ALBERT

Description: Canadian deuterium uranium (CANDU) pressurized heavy-water reactors produce 14C by neutron activation of trace quantities of nitrogen in annular gas and reactor components (14N(n,p)14C), and from 17O in the heavy water moderator by (17O(n,α)14C). The radiocarbon produced in the moderator is removed on ion exchange resins incorporated in the water purification systems; however, a much smaller gaseous portion is vented from reactor stacks at activity levels considerably below 1% of permissible derived emission limits. Early measurements of the carbon speciation indicated that 〉90% of the 14C emitted was in the form of CO2. We conducted surveys of the atmospheric dispersion of 14CO2 at the Chalk River Laboratories and at the Pickering Nuclear Generating Station. We analyzed air, vegetation, soils and tree rings to add to the historical record of 14C emissions at these sites, and to gain an understanding of the relative importance of the various carbon pools that act as sources/sinks within the total 14C budget. Better model parameters than those currently available for calculating the dose to the critical group can be obtained in this manner. Global dose estimates may require the development of techniques for estimating emissions occurring outside the growing season.

Description: Experimental results for a reactive non-buoyant plume of nitric oxide (NO) in a turbulent grid flow doped with ozone (O3) are presented. The Damköhler number (ND) for the experiment is of order unity indicating the turbulence and chemistry have similar timescales and both affect the chemical reaction rate. Continuous measurements of two components of velocity using hot-wire anemometry and the two reactants using chemiluminescent analysers have been made. A spatial resolution for the reactants of four Kolmogorov scales has been possible because of the novel design of the experiment. Measurements at this resolution for a reactive plume are not found in the literature. The experiment has been conducted relatively close to the grid in the region where self-similarity of the plume has not yet developed. Statistics of a conserved scalar, deduced from both reactive and non-reactive scalars by conserved scalar theory, are used to establish the mixing field of the plume, which is found to be consistent with theoretical considerations and with those found by other investigators in non-reactive flows. Where appropriate the reactive species means and higher moments, probability density functions, joint statistics and spectra are compared with their respective frozen, equilibrium and reaction-dominated limits deduced from conserved scalar theory. The theoretical limits bracket reactive scalar statistics where this should be so according to conserved scalar theory. Both reactants approach their equilibrium limits with greater distance downstream. In the region of measurement, the plume reactant behaves as the reactant not in excess and the ambient reactant behaves as the reactant in excess. The reactant covariance lies outside its frozen and equilibrium limits for this value of ND. The reaction rate closure of Toor (1969) is compared with the measured reaction rate. The gradient model is used to obtain turbulent diffusivities from turbulent fluxes. Diffusivity of a non-reactive scalar is found to be close to that measured in non-reactive flows by others.

Description: Since snow avalanches are believed to release from zones of localized weakness, knowledge of snow-strength patterns is important for determining slope stability and for applying effective avalanche-control measures. In this study, the spatial variability of snow resistance (an index of snow strength) and depth were measured and compared with terrain features on two inclined slopes. A refined instrument allowed the strength of an entire snow slab to be characterized in a short time. The spatial pattern of trees appeared to affect the pattern of snow depth at one site, where a significant linear relationship was found between snow depth and average snow resistance. These results suggest that localized snow-depth variations may be important in snow-strength genesis. Although a linear relationship existed at that site, additional factors may be critically relevant. A second site with more complex terrain features and less localized wind drifting did not show a linear relationship between depth and average resistance. Instead, complex patterns of resistance demonstrated that many factors contribute to snow resistance. In particular, die snow overlying rocks was found to have significantly weaker resistance than that in adjacent areas not over rocks.

Description: To obtain a better understanding of the compliance of saline ice, we developed a simple conceptual model of a process that presumably takes place in saline ice. Using elastic models, we assessed the role that phase transformations might play when brine is sealed into small cells during crystal growth. Cooling of a sealed brine cell, leading to the precipitation of ice, provides a mechanism for the accumulation of “large” localized stresses. Based on our analysis, this mechanism has the potential to be a significant source for the nucleation of dislocations, and can conceivably make a significant contribution to the greater compliance (softness) of saline ice relative to non-saline ice.The results of this model are consistent with the observation that laboratory-grown saline crystals sometimes display extensive differences in mechanical behavior that appear to be due to variations in the growth and storage conditions experienced by the crystals.

Description: To obtain a better understanding of the compliance of saline ice, we developed a simple conceptual model of a process that presumably takes place in saline ice. Using elastic models, we assessed the role that phase transformations might play when brine is sealed into small cells during crystal growth. Cooling of a sealed brine cell, leading to the precipitation of ice, provides a mechanism for the accumulation of “large” localized stresses. Based on our analysis, this mechanism has the potential to be a significant source for the nucleation of dislocations, and can conceivably make a significant contribution to the greater compliance (softness) of saline ice relative to non-saline ice.The results of this model are consistent with the observation that laboratory-grown saline crystals sometimes display extensive differences in mechanical behavior that appear to be due to variations in the growth and storage conditions experienced by the crystals.

Description: Since snow avalanches are believed to release from zones of localized weakness, knowledge of snow-strength patterns is important for determining slope stability and for applying effective avalanche-control measures. In this study, the spatial variability of snow resistance (an index of snow strength) and depth were measured and compared with terrain features on two inclined slopes. A refined instrument allowed the strength of an entire snow slab to be characterized in a short time. The spatial pattern of trees appeared to affect the pattern of snow depth at one site, where a significant linear relationship was found between snow depth and average snow resistance. These results suggest that localized snow-depth variations may be important in snow-strength genesis. Although a linear relationship existed at that site, additional factors may be critically relevant. A second site with more complex terrain features and less localized wind drifting did not show a linear relationship between depth and average resistance. Instead, complex patterns of resistance demonstrated that many factors contribute to snow resistance. In particular, die snow overlying rocks was found to have significantly weaker resistance than that in adjacent areas not over rocks.