Publication Date:
2017-10-13
Description:
We successfully employed bisphenol A and several different formyl-containing monomers as useful building blocks to construct a series of hydroxy-group-containing porous organic polymers in a sealed tube at high temperature. Fourier transform infrared and solid-state 13 C CP/MAS NMR spectroscopy are utilized to characterize the possible structure of the obtained polymers. The highest Brunauer–Emmet–Teller specific surface area of the phenolic-resin porous organic polymers (PPOPs) is estimated to be 920 m 2 g –1 . The PPOPs exhibit a highest carbon dioxide uptake (up to 15.0 wt % (273 K) and 8.8 wt % (298 K) at 1.0 bar), and possess moderate hydrogen storage capacities ranging from 1.28 to 1.04 wt % (77 K) at 1.0 bar. Moreover, the highest uptake of methane for the PPOPs is measured as 4.3 wt % (273 K) at 1.0 bar. Beilstein J. Org. Chem. 2017, 13, 2131–2137. doi:10.3762/bjoc.13.211
Keywords:
bisphenol Acarbon dioxide uptakehydrogen storageOH-containingporous organic polymers
Electronic ISSN:
1860-5397
Topics:
Chemistry and Pharmacology
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