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  • 1
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Plasma desorption time-of-flight mass spectrometry (PD-TOFMS) using accelerated argon ions (9 MeV) has been successfully used for characterizing the surface modifications induced at the surface of poly(ether etherketone) (PEEK) by cold plasma treatments. While the intact polymer structure leads to the emission of negative ions from fragmentation of the repeat unit, the degradation of such a structure under plasma exposure gives rise to production of oxidized fragments. It is demonstrated that this production is highest for a plasma using a mixture of O2 and N2 (20:80), and that as a function of treatment duration, the rate of oxidation of the modified surface layer correlates with adhesive strength, at least in a first step. PD-TOFMS is used for analysis of the failure patterns of epoxyamine adhesive/PEEK/carbon composite in order to localize the fracture position. It is concluded that the increase of the cohesion of the interphase layer as a function of the plasma treatment duration leads to a shift from the interphase/PEEK interface to the bulk of the matrial.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 20 (1981), S. 891-896 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We report on the band structure and wave functions of positrons, annihilating with electrons, from the thermalized state k+ = 0. We find that the bottom of the band to which the positron thermalizes in this metal is definitely nonambiguous. It is also found that even though the first few Bloch terms in the wave function can give the gross shape of the positron annihilation curve for this metal, the higher momentum components of high orders are definitely important if one is to assay the fine details of the curve.
    Additional Material: 4 Ill.
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  • 3
    Publication Date: 2014-10-07
    Description: This study examines impacts of oil foreign direct investment on the environment and welfare of people of Niger delta oil producing communities, using structural equation models. Overall, it was found that oil foreign direct investment has consistent impact on the environment than the well-being of the community, which results in high levels of poverty. The implication is that there is environmental diseconomies and widespread of poverty in the area. Thus, there is need for fostering sustainable partnership between the oil foreign direct investors and the host communities by suitable consideration of the issues of mitigation of environmental problems that will reduce the poverty level of the people. The environmental and socioeconomic system should be developed to maintain an intensity of biodiversity that will give assurance to the buoyancy of the ecosystems on which human consumption and production depend. Keywords: Foreign direct investment; environmental degradation; poverty; structural equation modeling JEL Classifications: C39; F21; F64; I31
    Electronic ISSN: 2146-4553
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Published by EconJournals
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  • 4
    Publication Date: 2018-10-24
    Description: We investigated total electron content (TEC) at Ilorin (8.50∘ N 4.65∘ E, dip lat. 2.95) for the year 2010, a year of low solar activity in 2010 with Rz=15.8. The investigation involved the use of TEC derived from GPS, estimated TEC from digisonde portable sounder data (DPS), and the International Reference Ionosphere (IRI) and NeQuick 2 (NeQ) models. During the sunrise period, we found that the rate of increase in DPS TEC, IRI TEC, and NeQ TEC was higher compared with GPS TEC. One reason for this can be attributed to an overestimation of plasmaspheric electron content (PEC) contribution in modeled TEC and DPS TEC. A correction factor around the sunrise, where our finding showed a significant percentage deviation between the modeled TEC and GPS TEC, will correct the differences. Our finding revealed that during the daytime when PEC contribution is known to be absent or insignificant, GPS TEC and DPS TEC in April, September, and December predict TEC very well. The lowest discrepancies were observed in May, June, and July (June solstice) between the observed values and all the model values at all hours. There is an overestimation in DPS TEC that could be due to extrapolation error while integrating from the peak electron density of F2 (NmF2) to around ∼1000 km in the Ne profile. The underestimation observed in NeQ TEC must have come from the inadequate representation of contribution from PEC on the topside of the NeQ model profile, whereas the exaggeration of PEC contribution in IRI TEC amounts to overestimation in GPS TEC. The excess bite-out observed in DPS TEC and modeled TEC indicates over-prediction of the fountain effect in these models. Therefore, the daytime bite-out observed in these models requires a modifier that could moderate the perceived fountain effect morphology in the models accordingly. The daytime DPS TEC performs better than the daytime IRI TEC and NeQ TEC in all the months. However, the dusk period requires attention due to the highest percentage deviation recorded, especially for the models, in March, November, and December. Seasonally, we found that all the TECs maximize and minimize during the March equinox and June solstice, respectively. Therefore, GPS TEC and modeled TEC reveal the semiannual variations in TEC.
    Print ISSN: 0992-7689
    Electronic ISSN: 1432-0576
    Topics: Geosciences , Physics
    Published by Copernicus on behalf of European Geosciences Union.
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  • 5
    Publication Date: 2017-01-03
    Description: Rate of change of TEC (ROT) and its index (ROTI) are considered a good proxy to characterize the occurrence of ionospheric plasma irregularities like those observed after sunset at low latitudes. SBASs (satellite-based augmentation systems) are civil aviation systems that provide wide-area or regional improvement to single-frequency satellite navigation using GNSS (Global Navigation Satellite System) constellations. Plasma irregularities in the path of the GNSS signal after sunset cause severe phase fluctuations and loss of locks of the signals in GNSS receiver at low-latitude regions. ROTI is used in this paper to characterize plasma density ionospheric irregularities in central–western Africa under nominal and disturbed conditions and identified some days of irregularity inhibition. A specific low-latitude algorithm is used to emulate potential possible SBAS message using real GNSS data in the western African low-latitude region. The performance of a possible SBAS operation in the region under different ionospheric conditions is analysed. These conditions include effects of geomagnetic disturbed periods when SBAS performance appears to be enhanced due to ionospheric irregularity inhibition. The results of this paper could contribute to a feasibility assessment of a European Geostationary Navigation Overlay System-based SBAS in the sub-Saharan African region.
    Print ISSN: 0992-7689
    Electronic ISSN: 1432-0576
    Topics: Geosciences , Physics
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 2018-06-08
    Description: We investigated total electron content (TEC) at Ilorin (8.50°N 4.65°E, dip lat. 2.95) during a low solar activity 2010. The investigation involved the use of GPS derived TEC, TEC estimated from digisonde portable sounder data (DPS-TEC), the International Reference Ionosphere model (IRI-TEC) and NeQuick 2 model (NeQ-TEC). The five most quietest days of the months obtained from the international quiet days (IQD) from the website http://www.ga.gov.au/oracle/geomag/iqd_form.jsp were used for the investigation. During the sunrise period, we found that the rate of increases in DPS-TEC, IRI-TEC and NeQ-TEC were higher with respect to GPS-TEC. One reason for this can be alluded to an overestimation of plasmaspheric electron content (PEC) contribution in modeled TEC and DPS-TEC. A correction factor around the sunrise where a significant percentage difference of overestimations between the modeled TEC and GPS-TEC was obtained will correct the differences. Our finding revealed that during the daytime when PEC contribution is known to be absent or insignificant, GPS-TEC and DPS-TEC in April, September and December predicts TEC very well. The lowest discrepancies were observed in May, June and July (June solstice) between the observed and all the model values in all hours. There is an overestimation in DPS-TEC that could be due to extrapolation error while integrating from the peak electron density of F2 (NmF2) to around ~1000km in the Ne profile. The underestimation observed in NeQ-TEC must have come from the inadequate representation of contribution from PEC on the topside of NeQ model profile whereas the exaggeration of PEC contribution in IRI-TEC amount to overestimations of GPS-TEC. The excess bite-out observed in DPS-TEC and NeQ-TEC show the indication of overprediction of fountain effect in these models. Therefore, the daytime bite-out observed in these two models require a modifier that could moderate the perceived fountain effect morphology in the models accordingly. Seasonally, we found that all the TECs maximize and minimize during the March equinox and June solstice, respectively. Therefore, GPS-, DPS-, IRI- and NeQ-TEC reveal the semi-annual variations in TEC as reported in all regions. The daytime DPS-TEC performs better than the daytime IRI-TEC and NeQ-TEC in all the months, however, the dusk period requires attention due to highest percentage difference recorded especially for DPS-TEC and the models in March, and November and December for DPS-TEC.
    Electronic ISSN: 2568-6402
    Topics: Geosciences , Physics
    Published by Copernicus on behalf of European Geosciences Union.
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  • 7
    Publication Date: 2013-01-01
    Electronic ISSN: 2115-7251
    Topics: Geosciences , Physics
    Published by EDP Sciences
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