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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 511-513 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: On lowering the chemical potential of diatomic oxygen, the compound YBa2Cu4O8 was found to decompose into a mixture of YBa2Cu3O6+x and CuO. The equilibrium oxygen potential corresponding to this decomposition has been measured from 870 to 1150 K using a solid-state cell incorporating yttria-stabilized zirconia as the solid electrolyte and pure oxygen at a pressure of 1.01×105 Pa as the reference electrode: Pt, O'2||YBa2Cu4O8+YBa2Cu3O6+x+CuO(parallel)(Y2O3) ZrO2(parallel)O2(1.01×105 Pa), Pt. The low oxygen potential boundary for the stability of YBa2Cu4O8 can be represented by ΔμO2=−238 900+207.7 T(±800) J mol−1. At the standard pressure of oxygen (1.01×105 Pa) the decomposition occurs at 1150 K.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2014-12-25
    Description: The thermal and mechanical, near-resonant responses of particulate composite plates formed from hydroxyl-terminated polybutadiene (HTPB) binder and varying volume ratios of ammonium chloride (NH 4 Cl) particles (50, 65, 75%) are investigated. Each test specimen is clamped and forced with three levels of band-limited, white noise inertial excitation (10–1000 Hz at 1.00, 1.86 and 2.44 g RMS). The mechanical response of each plate is recorded via scanning laser Doppler vibrometry. The plates are then excited at a single resonant frequency and the thermal response is recorded via infrared thermography. Comparisons are made between the mechanical operational deflection shapes of each plate and spatial temperature distributions, with correlation seen between the observed level of strain, as visualized by strain energy density, and heat generation. The effect of particle/binder ratio on both the thermal and mechanical responses is discussed. Acquired results are also compared to an analytical model of the system. The observed thermomechanical effects render an improved understanding of the thermomechanics of plastic-bonded composites, an essential step in support of the development of new technologies for the vapor-based detection of hidden explosives.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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