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  • American Meteorological Society  (9)
  • American Institute of Physics (AIP)
  • 2015-2019  (10)
  • 1
    Publication Date: 2015-12-10
    Description: The electronic structure of [6,6]-phenyl C 61 butyric acid methyl ester (PCBM), poly(3-hexylthiophene) (P3HT), and P3HT/PCBM blends is studied using soft X-ray emission and absorption spectroscopy and density functional theory calculations. We find that annealing reduces the HOMO-LUMO gap of P3HT and P3HT/PCBM blends, whereas annealing has little effect on the HOMO-LUMO gap of PCBM. We propose a model connecting torsional disorder in a P3HT polymer to the HOMO-LUMO gap, which suggests that annealing helps to decrease the torsional disorder in the P3HT polymers. Our model is used to predict the characteristic length scales of the flat P3TH polymer segments in P3HT and P3HT/PCBM blends before and after annealing. Our approach may prove useful in characterizing organic photovoltaic devices in situ or even in operando .
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 2018-06-01
    Description: Global climate models play an important role in quantifying past and projecting future changes in drought. Previous studies have pointed to shortcomings in these models for simulating droughts, but systematic evaluation of their level of agreement has been limited. Here, historical simulations (1950–2004) for 20 models from the latest Coupled Model Intercomparison Project (CMIP5) were analyzed for a variety of drought metrics and thresholds using a standardized drought index. Model agreement was investigated for different types of drought (precipitation, runoff, and soil moisture) and how this varied with drought severity and duration. At the global scale, climate models were shown to agree well on most precipitation drought metrics, but systematically underestimated precipitation drought intensity compared to observations. Conversely, simulated runoff and soil moisture droughts varied significantly across models, particularly for intensity. Differences in precipitation simulations were found to explain model differences in runoff and soil moisture drought metrics over some regions, but predominantly with respect to drought intensity. This suggests it is insufficient to evaluate models for precipitation droughts to increase confidence in model performance for other types of drought. This study shows large but metric-dependent discrepancies in CMIP5 for modeling different types of droughts that relate strongly to the component models (i.e., atmospheric or land surface scheme) used in the coupled modeling systems. Our results point to a need to consider multiple models in drought impact studies to account for high model uncertainties.
    Print ISSN: 1525-755X
    Electronic ISSN: 1525-7541
    Topics: Geography , Geosciences , Physics
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  • 3
    Publication Date: 2016-10-01
    Description: This paper presents a methodology for examining land–atmosphere coupling in a regional climate model by examining how the resistances to moisture transfer from the land to the atmosphere control the surface turbulent energy fluxes. Perturbations were applied individually to the aerodynamic resistance from the soil surface to the displacement height, the aerodynamic resistance from the displacement height to the reference level, the stomatal resistance, and the leaf boundary layer resistance. Only perturbations to the aerodynamic resistance from the soil surface to the displacement height systematically affected 2-m air temperature for the shrub and evergreen boreal forest plant functional types (PFTs). This was associated with this resistance systematically increasing the terrestrial and atmospheric components of the land–atmosphere coupling strength through changes in the partitioning of the surface energy balance. Perturbing the other resistances did contribute to changing the partitioning of the surface energy balance but did not lead to systematic changes in the 2-m air temperature. The results suggest that land–atmosphere coupling in the modeling system presented here acts mostly through the aerodynamic resistance from the soil surface to the displacement height, which is a function of both the friction velocity and vegetation height and cover. The results show that a resistance pathway framework can be used to examine how changes in the resistances affect the partitioning of the surface energy balance and how this subsequently influences surface climate through land–atmosphere coupling. Limitations in the present analysis include grid-scale rather than PFT-scale analysis, the exclusion of resistance dependencies, and the linearity assumption of how temperature responds to a resistance perturbation.
    Print ISSN: 1525-755X
    Electronic ISSN: 1525-7541
    Topics: Geography , Geosciences , Physics
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  • 4
    Publication Date: 2016-05-25
    Description: The Protocol for the Analysis of Land Surface Models (PALS) Land Surface Model Benchmarking Evaluation Project (PLUMBER) illustrated the value of prescribing a priori performance targets in model intercomparisons. It showed that the performance of turbulent energy flux predictions from different land surface models, at a broad range of flux tower sites using common evaluation metrics, was on average worse than relatively simple empirical models. For sensible heat fluxes, all land surface models were outperformed by a linear regression against downward shortwave radiation. For latent heat flux, all land surface models were outperformed by a regression against downward shortwave radiation, surface air temperature, and relative humidity. These results are explored here in greater detail and possible causes are investigated. It is examined whether particular metrics or sites unduly influence the collated results, whether results change according to time-scale aggregation, and whether a lack of energy conservation in flux tower data gives the empirical models an unfair advantage in the intercomparison. It is demonstrated that energy conservation in the observational data is not responsible for these results. It is also shown that the partitioning between sensible and latent heat fluxes in LSMs, rather than the calculation of available energy, is the cause of the original findings. Finally, evidence is presented that suggests that the nature of this partitioning problem is likely shared among all contributing LSMs. While a single candidate explanation for why land surface models perform poorly relative to empirical benchmarks in PLUMBER could not be found, multiple possible explanations are excluded and guidance is provided on where future research should focus.
    Print ISSN: 1525-755X
    Electronic ISSN: 1525-7541
    Topics: Geography , Geosciences , Physics
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  • 5
    Publication Date: 2018-01-31
    Description: Global warming, in combination with the urban heat island effect, is increasing the temperature in cities. These changes increase the risk of heat stress for millions of city dwellers. Given the large populations at risk, a variety of mitigation strategies have been proposed to cool cities—including strategies that aim to reduce the ambient air temperature. This paper uses common heat stress metrics to evaluate the performance of several urban heat island mitigation strategies. The authors found that cooling via reducing net radiation or increasing irrigated vegetation in parks or on green roofs did reduce ambient air temperature. However, a lower air temperature did not necessarily lead to less heat stress because both temperature and humidity are important factors in determining human thermal comfort. Specifically, cooling the surface via evaporation through the use of irrigation increased humidity—consequently, the net impact on human comfort of any cooling was negligible. This result suggests that urban cooling strategies must aim to reduce ambient air temperatures without increasing humidity, for example via the deployment of solar panels over roofs or via cool roofs utilizing high albedos, in order to combat human heat stress in the urban environment.
    Print ISSN: 1558-8424
    Electronic ISSN: 1558-8432
    Topics: Geography , Physics
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  • 6
    Publication Date: 2017-10-04
    Print ISSN: 0894-8755
    Electronic ISSN: 1520-0442
    Topics: Geography , Geosciences , Physics
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  • 7
    Publication Date: 2015-05-27
    Description: The Protocol for the Analysis of Land Surface Models (PALS) Land Surface Model Benchmarking Evaluation Project (PLUMBER) was designed to be a land surface model (LSM) benchmarking intercomparison. Unlike the traditional methods of LSM evaluation or comparison, benchmarking uses a fundamentally different approach in that it sets expectations of performance in a range of metrics a priori—before model simulations are performed. This can lead to very different conclusions about LSM performance. For this study, both simple physically based models and empirical relationships were used as the benchmarks. Simulations were performed with 13 LSMs using atmospheric forcing for 20 sites, and then model performance relative to these benchmarks was examined. Results show that even for commonly used statistical metrics, the LSMs’ performance varies considerably when compared to the different benchmarks. All models outperform the simple physically based benchmarks, but for sensible heat flux the LSMs are themselves outperformed by an out-of-sample linear regression against downward shortwave radiation. While moisture information is clearly central to latent heat flux prediction, the LSMs are still outperformed by a three-variable nonlinear regression that uses instantaneous atmospheric humidity and temperature in addition to downward shortwave radiation. These results highlight the limitations of the prevailing paradigm of LSM evaluation that simply compares an LSM to observations and to other LSMs without a mechanism to objectively quantify the expectations of performance. The authors conclude that their results challenge the conceptual view of energy partitioning at the land surface.
    Print ISSN: 1525-755X
    Electronic ISSN: 1525-7541
    Topics: Geography , Geosciences , Physics
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  • 8
    Publication Date: 2015-10-01
    Description: Land–atmosphere coupling can strongly affect climate and climate extremes. Estimates of land–atmosphere coupling vary considerably between climate models, between different measures used to define coupling, and between the present and the future. The Australian Community Climate and Earth-System Simulator, version 1.3b (ACCESS1.3b), is used to derive and examine previously used measures of coupling strength. These include the GLACE-1 coupling measure derived on seasonal time scales; a similar measure defined using multiyear simulations; and four other measures of different complexity and data requirements, including measures that can be derived from standard model runs and observations. The ACCESS1.3b land–atmosphere coupling strength is comparable to other climate models. The coupling strength in the Southern Hemisphere summer is larger compared to the Northern Hemisphere summer and is dominated by a strong signal in the tropics and subtropics. The land–atmosphere coupling measures agree on the location of very strong land–atmosphere coupling but show differences in the spatial extent of these regions. However, the investigated measures show disagreement in weaker coupled regions, and some regions are only identified by a single measure as strongly coupled. In future projections the soil moisture trend is crucial in generating regions of strong land–atmosphere coupling, and the results suggest an expansion of coupling “hot spots.” It is concluded that great care needs to be taken in using different measures of coupling strength and shown that several measures that can be easily derived lead to inconsistent conclusions with more computationally expensive measures designed to measure coupling strength.
    Print ISSN: 1525-755X
    Electronic ISSN: 1525-7541
    Topics: Geography , Geosciences , Physics
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  • 9
    Publication Date: 2015-10-01
    Description: The role of land–atmosphere coupling in modulating the impact of land-use change (LUC) on regional climate extremes remains uncertain. Using the Weather and Research Forecasting Model, this study combines the Global Land–Atmosphere Coupling Experiment with regional LUC to assess the combined impact of land–atmosphere coupling and LUC on simulated temperature extremes. The experiment is applied to an ensemble of planetary boundary layer (PBL) and cumulus parameterizations to determine the sensitivity of the results to model physics. Results show a consistent weakening in the soil moisture–maximum temperature coupling strength with LUC irrespective of the model physics. In contrast, temperature extremes show an asymmetric response to LUC dependent on the choice of PBL scheme, which is linked to differences in the parameterization of vertical transport. This influences convective precipitation, contributing a positive feedback on soil moisture and consequently on the partitioning of the surface turbulent fluxes. The results suggest that the impact of LUC on temperature extremes depends on the land–atmosphere coupling that in turn depends on the choice of PBL. Indeed, the sign of the temperature change in hot extremes resulting from LUC can be changed simply by altering the choice of PBL. The authors also note concerns over the metrics used to measure coupling strength that reflect changes in variance but may not respond to LUC-type perturbations.
    Electronic ISSN: 1087-3562
    Topics: Geography , Geosciences , Physics
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  • 10
    Publication Date: 2019-07-15
    Description: China is several decades into large-scale afforestation programs to help address significant ecological and environmental degradation, with further afforestation planned for the future. However, the biophysical impact of afforestation on local surface temperature remains poorly understood, particularly in midlatitude regions where the importance of the radiative effect driven by albedo and the nonradiative effect driven by energy partitioning is uncertain. To examine this issue, we investigated the local impact of afforestation by comparing adjacent forest and open land pixels using satellite observations between 2001 and 2012. We attributed local surface temperature change between adjacent forest and open land to radiative and nonradiative effects over China based on the Intrinsic Biophysical Mechanism (IBM) method. Our results reveal that forest causes warming of 0.23°C (±0.21°C) through the radiative effect and cooling of −0.74°C (±0.50°C) through the nonradiative effect on local surface temperature compared with open land. The nonradiative effect explains about 79% (±16%) of local surface temperature change between adjacent forest and open land. The contribution of the nonradiative effect varies with forest and open land types. The largest cooling is achieved by replacing grasslands or rain-fed croplands with evergreen tree types. Conversely, converting irrigated croplands to deciduous broadleaf forest leads to warming. This provides new guidance on afforestation strategies, including how these should be informed by local conditions to avoid amplifying climate-related warming.
    Print ISSN: 0894-8755
    Electronic ISSN: 1520-0442
    Topics: Geography , Geosciences , Physics
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