ALBERT

Description: Surface-atmosphere exchange fluxes of CO2, estimated by an interannual atmospheric transport inversion from atmospheric mixing ratio measurements, are affected by several sources of errors, one of which is experimental errors. Quantitative information about such measurement errors can be obtained from regular co-located measurements done by different laboratories or using different experimental techniques. The present quantitative assessment is based on intercomparison information from the CMDL and CSIRO atmospheric measurement programs. We show that the effects of systematic measurement errors on inversion results are very small compared to other errors in the flux estimation (as well as compared to signal variability). As a practical consequence, this assessment justifies the merging of data sets from different laboratories or different experimental techniques (flask and in-situ), if systematic differences (and their changes) are comparable to those considered here. This work also highlights the importance of regular intercomparison programs.

Description: Observations of CO2 were made in the upper troposphere and lower stratosphere in the deep tropics in order to determine the patterns of large-scale vertical transport and age of air in the Tropical Tropopause Layer (TTL). Flights aboard the NASA WB-57F aircraft over Central America and adjacent ocean areas took place in January and February, 2004 (Pre-AURA Validation Experiment, Pre-AVE) and 2006 (Costa Rice AVE, CR-AVE), and for the same flight dates of 2006, aboard the Proteus aircraft from the surface to 15 km over Darwin, Australia (Tropical Warm Pool International Cloud Experiment, TWP-ICE). The data demonstrate that the TTL is composed of two layers with distinctive features: (1) the lower TTL, 350–360 K (potential temperature(θ); approximately 12–14 km), is subject to inputs of convective outflows, as indicated by layers of variable CO2 concentrations, with air parcels of zero age distributed throughout the layer; (2) the upper TTL, from θ=~360 K to ~390 K (14–18 km), ascends slowly and ages uniformly, as shown by a linear decline in CO2 mixing ratio tightly correlated with altitude, associated with increasing age. This division is confirmed by ensemble trajectory analysis. The CO2 concentration at the level of 360 K was 380.0(±0.2) ppmv, indistinguishable from surface site values in the Intertropical Convergence Zone (ITCZ) for the flight dates. Values declined with altitude to 379.2(±0.2) ppmv at 390 K, implying that air in the upper TTL monotonically ages while ascending. In combination with the winter slope of the CO2 seasonal cycle (+10.8±0.4 ppmv/yr), the vertical gradient of –0.78 (±0.09) ppmv gives a mean age of 26(±3) days for the air at 390 K and a mean ascent rate of 1.5(±0.3) mm s−1. The TTL near 360 K in the Southern Hemisphere over Australia is very close in CO2 composition to the TTL in the Northern Hemisphere over Costa Rica, with strong contrasts emerging at lower altitudes (

Description: Surface-atmosphere exchange fluxes of CO2, estimated by an interannual atmospheric transport inversion from atmospheric mixing ratio measurements, are affected by several sources of errors, one of which is experimental errors. Quantitative information about such measurement errors can be obtained from regular co-located measurements done by different laboratories or using different experimental techniques. The present quantitative assessment is based on intercomparison information from the CMDL and CSIRO atmospheric measurement programs. We show that the effects of systematic measurement errors on inversion results are very small compared to other errors in the flux estimation (as well as compared to signal variability). As a practical consequence, this assessment justifies the merging of data sets from different laboratories or different experimental techniques (flask and in-situ), if systematic differences (and their changes) are comparable to those considered here. This work also highlights the importance of regular intercomparison programs.

Description: Observations of CO2 were made in the upper troposphere and lower stratosphere in the deep tropics in order to determine the patterns of large-scale vertical transport and age of air in the Tropical Tropopause Layer (TTL). Flights aboard the NASA WB-57F aircraft over Central America and adjacent ocean areas took place in January and February, 2004 (Pre-AURA Validation Experiment, Pre-AVE) and 2006 (Costa Rice AVE, CR-AVE), and for the same flight dates of 2006, aboard the Proteus aircraft from the surface to 15 km over Darwin, Australia (Tropical Warm Pool International Cloud Experiment , TWP-ICE). The data demonstrate that the TTL is composed of two layers with distinctive features: (1) the lower TTL, 350–360 K (potential temperature (θ); approximately 12–14 km), is subject to inputs of convective outflows, as indicated by layers of variable CO2 concentrations, with air parcels of zero age distributed throughout the layer; (2) the upper TTL, from θ= ~360 K to ~390 K (14–18 km), ascends slowly and ages uniformly, as shown by a linear decline in CO2 mixing ratio tightly correlated with altitude, associated with increasing age. This division is confirmed by ensemble trajectory analysis. The CO2 concentration at the level of 360 K was 380.0(±0.2) ppmv, indistinguishable from surface site values in the Intertropical Convergence Zone (ITCZ) for the flight dates. Values declined with altitude to 379.2(±0.2) ppmv at 390 K, implying that air in the upper TTL monotonically ages while ascending. In combination with the winter slope of the CO2 seasonal cycle (+10.8±0.4 ppmv/yr), the vertical gradient of 0.78 (±0.09) ppmv gives a mean age of 26(±3) days for the air at 390 K and a mean ascent rate of 1.5(±0.3) mm s−1. The TTL near 360 K in the Southern Hemisphere over Australia is very close in CO2 composition to the TTL in the Northern Hemisphere over Costa Rica, with strong contrasts emerging at lower altitudes (