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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This work shows preliminary results on the study of FexMn0.6−xAl0.40 alloys. It includes measurements of the temperature dependence of the ac susceptibility, zero field cooled magnetization, and Mössbauer spectroscopy. From the results obtained, the occurrence of reentrant spin glass behavior from a spin glass phase to an antiferromagnetic one for 0.2≤x≤0.35 and from a spin glass phase to a ferromagnetic one for the x=0.55 sample is proposed. Also, a normal spin glass transition was detected in the Fe range corresponding to 0.35≤x≤0.5. These results allow us to construct a magnetic phase diagram for the alloy series. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Results are presented concerning the magnetic properties at low temperatures of mechanically alloyed samples of the FexMn0.7−x Al0.3 (0.4≤x≤0.5) series. According to these results the samples were characterized as having a broad spectrum of relaxation times related to the occurrence of clustering. Also, in the particular case of the x=0.40 sample, we were able to detect a reentrant spin glass freezing transition. © 1996 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 7999-8004 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A radio frequency probe has been used to monitor changes in charge-carrier recombination centers at a SiO2/Si interface by following the steady-state photogenerated carrier concentration in the silicon. A silicon surface covered with ∼200 Å of thermal oxide was exposed to gaseous molecular hydrogen at temperatures between 135 and 300 °C. The reaction was found to occur with a nonexponential rate law that could be described by a cluster of rate constants governed by a Gaussian distribution of activation energies. At high temperatures, the dominant reaction was found to be that of "Pb" centers with a rate law that is consistent with that previously obtained by electron paramagnetic resonance. At low temperatures the reaction is dominated by the passivation of a carrier recombination center with a much lower activation energy. This new species makes up about 25% of the total recombination center concentration at the Si/SiO2 interface. Almost 20% of the recombination centers could not be passivated by H2. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 2881-2887 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The photothermal deflection technique has been used to determine the thermophysical properties of artificially aged paper samples. The deflection amplitude ratio and the phase difference of the deflection angle between front and rear surface illumination have been measured as a function of the pump beam modulation frequency, in order to avoid the dispersion effects mainly introduced by the probe beam vertical offset with respect to the sample surface. A theoretical model for the photothermal signal generation, taking into account the unavoidable light scattering occurring at the paper fibers–air interfaces, has been developed. A photothermal deflection method has been also proposed to measure the transmittance and the reflectance values of a given paper sheet, thus offering a proper constraint to the whole fitting procedure. In this way it has been possible to estimate the thermal diffusivity, the optical absorption and the scattering coefficient values of all the samples examined. A correlation between these values and the aging state of the paper has been found. © 1999 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 6165-6169 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic properties of the FexMn0.7−xAl0.30 (0.40≤x≤0.58) alloy series have been investigated by means of 57Fe Mössbauer spectroscopy and ac magnetic susceptibility measurements. From our data, we propose a magnetic phase diagram for the system which is adequately reproduced by a diluted and random-bond Ising model which was analyzed on the basis of the mean-field renormalization-group method. © 1997 American Institute of Physics.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this work, we report an ac susceptibility study of Fe0.5Mn0.2Al0.3, Fe0.5Mn0.1Al0.4, and Fe0.225Mn0.375Al0.40 disordered alloys. All the samples exhibit only one well defined peak near 58, 18, and 31 K, respectively. When the frequency of the ac field increases, the measured intensities of the peaks decrease and the maxima shift to higher temperatures, and when the dc field increases the intensity of the peaks decreases. This dependence of the position and intensity of the peaks on the field and frequency is evidence of the spin glass character of the transitions in these alloys. Mössbauer spectra at different temperatures were performed for the sample with 30 at. % Al and the plot of the adjusted mean hyperfine field versus temperature shows a kink at 53 K which is further evidence that this sample shows spin glass behavior. © 1997 American Institute of Physics.
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  • 7
    Publication Date: 2016-06-25
    Description: Hematite (α-Fe 2 O 3 ) thin films were prepared by sol-gel route and investigated for application in H 2 generation by photo-assisted water splitting. The photoelectrochemical (PEC) performance was shown to increase significantly for films deposited on SnO 2 :F/glass subjected to high temperature (T) annealing (〉750 °C). Strong correlation was found between photogenerated current, donor concentration, and Sn concentration as determined by Mott-Schottky analysis and X-ray photoelectron spectroscopy. The effects of thermal annealing and Sn addition in the resulting microstructure and optical properties of hematite films deposited on fused silica substrates were determined by a combination of structural characterization techniques and spectroscopic ellipsometry. Thermal annealing (〉600 °C) induces a higher optical absorption that is associated directly to film densification and grain growth; however, it promotes no changes in the energy positions of the main Fe 2 O 3 electronic transitions. The band gap energy was found to be 2.21 eV and independent of microstructure and of Sn concentration for all studied films. On the other hand, Sn can be incorporated in the Fe 2 O 3 lattice for concentration up to Sn/Fe ∼2%, leading to an increase in energy split of the main absorption peak, attributed to a distortion of the Fe 2 O 3 lattice. For higher concentrations, Sn incorporation leads to a reduction in absorption, associated with higher porosity and the formation of a secondary Sn-rich phase. In summary, the variation in the optical properties induced by thermal annealing and Sn addition cannot account for the order of magnitude increase of the current density generated by photoanodes annealed at high T (〉750 °C); thus, it is concluded that the major contribution for the enhanced PEC performance comes from improved electronic properties induced by the n-type doping caused by Sn diffusion from the SnO 2 :F substrate.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 8
    Publication Date: 2016-01-21
    Description: Asymptotic behavior (with respect to the number of trials) of symmetric generalizations of binomial distributions and their related entropies is studied through three examples. The first one has the q -exponential as the generating function, the second one involves the modified Abel polynomials, and the third one has Hermite polynomials. We prove analytically that the Rényi entropy is extensive for these three cases, i.e., it is proportional (asymptotically) to the number n of events and that q -exponential and Hermite cases have also extensive Boltzmann-Gibbs. The Abel case is exceptional in the sense that its Boltzmann-Gibbs entropy is not extensive and behaves asymptotically as the square root of n . This result is obtained numerically and also confirmed analytically, under reasonable assumptions, by using a regularization of the beta function and its derivative. Probabilistic urn and genetic models are presented for illustrating this remarkable case.
    Print ISSN: 0022-2488
    Electronic ISSN: 1089-7658
    Topics: Mathematics , Physics
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