collection of transient tracer (CFC-12, SF6 and tritium) data from nine cruises conducted between 1987 and 2011 and use these data to determine temporal variability of Mediterranean ventilation. We also discuss biases and technical problems with transient tracer-based ages arising from their different input histories over time; particularly in the case of time-dependent ventilation. We observe a period of stagnation in the deep eastern (Levantine) basin after it was ventilated by the EMT so that the age of the deep water is increasing with time. In the Ionian Sea, on the other hand, we see evidence of increased ventilation after year 2001, indicating the restarted deep water formation in the Adriatic Sea. This is also reflected in the increasing age of the Cretan Sea deep water and decreasing age of Adriatic Sea deep water since the end of the 1980s. In the western Mediterranean deep basin we see the massive input of recently ventilated waters during the WMT. This signal is not yet apparent in the Tyrrhenian Sea, where the ventilation seems to be fairly constant since the EMT. Also the western Alboran Sea does not show any temporal trends in ventilation.
    Print ISSN: 1812-0806
    Electronic ISSN: 1812-0822
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 4
    Publication Date: 2016-01-19
    Description: For version 2 of the Global Ocean Data Analysis Project (GLODAPv2) we collated data from 724 scientific cruises covering the global ocean: data assembled in the previous efforts GLODAPv1.1 (Global Ocean Data Analysis Project version 1.1) in 2004, CARINA (CARbon IN the Atlantic) in 2009/10, and PACIFICA (PACIFic ocean Interior CArbon) in 2013, and an additional 168 cruises. Twelve core parameters (salinity, oxygen, macronutrients, seawater CO2 chemistry parameters and halogenated transient tracers) have been subjected to extensive quality control including systematic evaluation of biases between cruises. The data are available in two formats: (i) as submitted but updated to WOCE exchange format whenever required, and (ii) as a merged and calibrated data product. In the latter, adjustments have been applied to remove significant biases, respecting occurrences of any known or likely time trends. Adjustments determined by previous efforts have been re-evaluated. Hence, GLODAPv2 is not a simple merge of previous collections and some new data, but represents a unique, internally consistent data product. The original data and their documentation and doi codes are available at the Carbon Dioxide Information Analysis Center (http://cdiac.ornl.gov/oceans/GLODAPv2/). This site also provides access to the calibrated data product, which is provided as a single global file or 4 regional ones: the Arctic, Atlantic, Indian, and Pacific Oceans, under the doi:10.3334/CDIAC/OTG.NDP093_GLODAPv2. The product files also include significant ancillary and approximated data. The latter were obtained either by interpolation of, or by calculation from, measured data. This paper documents the GLODAPv2 history, methods, and products, including a broad overview of the secondary quality control results. The magnitude of and reasoning behind the adjustments are available on a per cruise and parameter basis in an online Adjustment Table.
    Electronic ISSN: 1866-3591
    Topics: Geosciences
    Published by Copernicus
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  • 5
    Publication Date: 2009-07-09
    Description: Water column data of carbon and carbon-relevant parameters have been collected and merged into a new database called CARINA (CARbon IN the Atlantic). In order to provide a consistent data set, all data have been examined for systematic biases and adjusted if necessary (secondary quality control (QC)). The CARINA data set is divided into three regions: the Arctic/Nordic Seas, the Atlantic region and the Southern Ocean. Here we present the CFC data for the Atlantic region, including the chlorofluorocarbons CFC-11, CFC-12 and CFC-113 as well as carbon tetrachloride (CCl4). The methods applied for the secondary quality control, a crossover analyses, the investigation of CFC ratios in the ocean and the CFC surface saturation are presented. Bases on the results, the CFC data of some cruises are adjusted by a certain factor or given a "poor" quality flag.
    Electronic ISSN: 1866-3591
    Topics: Geosciences
    Published by Copernicus
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  • 6
    Publication Date: 2009-08-20
    Description: Water column data of carbon and carbon-relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruise data sets in the Arctic, Atlantic and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon IN the Atlantic). The data have gone through rigorous quality control procedures to assure the highest possible quality and consistency. The data for the pertinent parameters in the CARINA database were objectively examined in order to quantify systematic differences in the reported values, i.e. secondary quality control. Systematic biases found in the data have been corrected in the data products, i.e. three merged data files with measured, calculated and interpolated data for each of the three CARINA regions, i.e. Arctic, Atlantic and Southern Ocean. Ninety-eight of the cruises in the CARINA database were conducted in the Atlantic Ocean, defined here as the region south of the Greenland-Iceland-Scotland Ridge and north of about 30° S. Here we present an overview of the Atlantic Ocean synthesis of the CARINA data and the adjustments that were applied to the data product. We also report details of the secondary QC for salinity for this data set. Procedures of quality control – including crossover analysis between stations and inversion analysis of all crossover data – are briefly described. Adjustments to salinity measurements were applied to the data from 10 cruises in the Atlantic Ocean region. Based on our analysis we estimate the internal accuracy of the CARINA-ATL salinity data to be 4.1 ppm. With these adjustments the CARINA database is consistent both internally as well as with GLODAP data, an oceanographic data set based on the World Hydrographic Program in the 1990s (Key et al., 2004), and is now suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation.
    Electronic ISSN: 1866-3591
    Topics: Geosciences
    Published by Copernicus
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  • 7
    Publication Date: 2010-02-01
    Description: Water column data of carbon and carbon-relevant hydrographic and hydrochemical parameters from 188 previously non-publicly available cruise data sets in the Arctic Mediterranean Seas, Atlantic and Southern Ocean have been retrieved and merged into a new database: CARINA (CARbon dioxide IN the Atlantic Ocean). The data have gone through rigorous quality control procedures to assure the highest possible quality and consistency. The data for the pertinent parameters in the CARINA database were objectively examined in order to quantify systematic differences in the reported values, i.e. secondary quality control. Systematic biases found in the data have been corrected in the three data products: merged data files with measured, calculated and interpolated data for each of the three CARINA regions, i.e. the Arctic Mediterranean Seas, the Atlantic and the Southern Ocean. These products have been corrected to be internally consistent. Ninety-eight of the cruises in the CARINA database were conducted in the Atlantic Ocean, defined here as the region south of the Greenland-Iceland-Scotland Ridge and north of about 30° S. Here we present an overview of the Atlantic Ocean synthesis of the CARINA data and the adjustments that were applied to the data product. We also report the details of the secondary QC (Quality Control) for salinity for this data set. Procedures of quality control – including crossover analysis between stations and inversion analysis of all crossover data – are briefly described. Adjustments to salinity measurements were applied to the data from 10 cruises in the Atlantic Ocean region. Based on our analysis we estimate the internal consistency of the CARINA-ATL salinity data to be 4.1 ppm. With these adjustments the CARINA data products are consistent both internally as well as with GLODAP data, an oceanographic data set based on the World Hydrographic Program in the 1990s, and is now suitable for accurate assessments of, for example, oceanic carbon inventories and uptake rates and for model validation.
    Print ISSN: 1866-3508
    Electronic ISSN: 1866-3516
    Topics: Geosciences
    Published by Copernicus
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  • 8
    Publication Date: 2010-01-11
    Description: Water column data of carbon and carbon-relevant parameters have been collected and merged into a new database called CARINA (CARbon IN the Atlantic). In order to provide a consistent data set, all data have been examined for systematic biases and adjusted if necessary (secondary quality control (QC)). The CARINA data set is divided into three regions: the Arctic/Nordic Seas, the Atlantic region and the Southern Ocean. Here we present the CFC data for the Atlantic region, including the chlorofluorocarbons CFC-11, CFC-12 and CFC-113 as well as carbon tetrachloride (CCl4). The methods applied for the secondary quality control, a crossover analyses, the investigation of CFC ratios in the ocean and the CFC surface saturation are presented. Based on the results, the CFC data of some cruises are adjusted by a certain factor or given a "poor'' quality flag.
    Print ISSN: 1866-3508
    Electronic ISSN: 1866-3516
    Topics: Geosciences
    Published by Copernicus
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  • 9
    Publication Date: 2015-06-09
    Description: Carbon dioxide (CO2) is, next to water vapour, considered to be the most important natural greenhouse gas on Earth. Rapidly rising atmospheric CO2 concentrations caused by human actions such as fossil fuel burning, land-use change or cement production over the past 250 years have given cause for concern that changes in Earth's climate system may progress at a much faster pace and larger extent than during the past 20 000 years. Investigating global carbon cycle pathways and finding suitable adaptation and mitigation strategies has, therefore, become of major concern in many research fields. The oceans have a key role in regulating atmospheric CO2 concentrations and currently take up about 25% of annual anthropogenic carbon emissions to the atmosphere. Questions that yet need to be answered are what the carbon uptake kinetics of the oceans will be in the future and how the increase in oceanic carbon inventory will affect its ecosystems and their services. This requires comprehensive investigations, including high-quality ocean carbon measurements on different spatial and temporal scales, the management of data in sophisticated databases, the application of Earth system models to provide future projections for given emission scenarios as well as a global synthesis and outreach to policy makers. In this paper, the current understanding of the ocean as an important carbon sink is reviewed with respect to these topics. Emphasis is placed on the complex interplay of different physical, chemical and biological processes that yield both positive and negative air–sea flux values for natural and anthropogenic CO2 as well as on increased CO2 (uptake) as the regulating force of the radiative warming of the atmosphere and the gradual acidification of the oceans. Major future ocean carbon challenges in the fields of ocean observations, modelling and process research as well as the relevance of other biogeochemical cycles and greenhouse gases are discussed.
    Print ISSN: 2190-4979
    Electronic ISSN: 2190-4987
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2014-12-05
    Description: Carbon dioxide (CO2) is, next to water vapour, considered to be the most important natural greenhouse gas on Earth. Rapidly rising atmospheric CO2 concentrations caused by human actions such as fossil-fuel burning, land-use change or cement production over the past 250 years have given cause for concern that changes in Earth's climate system may progress at a much faster pace and larger extent than during the past 20 000 years. Investigating global carbon cycle pathways and finding suitable mitigation strategies has, therefore, become of major concern in many research fields. The oceans have a key role in regulating atmospheric CO2 concentrations and currently take up about 25% of annual anthropogenic carbon emissions to the atmosphere. Questions that yet need to be answered are what the carbon uptake kinetics of the oceans will be in the future and how the increase in oceanic carbon load will affect its ecosystems and their services. This requires comprehensive investigations, including high-quality ocean carbon measurements on different spatial and temporal scales, the management of data in sophisticated data bases, the application of state-of-the-art Earth system models to provide future projections for given emission scenarios as well as a global synthesis and outreach to policy makers. In this paper, the current understanding of the ocean as an important carbon sink is reviewed with respect to these topics. Emphasis is placed on the complex interplay of different physical, chemical, and biological processes that yield both positive and negative air–sea flux values for natural and anthropogenic CO2 as well as on increased CO2 (uptake) as the regulating force of the radiative warming of the atmosphere and the gradual acidification of the oceans. Major future ocean carbon challenges in the fields of ocean observations, modelling, and process research as well as the relevance of other biogeochemical cycles and greenhouse gases are discussed.
    Electronic ISSN: 2190-4995
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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