ALBERT

Description: The National Aeronautics and Space Administration's (NASA) Mars Exploration Program is focused on understanding the past or present habitability of Mars (MEPAG, 2010). Central to this aim is determining the history of liquid water on Mars. Some of the most salient evidence for liquid water is giant outflow channels that debouch into Chryse Planitia, hypothesized to be part of an ancient Martian ocean (Parker et al., 1993; Head et al., 1999; Perron et al., 2007; Di Achille and Hynek, 2010). An ocean should be a fertile nursery for Martian life, based on terrestrial evidence (e.g., Walter et al., 1980; Van Kranendonk et al., 2003). Thus, understanding whether the streamlined forms around Chryse Planitia were created in the outflow channels or within the hypothesized ocean contributes to identifying habitable zones on Mars...

Description: Fluvial features on Titan have been identified in synthetic aperture radar (SAR) data taken during spacecraft flybys by the Cassini Titan Radar Mapper (RADAR) and in Descent Imager/Spectral Radiometer (DISR) images taken during descent of the Huygens probe to the surface. Interpretations using terrestrial analogs and process mechanics extend our perspective on fluvial geomorphology to another world and offer insight into their formative processes. At the landscape scale, the varied morphologies of Titan’s fluvial networks imply a variety of mechanical controls, including structural influence, on channelized flows. At the reach scale, the various morphologies of individual fluvial features, implying a broad range of fluvial processes, suggest that (paleo-)flows did not occupy the entire observed width of the features. DISR images provide a spatially limited view of uplands dissected by valley networks, also likely formed by overland flows, which are not visible in lower-resolution SAR data. This high-resolution snapshot suggests that some fluvial features observed in SAR data may be river valleys rather than channels, and that uplands elsewhere on Titan may also have fine-scale fluvial dissection that is not resolved in SAR data. Radar-bright terrain with crenulated bright and dark bands is hypothesized here to be a signature of fine-scale fluvial dissection. Fluvial deposition is inferred to occur in braided channels, in (paleo)lake basins, and on SAR-dark plains, and DISR images at the surface indicate the presence of fluvial sediment. Flow sufficient to move sediment is inferred from observations and modeling of atmospheric processes, which support the inference from surface morphology of precipitation-fed fluvial processes. With material properties appropriate for Titan, terrestrial hydraulic equations are applicable to flow on Titan for fully turbulent flow and rough boundaries. For low-Reynolds-number flow over smooth boundaries, however, knowledge of fluid kinematic viscosity is necessary. Sediment movement and bed form development should occur at lower bed shear stress on Titan than on Earth. Scaling bedrock erosion, however, is hampered by uncertainties regarding Titan material properties. Overall, observations of Titan point to a world pervasively influenced by fluvial processes, for which appropriate terrestrial analogs and formulations may provide insight.

Description: We discuss a radiocarbon study of sediment samples collected from Nanfu terrace in western Taiwan. From these, we extracted humic acids (HA) and humin from the very fine and coarse grain-size fractions using a standard acid-alkali-acid pretreatment. The humin extracts were combusted at 400 and 1100 °C by stepped-combustion, to yield a low-temperature (LT) carbon component and a high-temperature (HT) carbon component. We compare the ages of the LT and HT humin fractions to the HA fractions, in samples collected at 2 depths within the Nanfu terrace. As in previous stepped-combustion studies on sediments, we find that the HA ages are the youngest on average, and overlap the LT ages, and that the carbon contained in the HT fraction is always distinctly older than the LT and HA ages. To better understand the relationship between 14C age and combustion temperature, we conducted an incremental stepped-combustion experiment with one of the samples (1E) using 50 °C steps that ranged from 300 to 1100 °C. The 14C results of the stepped-combustion products show a clear division between 2 isotopically identifiable carbon constituents, from carbon released below 400 °C and carbon released above 550 °C. By comparing the δ13C and 14C results, we find evidence for a third carbon isotopic component in the humin that is released when combusted at ∼500 °C.

Description: Radiocarbon measured in seawater dissolved inorganic carbon (DIC) can be used to investigate ocean circulation, atmosphere/ocean carbon flux, and provide powerful constraints for the fine-tuning of general circulation models (GCMs). Time series of 14C in seawater are derived most frequently from annual bands of hermatypic corals. However, this proxy is unavailable in temperate and polar oceans. Fish otoliths, calcium carbonate auditory, and gravity receptors in the membranous labyrinths of teleost fishes, can act as proxies for 14C in most oceans and at most depths. Arcto-Norwegian cod otoliths are suited to this application due to the well-defined distribution of this species in the Barents Sea, the ability to determine ages of individual Arcto-Norwegian cod with a high level of accuracy, and the availability of archived otoliths collected for fisheries research over the past 60 years. Using measurements of 14C derived from Arcto-Norwegian cod otoliths, we present the first pre- and post-bomb time series (1919–1992) of 14C from polar seas and consider the significance of these data in relation to ocean circulation and atmosphere/ocean flux of 14C. The data provide evidence for a minor Suess effect of only 0.2‰ per year between 1919 and 1950. Bomb 14C was evident in the Barents Sea as early as 1957 and the highest 14C value was measured in an otolith core from a cod with a birth date of 1967. The otolith 14C data display key features common to records of 14C obtained from a Georges Bank mollusc and corals from the tropical and subtropical North Atlantic.

Description: In this paper, we review the production of radiocarbon and other radionuclides in extraterrestrial materials. This radioactivity can be produced by the effects of solar and galactic cosmic rays on solid material in space. In addition, direct implantation at the lunar surface of 14C and other radionuclides can occur. The level of 14C and other radionuclides in a meteorite can be used to determine its residence time on the Earth's surface, or “terrestrial age”. 14C provides the best tool for estimating terrestrial ages of meteorites collected in desert environments. Age control allows us to understand the time constraints on processes by which meteorites are weathered, as well as mean storage times. Third, we discuss the use of the difference in 14C/12C ratio of organic material and carbonates produced on other planetary objects and terrestrial material. These differences can be used to assess the importance of distinguishing primary material formed on the parent body from secondary alteration of meteoritic material after it lands on the earth.

Description: We report results of a three-year intercomparison experiment between the WHOI Radiocarbon Laboratory (now at University of California, Irvine) and the NSF-University of Arizona AMS Laboratory. The purpose of this study was to compare high-precision measurements of samples obtained routinely using gas proportional counting techniques with results obtained using AMS techniques. Three sets of annually banded, modern coral samples were used for the intercomparison. Each sample was acidified to CO2 at WHOI and split into two fractions. The larger fraction was converted to acetylene gas and counted at WHOI in quartz, gas-proportional beta counters. The smaller fractions were converted to graphite and analyzed for 14C using AMS techniques at the University of Arizona. Results of the three sample sets are presented. Except for a single outlier, the data from the two laboratories are in good agreement. Of the 13 samples in the third set of the intercomparison, for which a new high-intensity ion source was in operation at the Arizona AMS laboratory, agreement of results is excellent. This finding indicates that measurements made with precisions of 〈 3% are reproducible at both laboratories.

Description: We find no evidence for an anomalously intense 11-yr cycle in Δ14C at high latitudes during the period, AD 1870–1885, as reported by Fan et al. (1983, 1986). However, there does appear to be a regional effect within the MacKenzie River region (67°N, 130°W), with atmospheric 14C depressed by relative to the Olympic Peninsula. Such an effect would require only 5% of CO2 in the air mass to have been derived from 5% 14C-depleted soil gas CO2. This small but apparently significant regional effect could be caused by accumulation of CO2 within the frozen earth followed by outgassing during the spring thaw. The short growing season would enhance the effect by allowing insufficient time for global atmospheric equilibration.

Description: We report on an initial long-term study of dissolved inorganic and organic carbon (DIC) from Sabino Creek, located in Sabino Canyon, Pima County, Arizona. The purpose of this study was to monitor changes in dissolved radiocarbon (14C) with time and to understand the processes contributing to these variations. Our results span the period 2009–2016 and show a mixing trend between dissolved inorganic and organic carbon modern end-members with an older component. This study provides preliminary information for more detailed research on recycling of organic components in this stream system.

Description: A compilation of direct age determinations for Late Pleistocene human fossils in eastern Europe and Asia is presented in this paper, and current problems with the dating of hominids in these regions are discussed. Only 25 human finds (4 Neanderthals and 21 modern humans) have been directly dated from Pleistocene eastern Europe and Asia. Indirect dating of human remains (using presumably associated organics) often is insecure, especially when information about the exact provenance of human fossils is lacking. Continuation of direct dating of Late Pleistocene humans in Eurasia, primarily with the help of the accelerator mass spectrometry (AMS) 14C method, is therefore an urgent task.

Description: A method of thermal and acid treatments was developed at the Archaeo-metallurgy Laboratory of Hongik University in Korea to extract carbon from cast iron, and carbon objects thus prepared from cast iron artifacts of ancient Korea were dated at the University of Arizona's AMS Facility. The thermal treatments consist of heating a specimen to ∼1000 °C in a controlled environment with reduced oxygen potential, then cooling it rapidly to room temperature. The heating causes the cementite phase in white cast iron to be graphitized and the quenching suppresses pearlite formation. The specimen then consists of flakes of graphite embedded in a matrix of martensite. The next stage of the treatment is to dissolve the martensite matrix in a solution of nitric and hydrochloric acids to release the graphite as a powder. This material is then cleaned, dried, and pressed into target holders for accelerator mass spectrometry (AMS) analysis. The method was applied to a collection of artifacts from the Korean Three Kingdoms period (about AD 300–668) and the AMS results were compared with chronological estimates from other means.