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  • 1
    Electronic Resource
    Electronic Resource
    Melbourne, Australia : Blackwell Science Pty
    The @island arc 13 (2004), S. 0 
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract  Interstitial pore waters from Ocean Drilling Program Site 1150, where ∼1200 m of sub-sea-floor sediment from the upper Japan Trench forearc were recovered, were analyzed for element concentrations and Cl, Sr and B isotopes. Although chlorinity showed profound down-hole freshening to values as low as ∼310 mm (0.55 × seawater) in the deeper part of the claystone-dominated succession, both Sr and B concentrations showed an overall increase. Sr reached concentrations of up to 〉250 µm (∼3.00 × seawater), whereas B-enrichment was even stronger (3920 µm; i.e. 9.30 × seawater). The strong variations in concentration correspond to fractionation reactions in the deep, tectonically deformed part of the forearc. The heavily fractured portion of Site 1150 (from ∼700 m to the total depth of the hole) has two shear zones that very likely act as conduits that expel deep-seated fluids to the sea floor. These fluids not only showed the strongest freshening of Cl, but were also characterized by low δ37Cl measurements (down to −1.1‰), the heaviest δ11B measurements (∼40–46‰) and the least radiogenic 87Sr/ 86Sr measurements. The profound isotope anomalies together with the excursions in element concentrations suggest that diagenetic processes operate at that depth. These include clay mineral diagenesis, alteration of tephra from the Japan and Izu Arcs, and possibly transformation of biogenic silica from abundant diatoms. Given the strong enrichment of some mobile elements (e.g. Sr, B, Li), enhanced fluid flow through permeable penetrative faults through the forearc (like the shear zones at Site 1150) could be an efficient mechanism for back-flux of those elements from the deep forearc into the hydrosphere.
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  • 2
    ISSN: 1440-1738
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract  Fluids and sediments from Deep Sea Drilling Project/Ocean Drilling Program Legs (56, 57, 87 and 186) along a transect extending from the subducting plate, across the midslope and upper slope of the Japan Trench forearc were analyzed for B and B isotopes in order to assess their composition and fluid–sediment interaction. At the reference Site 436 on the subducting plate, changes in B contents and B isotopes are controlled by the lithology and diagenesis only. The midslope Sites 440 and 584 showed stronger variations in the B geochemistry, which can be related to diagenesis and tectonic dewatering along faults. The strongest changes in the B geochemistry were observed on the upper slope Sites 1150 and 1151, where profound down-hole freshening (chlorinities as low as ∼310 mmol) coincides with a B enrichment (up to 9.3 × seawater concentration). The B isotope pore fluid profile of Site 1150 displayed a bimodal variation with depth, first increasing to values more positive than seawater, then shifting to lower signatures typical for deep-seated fluids, whereas Site 1151 showed a constant B decrease with depth. Sites 1150 and 1151 sediments showed B increases with depth to values as high as ∼164 p.p.m. and isotopic compositions ranging from ∼+4 to −9‰. A linear decrease in Bsolid/Bfluid ratio, suggests that B geochemistry of the upper slope sites is controlled by fluid–rock interaction and deep-seated fluid flow, whereas constant Bsolid/Bfluid ratios were observed at the reference site on the incoming plate. This fluid overprint is probably caused by normal faults in the sediment cover which might be interconnected to deep thrusts in the underlying Cretaceous accreted wedge. This suggests that the erosive Japan Trench margin is characterized by back-flux of deep-seated, B-enriched fluids into the ocean, which is facilitated by extensional normal faulting as a result of tectonic erosion and subsidence.
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