ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The rotational structure of the 1–0, 0–0, and 0–1 bands of the Baldet–Johnson (B 2Σ+–A 2Πi) system of the molecular ion 13C18O+, excited in the cathode glow of a hollow-cathode discharge tube, was recorded in the spectral region 3700–4225 A(ring) and analyzed. An effective Hamiltonian proposed by Brown et al. [J. M. Brown, E. A. Colbourn, J. K. G. Watson, and F. D. Wayne, J. Mol. Spectrosc. 74, 294 (1979)] was used to obtain the molecular constants from the wave number data of these three bands. These molecular constants were first "merged'' together and the resulting constants were then "merged'' with those of the comet-tail (A 2Πi–X 2Σ+) system of 13C18O+ recently reported by us [C. V. V. Prasad and S. P. Reddy, J. Chem. Phys. 90, 3010 (1989)] to obtain a unique set of constants for the X 2Σ+, A 2Πi, and B 2Σ+ states. Some of the derived constants of 13C18O+ (in cm−1) are for X 2Σ+: Be=1.794 28(4), αe=0.016 61(3), ωe =2110.27(2), and ωexe =13.81(6); for A 2Πi : Be=1.441 92(4), αe=0.016 76(1), ωe =1488.99(2), ωexe =12.454(7), and ωeye =0.0279(8); for B 2Σ+: Be=1.632 62(4), αe=0.025 49(2), ωe=1657.56, and ωexe =27.42.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.457647
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