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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 2814-2817 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: At room temperature, cyanoacetylene undergoes a liquid–solid transition at 70±30 MPa and further a polymerization reaction at 1.5 GPa. Raman spectra indicates that the crystal structure of the high-pressure phase is isomorphic with the monoclinic low-temperature structure (P21/m, Z=2), in which linear cyanoacetylene molecules are joined with CH NC hydrogen bonds to form infinite one-dimensional chains. The internal stretching frequency of the C–H proton donor decreases wtih increasing pressure, while that of the C 3/4 N proton acceptor increases. The librational modes associated with the rotational motions of the rigid molecules show large shifts to higher frequencies with pressure. The observed frequency shifts are attributed to the strengthening of the CH⋅⋅⋅NC hydrogen bond in the one-dimensional molecular chain.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 4565-4568 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Raman spectra were measured for liquid (0–0.7 GPa), crystalline cubic (0.7–0.9 GPa), and orthorhombic (0.9–3.5 GPa) phases in C2H2 at room temperature. For the orthorhombic phase, the high-pressure behavior of the librational and internal vibrations was obtained in a wide pressure range. The frequencies of all the librational modes increased monotonically with pressure, while those of the internal modes showed a variety of frequency shifts depending on vibrational mode. These high-pressure data will be of great use for the construction of theoretical models for the intermolecular interactions in crystalline C2H2.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 778-782 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Cyanoacetylene underwent polymerization reaction in a solid phase at pressures above 1.5 GPa. The Raman study of the reaction product showed that the polymer had a conjugated linear backbone with CN pendant groups. The Raman spectra for this substituted polyacetylene demonstrated a resonance behavior similar to that reported for trans-polyacetylene. The optical gap associated with the π–π* transition in the conjugated system was smaller than that of trans-polyacetylene, probably due to the resonance interactions between the CN triple bonds and the conjugated double bonds.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 529-534 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The mechanism and kinetics of the pressure-induced polymerization of acetylene were studied by Raman spectroscopy. The polymerization reaction occurred in the orthorhombic phase at room temperature and pressures above 3.5 GPa. Dominant formation of trans-polyacetylene suggested that the monomer underwent trans opening of the triple bond and polymerized along the diagonal of the bc plane of the unit cell. The reaction was described as an idealized one-step and one-dimensional growth process by an Avrami equation with an exponent 1.34.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 4674-4676 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: As a new technique for the measurements of the Hugoniot equation of state in laser-driven shock experiments, a line-imaging optically recording velocity interferometer system (Line-ORVIS) is developed and applied to investigate the Hugoniot of nitrobenzene. The experimental result agrees with the previous data obtained by another method. Thus, it is suggested that a Line-ORVIS is effective for the measurements of the Hugoniot equation of state in laser-driven shock experiments. © 2000 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 1216-1218 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have developed a high-current laser ion source that can provide low-charge-state ions for induction accelerators. A frequency-doubled Nd:YAG laser (λ=532 nm) irradiated a copper target with relatively low intensities of 108–109 W/cm2. The laser-produced plasma supplied a large number of Cu+ and Cu2+ ions over 1014 ions/cm2 at a distance of 10 cm from the target. We have successfully extracted high-current copper beams over 0.1 A/cm2 using an inductive acceleration module. The beam emittance measured by a pepper-pot method was about 40 πmm mrad. © 2000 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 62 (1991), S. 1609-1613 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A system for measuring the transitional dielectric constant of a ferroelectric liquid-crystal (FLC) medium aligned in a sandwich cell has been developed. The system developed in this work is shown to be capable of detecting the average molecular motion of the FLC during the course of the switching in terms of the measurement of the dielectric constant in the soft mode at 40 kHz by applying a triangular-voltage wave form ranging from 0.1 to 100 Hz to induce the Goldstone mode. This method is more accurate compared to the conventional method based on the observation of the switching current, since the latter usually accompanies the disturbances originating from ionic current, the charge/discharge as a capacitor, and electrical noise.
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  • 8
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Newly designed spectrometer arrays for ion-energy-spectrum observations are proposed and constructed in both end regions of the GAMMA 10 tandem mirror so as to obtain two dimensionally resolved radial profiles of end-loss-ion fluxes IELA, ion temperatures, and ion-confining potentials φc by the use of a single plasma discharge alone. Each spectrometer unit in the array has a specific structure with obliquely placed multiple grids with respect to the direction of the ambient plasma-confining magnetic fields. This structure is proposed to obtain precise ion-energy spectra without the disturbance of simultaneously incident energetic electrons into the array, since widely distributed "multigridded Faraday cup" signals have significant electron disturbances on ion spectra even if over a few tens of kV are applied to the electron-repeller grid. In tandem-mirror experiments, plasma-confining potentials produced by electron cyclotron heatings play one of the most critical roles in the improvement of simple-mirror confinement. Thus, diagnostics of these confining potentials using clear ion spectra are of essential importance. From these motivations, the spatial distribution details and relations of φc and IELA are investigated by the use of the novel ion spectrometers. Axisymmetric profiles of φc are found to have a good correlation with axisymmetric plugging distributions in IELA. These are consistently interpreted in terms of the Pastukhov theory of the relation of φc with IELA. Information on such specific spectrometer arrays would contribute to researchers in a wide variety of plasma devices, who employ analyzers for flux, temperature, and potential diagnostics under energetic plasma circumstances. © 2001 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 2943-2947 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The experiments of flyer acceleration by the irradiation of a high power laser are carried out using the ASHURA system at the Electrotechnical Laboratory, in which the laser has a short wavelength (∼249 nm) and a long pulse duration (∼30 ns). Three-layered targets (aluminum–polyimide–tantalum) are irradiated. The laser ablates the aluminum and polyimide layers and the rear layer (tantalum) is accelerated as a flyer. It is suggested that the tantalum flyer is in a condensed state for the duration of flight. The flyer velocity estimated from the acceleration profile is at least 8 km/s. One-dimensional numerical simulation indicates that the terminal flyer velocity becomes higher than 15 km/s. The energy conversion from laser energy to flyer kinetic energy is more efficient than that in the previous experiments using the three-layered targets with a longer wavelength and a shorter pulse duration (1–2 ns). Thus, it is found that a facility with a long pulse duration and a short wavelength is suitable for the realization of a fast flyer keeping its state in a condensed phase. © 2000 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 6235-6237 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cobalt ferrite was obtained by coprecipitation of iron and cobalt sulphates into acetone medium. The Co0.62+Fe0.43+[Co0.42+Fe1.63+]O4 cation distribution was obtained from Mössbauer spectroscopy at room temperature. Saturation magnetization of 74.1 emu/g and an intrinsic coercive field of 528 Oe were measured using a vibrating sample magnetometer. Using the moving Preisach model, separation of reversible (Mrev) and irreversible (Mirr) magnetization components was performed. The parameters η defined as η=(dMrev/dMirr)Hi and km the moving Preisach parameter expressed through the relation η=kmχrev, were evaluated in order to investigate the hysteretic behavior of Mrev. Additional characterization was done in order to investigate the elemental composition, structure, and morphology of the samples.© 2000 American Institute of Physics.
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