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  • 1
    Electronic Resource
    Electronic Resource
    The electric dipole moment and hyperfine interactions of KOH (1996)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 3361-3365 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A molecular beam spectrometer has been used to observe the hyperfine spectrum and determine the electric dipole moment of the KOH molecule. This EDM had never been measured previously, although theoretical calculations had been made. A refined line shape fitting procedure has helped make possible this determination from the molecular beam hyperfine spectrum. The value of the EDM, which we found for the ground vibrational state, is 7.415±0.002 debye. The hyperfine constants, including the potassium nuclear quadrupole, both spin–rotation interactions, and the tensor and scalar spin–spin interactions have been determined for several vibrational states. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.472221
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  • 2
    Electronic Resource
    Electronic Resource
    Space-charge-perturbed electrophoresis in nonpolar colloidal dispersions (1996)
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 6796-6803 
    Details
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: This paper reports the observation of bipolar, space-charge-perturbed transport in colloidal dispersions using an experimental technique that time-resolves electrophoresis in nonpolar colloidal systems. Unlike existing methods for studying electrophoresis, this technique can be applied to dispersions of diverse types and concentrations over a wide range of electric fields, including the space-charge-perturbed conditions often encountered in practical applications. The phenomenon is investigated as a special case of dielectric relaxation in a leaky capacitor connected in series to a perfect one. Using the first principle charge transport theory, such dielectric relaxation, occurring under the non-Ohmic supply and space-charge-perturbed transport conditions, is shown to differ from that expected by the conventional equivalent-circuit treatment. The combined theoretical analysis and the experimental technique provides a means for independently determining the densities and mobilities of charged species in such systems. Using a liquid developer for electrography as a prototype system, results are presented that illustrate the power of the technique as a new tool to provide new insights into the generic transport and generation mechanisms of charged species in colloidal systems. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.363807
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