Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
93 (1990), S. 8260-8269
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The magnetic-field dependence of hyperfine coupling-induced radical pair processes in micelles is studied theoretically. We show that experimental observations on reaction dynamics of triplet benzylic radical pairs can be explained by a hyperfine interaction mechanism when the exchange interaction between the unpaired spins in the radical pair confined to a micelle is taken into account. The theoretical description applied involves a stochastic Liouville equation. The time-dependent solutions of the stochastic Liouville equation qualitatively reproduce the observed magnetic-field and isotope dependence of micellar radical pair decay.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.459306
Permalink
|
Location |
Call Number |
Expected |
Availability |
