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  • 1
    Publication Date: 2013-11-15
    Description: The stability of a two-dimensional surfactant-free (gas-liquid) foam in a gravitational field is considered. The foam is assumed to have low liquid fraction, so the gas phase can be divided into approximately polygonal bubbles separated by thin liquid films. These free films drain toward accumulations of liquid at the bubble vertices, the Plateau borders, and eventually rupture due to van der Waals intermolecular attractions; this drives foam coarsening through the coalescence of neighbouring bubbles. In particular, we demonstrate how gravitational effects strongly modify the shape of the Plateau border interfaces and enhance the drainage flow in the liquid films, driving non-uniform thinning with exponential decay of the minimum film thickness, significantly faster than the power-law thinning predicted when gravitational effects are negligible. ©2013 Cambridge University Press.
    Print ISSN: 0022-1120
    Electronic ISSN: 1469-7645
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 2
    Publication Date: 2000-01-01
    Description: In the western Grand Canyon, fluvial terraces and pediment surfaces, both associated with a Pleistocene basalt flow, document Quaternary aggradation and downcutting by the Colorado River, illuminate the river's response to overload and the end of overload, and allow calibration of soil-carbonate stages and determination of downcutting rates. Four downcutting–aggradation cycles are present. Each begins with erosion of older deposits to form a new river channel in which a characteristic suite of deposits is laid down. The current cycle (I) started ∼700 yr B.P. The oldest (IV) includes the 603,000 ± 8000 to 524,000 ± 7000 yr Black Ledge basalt flow, emplaced when the river channel was ∼30 m higher than it is now. The flow is overlain by basalt–cobble gravel and basalt sand. Soils reach the stage V level of carbonate development. Calibrated ages for soil stages are Stage V, ∼525,000 yr; stage IV,
    Print ISSN: 0033-5894
    Electronic ISSN: 1096-0287
    Topics: Geography , Geosciences
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  • 3
    Publication Date: 2010-08-18
    Description: An ultra-thin viscous film on a substrate is susceptible to rupture instabilities driven by van der Waals attractions. When a unidirectional wind shear is applied to the free surface, the rupture instability in two dimensions is suppressed when exceeds a critical value c and is replaced by a permanent finite-amplitude structure, an intermolecular-capillary wave, that travels at approximately the speed of the surface. For small amplitudes, the wave is governed by the Kuramoto-Sivashinsky equation. If three-dimensional disturbances are allowed, the shear is decoupled from disturbances perpendicular to the flow, and line rupture would occur. In this case, replacing the unidirectional shear with a shear whose direction rotates with angular speed, suppresses the rupture if 2c. For the most dangerous wavenumber, c 102 dyn cm 2 at 1 rad s1 for a film with physical properties similar to water at a thickness of 100 nm. © 2010 Cambridge University Press.
    Print ISSN: 0022-1120
    Electronic ISSN: 1469-7645
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 4
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Priscu, J. C., Kalin, J., Winans, J., Campbell, T., Siegfried, M. R., Skidmore, M., Dore, J. E., Leventer, A., Harwood, D. M., Duling, D., Zook, R., Burnett, J., Gibson, D., Krula, E., Mironov, A., McManis, J., Roberts, G., Rosenheim, B. E., Christner, B. C., Kasic, K., Fricker, H. A., Lyons, W. B., Barker, J., Bowling, M., Collins, B., Davis, C., Gagnon, A., Gardner, C., Gustafson, C., Kim, O-S., Li, W., Michaud, A., Patterson, M. O., Tranter, M., Ryan Venturelli, R., Trista Vick-Majors, T., & Elsworth, C. Scientific access into Mercer Subglacial Lake: scientific objectives, drilling operations and initial observations. Annals of Glaciology, 62(85–86), (2021): 340–352, https://doi.org/10.1017/aog.2021.10.
    Description: The Subglacial Antarctic Lakes Scientific Access (SALSA) Project accessed Mercer Subglacial Lake using environmentally clean hot-water drilling to examine interactions among ice, water, sediment, rock, microbes and carbon reservoirs within the lake water column and underlying sediments. A ~0.4 m diameter borehole was melted through 1087 m of ice and maintained over ~10 days, allowing observation of ice properties and collection of water and sediment with various tools. Over this period, SALSA collected: 60 L of lake water and 10 L of deep borehole water; microbes 〉0.2 μm in diameter from in situ filtration of ~100 L of lake water; 10 multicores 0.32–0.49 m long; 1.0 and 1.76 m long gravity cores; three conductivity–temperature–depth profiles of borehole and lake water; five discrete depth current meter measurements in the lake and images of ice, the lake water–ice interface and lake sediments. Temperature and conductivity data showed the hydrodynamic character of water mixing between the borehole and lake after entry. Models simulating melting of the ~6 m thick basal accreted ice layer imply that debris fall-out through the ~15 m water column to the lake sediments from borehole melting had little effect on the stratigraphy of surficial sediment cores.
    Description: This material is based upon work supported by the US National Science Foundation, Section for Antarctic Sciences, Antarctic Integrated System Science program as part of the interdisciplinary (Subglacial Antarctic Lakes Scientific Access (SALSA): Integrated study of carbon cycling in hydrologically-active subglacial environments) project (NSF-OPP 1543537, 1543396, 1543405, 1543453 and 1543441). Ok-Sun Kim was funded by the Korean Polar Research Institute. We are particularly thankful to the SALSA traverse personnel for crucial technical and logistical support. The United States Antarctic Program enabled our fieldwork; the New York Air National Guard and Kenn Borek Air provided air support; UNAVCO provided geodetic instrument support. Hot water drilling activities, including repair and upgrade modifications of the WISSARD hot water drill system, for the SALSA project were supported by a subaward from the Ice Drilling Program of Dartmouth College (NSF-PLR 1327315) to the University of Nebraska-Lincoln. J. Lawrence assisted with manuscript preparation. Finally, we are grateful to C. Dean, the SALSA Project Manager, and R. Ricards, SALSA Project Coordinator at McMurdo Station, for their organizational skills, and B. Huber of Lamont-Doherty Earth Observatory for providing the SBE39 PT sensors and the Nortek Aquadopp current meter and assisting with interpretation of the data. B. Huber also provided helpful input on programing and calibrating the SBE19PlusV2 6112 CTD.
    Keywords: Antarctic glaciology ; Basal ice ; Biogeochemistry ; Glacial sedimentology ; Subglacial lakes
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 3427-3431 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Flow of fluids confined in molecularly narrow pores is studied by molecular dynamics. Strong density variations across the pore render the usual dependence of the local viscosity on local density inappropriate. At separations greater than four molecular diameters flow can be described by a simple redefinition of local viscosity. In narrower pores a dramatic increase of effective viscosities is observed and is due to the inability of fluid layers to undergo the gliding motion of planar flow. This effect is partially responsible for the strong viscosity increases observed experimentally in thin films that still maintain their fluidity.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 4308-4319 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Means are presented for using stationary points in two ways. One, for well-understood potentials, elucidates relations between the form of the surface and the dynamics that it supports, including the determination of the effective molecular symmetry group. The other, for potentials of uncertain quality, provides a test for unphysical characteristics and suggests how the surface might be improved if it is found to be unsatisfactory in some respect. Our approach involves comparison of transition state calculations using the slowest slide and Cerjan–Miller algorithms for two example systems: the Lennard-Jones Ar7 cluster and the Handy–Carter many-body-expansion potential for the ground state of formaldehyde.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 3246-3251 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: It is now generally accepted that some midrange microemulsions are bicontinuous, i.e., continuous in both oil and water simultaneously. The first model of the microstructure of microemulsion that could account for a progression from discrete to bicontinuous was the Talmon–Prager or "randomly decorated Voronoi'' model. Space is tessellated into Voronoi polyhedra and the polyhedra are randomly decorated with oil and water. In variations of the model DeGennes and Taupin and Widom decorate a cubic tesselation of space. At first glance it might appear that the decorated Voronoi and cubic tessellations are zero-mean-curvature models, since they are constructed from polyhedra with planar faces. However, the edges of the polyhedra are concentrations of mean curvature, and the vertices are concentrations of Gaussian curvature. The area-averaged mean and Gaussian curvatures of the oil–water interface in the randomly decorated Voronoi and cubic models are calculated. The area-averaged mean curvatures of the two models are linear functions of oil volume fraction, change sign at a volume fraction of 0.5, and are within 0.2% of one another in magnitude. The area-averaged Gaussian curvature of the Voronoi model varies quadratically with volume fraction, and is negative for oil volume fractions from 0.18 to 0.82 (oil and water are bicontinuous for volume fractions ranging from 0.135 to 0.865). The area-averaged Gaussian curvature of the randomly decorated cubic model is a sixth-order polynomial function of oil volume fraction and is negative for volume fractions ranging from 0.23 to 0.77 (oil and water are bicontinuous over the volume fraction range 0.25 to 0.75). As an additional application, the model results are used to interpret curvature aspects of the bilayer theory of the L3 phase of surfactant solutions presented recently by Cates et al. [Europhys. Lett. 5, 733 (1988)].
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1656-1663 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Törring–Ernst–Kindt (TEK) model for the alkaline-earth monohalide molecules was extended to predict molecular polarizabilities and quadrupole moments in addition to dipoles. Calculations were carried out for the 19 molecules for which experimental bond lengths and vibrational frequencies are known. It was found that for many of these molecules the TEK model predicts negative polarizability anisotropies, α⊥〉α(parallel). This is in disagreement with the dipole-induced dipole, or Silberstein, formula, but in agreement with an empirical correlation between the anisotropy and the molecular asymmetry noted by Winicur. The TEK polarizabilities give rise to a much smaller second-order Legendre anisotropy in the CaCl–Ar interaction potential than was found in earlier work using the Rittner model. The D-shell model applied earlier to the alkali halides was also applied to the 19 alkaline-earth monohalides. With a slight modification it was found to describe both classes of ionic compounds successfully, although less successfully for the alkaline-earth compounds. The D-shell model was shown to be a generalization of the TEK model which includes the effect of the shell overlap on the polarizing fields at the ions. Nevertheless, the TEK model predicts better dipole moments, unless the shell charge is treated as an additional, adjustable parameter in the D-shell model.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 2429-2456 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The collinear I+HI reaction is studied using an approach based on the concepts of nonlinear dynamics. Three closed regions in phase space are constructed by connecting the dynamical manifolds emanating from physically important periodic orbits. It is shown that many features of the reaction dynamics can be understood with reference to these regions. The oscillating reaction probability in this system is shown to stem from the geometrical pattern of overlap of heteroclinic oscillations of an interaction region. The process of complex formation is quantitatively described in terms of passage into a well defined complex region of phase space. The phase space representation predicts that the complex formation probability oscillates with energy and suggests that the complex lifetime might oscillate as well. We have carried out simulations which confirm both of these effects. The vibrational adiabatic approximation for the reaction is assessed relative to the exact classical dynamics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 3263-3272 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We compare quantum and classical mechanics for a collinear model of OCS at an energy (20 000 cm−1) where Davis [J. Chem. Phys. 83, 1016 (1985)] had previously found that phase space bottlenecks associated with golden mean tori inhibit classical flow between different chaotic regions in phase space. Accurate quantum eigenfunctions for this two mode system are found by diagonalizing a large basis of complex Gaussian functions, and these are then used to study the evolution of wave packets which have 20 000 cm−1 average energies. By examining phase space (Husimi) distributions associated with the wave functions, we conclude that these golden mean tori do indeed act as bottlenecks which constrain the wave packets to evolve within one (or a combination of) regions. The golden mean tori do not completely determine the boundaries between regions, however. Bottlenecks associated with resonance trapping and with separatrix formation are also involved. The analysis of the Husimi distributions also indicates that each exact eigenstate is nearly always associated with just one region, and because of this, superpositions of eigenstates that are localized within a region remain localized in that region at all times. This last result differs from the classical picture at this energy where flow across the bottlenecks occurs with a 2–4 ps lifetime. Since the classical phase space area through which flux must pass to cross the bottlenecks is small compared to (h-dash-bar) for OCS, the observed difference between quantum and classical dynamics is not surprising. Examination of the time development of normal mode energies indicates little or no energy flow quantum mechanically for wave packet initial conditions. Classical trajectory bundles constructed from the wave packet phase space distributions also show little or no energy flow even though noticeable flow is observed for more localized bundles chosen from the turnstile associated with flow through the bottleneck.
    Type of Medium: Electronic Resource
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