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  • 1
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An overview is given of recent advances toward the realization of high density, high confinement plasmas with radiating mantles in limiter and divertor tokamaks worldwide. Radiatively improved mode discharges on the Torus Experiment for Technology Oriented Research 94 (TEXTOR-94) [Proceedings of the 16th IEEE Symposium on Fusion Engineering, 1995 (Institute for Electrical and Electronics Engineers, Piscataway, NJ, 1995), p. 470] have recently been obtained at trans-Greenwald densities (up to n¯/nGW=1.4) with high confinement mode free of edge localized modes (ELM-free H-mode) confinement quality. Experiments in DIII-D [J. Luxon et al., Proceedings of the 11th IAEA Conference on Plasma Physics and Controlled Nuclear Fusion Research (International Atomic Energy Association, Vienna, 1987), Vol. 1, p. 159] divertor plasmas with a low confinement mode edge have confirmed the dramatic changes in confinement observed with impurity seeding on TEXTOR-94. Recent experiment with impurity seeding on the Joint European Torus [Rebut et al., Fusion Eng. Des. 22, 7 (1993)], and the Japanese Atomic Energy Research Institute Tokamak 60 Upgrade [Horiike et al., Fusion Eng. Des. 16, 285 (1991); Hosogane et al., Proceedings of the 16th IAEA Conference on Plasma Physics and Controlled Nuclear Fusion Research Montreal, 1987 (International Atomic Energy Association, Vienna, 1987), Vol. 3, p. 555] have extended high confinement in ELMy H-mode plasmas to higher densities. Finally, recent progress in the physical understanding of radiating mantle plasmas is summarized. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An overview of the results obtained so far for the radiative I-mode regime on the upgraded Torus Experiment for Technology Oriented Research (TEXTOR-94) [Proceedings of the 16th IEEE Symposium on Fusion Engineering (Institute of Electrical and Electronics Engineers, Piscataway, NJ, 1995), Vol. 1, p. 470] is given. This regime is obtained under quasistationary conditions with edge neon seeding in a pumped limiter tokamak with circular cross section. It combines high confinement and high β (up to a normalized beta, βn=2) with low edge q values (down to qa=2.8) and high density even above the Greenwald limit together with dominant edge radiative heat exhaust, and therefore shows promise for the future of fusion research. Bulk and edge properties of these discharges are described, and a detailed account is given of the energy and particle confinement and their scaling. Energy confinement scales linearly with density as for the nonsaturated Ohmic Neo-Alcator scaling, but the usual degradation with total power remains. No deleterious effects of the neon seeding on fusion reactivity and plasma stability have been observed. © 1997 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 29 (1986), S. 1472-1479 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A theoretical revision, motivated by experiments performed in a wide range of frequencies (0.4 GHz〈f〈4 GHz), leads to the accurate prediction in a greatly extended domain of the densities at which temperature (Tonks–Dattner) resonances occur in a plasma column. It is shown that a two-fluid scalar perturbed pressure plasma description using the radial density profile determined from positive column plasma discharge theory perfectly explains the experiments at low densities, a domain within which Parker, Nickel, and Gould [Phys. Rev. Lett. 11, 183 (1963); Phys. Fluids 7, 1489 (1964)] have computed the corresponding theoretical curves for the first two resonances. Introducing new dimensionless parameters, a new representation of these curves is developed, which results in a general linear law permitting a direct comparison with experimental results over a much wider density domain than was previously the case. Moreover this new law permits the direct measurement of the electron temperature and of the average density independently of each other using the plot of a single resonance.
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  • 4
    Publication Date: 2015-08-08
    Description: Photo-induced electron transfer between poly-(3-hexylthiophene) (P3HT) and small (2.4 nm) PbS quantum dots (QDs), capped by different ligands, was studied by picosecond and femtosecond time-resolved fluorescence and by photo-induced absorption (PIA) measurements. In line with previous experiments, we observed that the efficiency of the quenching of P3HT by PbS QDs increased upon decreasing the average thickness of the ligand shell. This trend was also observed in the PIA spectra and in prior work on the performance of photovoltaic devices where the active layer was a blend of P3HT with PbS QDs capped by different ligands. Combining the pico- and femtosecond fluorescence decays showed that the quenching in blend films of P3HT and PbS QDs treated with 1,4-benzenedithiol occurred over a broad time scale ranging from tens of femtoseconds to hundreds of picoseconds. This complex kinetics was attributed to exciton hopping followed by electron transfer to the conduction band of the QDs. We also compared the wavelength dependence of the internal quantum efficiency (IQE) in the hybrid photovoltaic devices to those devices where the photoactive layer consists of PbS QDs only. Although excitation in the first excitonic transition of the PbS QDs yielded a similar IQE in both devices, the IQE of the hybrid devices tripled at wavelengths where also P3HT started to absorb. This suggests that upon excitation of P3HT in the latter devices, charge generation occurs by photo-induced electron transfer from P3HT to the QDs rather than by energy transfer to the QDs followed by exciton dissociation in the QDs.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 5
    Publication Date: 2014-09-04
    Description: Different approaches of surface modification of the quantum dots (QDs), namely, solution-phase (octylamine, octanethiol) and post-deposition (acetic acid, 1,4-benzenedithiol) ligand exchange were used in the fabrication of hybrid bulk heterojunction solar cell containing poly (3-hexylthiophene) (P3HT) and small (2.4 nm) PbS QDs. We show that replacing oleic acid by shorter chain ligands improves the figures of merit of the solar cells. This can possibly be attributed to a combination of a reduced thickness of the barrier for electron transfer and an optimized phase separation. The best results were obtained for post-deposition ligand exchange by 1,4-benzenedithiol, which improves the power conversion efficiency of solar cells based on a bulk heterojunction of lead sulfide (PbS) QDs and P3HT up to two orders of magnitude over previously reported hybrid cells based on a bulk heterojunction of P3HT:PbS QDs, where the QDs are capped by acetic acid ligands. The optimal performance was obtained for solar cells with 69 wt. % PbS QDs. Besides the ligand effects, the improvement was attributed to the formation of an energetically favorable bulk heterojunction with P3HT, when small size (2.4 nm) PbS QDs were used. Dark current density-voltage ( J-V ) measurements carried out on the device provided insight into the working mechanism: the comparison between the dark J-V characteristics of the bench mark system P3HT:PCBM and the P3HT:PbS blends allows us to conclude that a larger leakage current and a more efficient recombination are the major factors responsible for the larger losses in the hybrid system.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 6
    Publication Date: 2015-03-07
    Description: The charge carrier transport in thin film hybrid solar cells is analyzed and correlated with device performance and the mechanisms responsible for recombination loss. The hybrid bulk heterojunction consisted of a blend of poly(3-hexylthiophene) (P3HT) and small size (2.4 nm) PbS quantum dots (QDs). The charge transport in the P3HT:PbS blends was determined by measuring the space-charge limited current in hole-only and electron-only devices. When the loading of PbS QDs exceeds the percolation threshold, a significant increase of the electron mobility is observed in the blend with PbS QDs. The hole mobility, on the other hand, only slightly decreased upon increasing the loading of PbS QDs. We also showed that the photocurrent is limited by the low shunt resistance rather than by space-charge effects. The significant reduction of the fill factor at high light intensity suggests that under these conditions the non-geminate recombination dominates. However, at open-circuit conditions, the trap-assisted recombination dominates over non-geminate recombination.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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