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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 4438-4444 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A small scale inductive pulsed power (IPP) generator with copper wire fuses as an opening switch has been applied to an argon gas-puff z-pinch plasma which can be used as a point source for x-ray lithography. The IPP generator with fuses supplies a driving current of 60 kA in 400 ns to the z-pinch plasma. Without fuses, the generator serves as a conventional fast bank (FB) system which supplies z-pinch current of 60 kA in 4.5 μs. Characteristics of the z-pinch implosions in IPP and FB systems are investigated and compared. The result obtained shows that the intensity of soft x rays emitted from hot spots in both systems is decreased gradually with longer delay time, which is the time difference between energizing a gas-puff actuator and a primary current trigger. Dual axis pinhole imagery shows that the hot spot size is 0.8 mm in diameter in both systems. However, the average radial displacement of hot spots is 0.9 mm in the FB system and it is reduced to 0.4 mm in the IPP system. Optical framing camera images have confirmed that the radial distribution of hot spots is due to kink instability. The framing images also show that the imploding plasma in the FB system which has a pinch size of 2.2 mm in diameter can be further compressed to 1.3 mm. The IPP system can suppress the kink instability of pinch plasma and increases plasma column uniformity along the z axis. This suggests that the IPP system can improve the stability of the pinched plasma so as to minimize the end-on source size for x-ray lithography applications. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2014-12-11
    Description: A Si etching process has been investigated with reactive neutral beams (NBs) extracted using a low acceleration voltage of less than 100 V from CF 4 and Ar mixed plasmas. The etched Si profile shows that the etching process is predominantly anisotropic. The reactive NB has a constant Si etching rate in the acceleration voltage range from 20 V to 80 V. It is considered that low-energy NBs can trigger Si etching because F radicals adsorb onto the Si surface and weaken Si–Si bonds. The etching rate per unit beam flux is 33 times higher than that with Ar NB. These results show that the low-energy reactive NB is useful for damage-free high speed Si etching.
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 631-641 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The structure of the rotator phase and the phase transitions in n-alcohols C17, C18, and their mixtures are studied by differential scanning calorimetry (DSC) and by x-ray diffraction. Both the heating and cooling phase diagrams of the binary system are determined. During cooling, a new intermediate phase α' is observed under a temperature region of the usual rotator phase α. These α and α' phases are found to correspond to the rotator-II phase and the rotator-I phase, respectively, of n-paraffins. The dynamical crystal structure in the α phase is revealed by investigation of the diffuse scattering from the single crystal. The characteristic diffuse scattering observed originates from molecular fluctuations due to the translation along and the rotation around the molecular axes. Both modes of the molecular motions are studied separately from the diffuse scattering on the first and on the second layer lines. The translational disorder is described by the averaged relative translation between the nearest neighbor molecules; it is found to be as much as 20% of the repeat period 2.55 A of the polymethylene chain. On the other hand, it is found that the rotational disorder of the molecules is much smaller than the translational. The molecules are found to have a tendency to make their molecular planes parallel. It is suggested that the crystal in the rotator phase consists of domains, within which the molecules are ordered with respect to the orientations of their molecular planes but are making fairly active translations. Such structural model of the rotator phase is found to be quite consistent with that obtained in our recent computer simulation.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 2513-2521 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the first observation of the 1g(3P2) ion-pair state of Br2 by the optical–optical double resonance technique. This state is accessible from the ground state stepwisely in the pump–probe excitation scheme, 1g(3P2) –A 3Π(1u) –X 1Σ+g. The double resonance transitions were interpreted on the basis of the optical selection rules. Emission spectra of the 1g(3P2) –A 3Π(1u) system were interpreted to establish the absolute v′ numbering of the ion-pair state from the Franck–Condon factor calculations. Observations were made on the v′=0 through v′=10 levels of the 79Br2 isotope species. The molecular parameters obtained are Te =49 390.364(16), ωe =151.704(10), ωexe =0.4169(24), ωeye =4.7(16)×10−4, Be =0.042 1840(73), αe =1.5209(61)×10−4, De =1.32(10)×10−8, and q=4.91(19)×10−5 (all in cm−1 with 3σ in parentheses).
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 40 (1999), S. 3791-3826 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: We construct a free field realization of vertex operators of the dilute AL models along with the Felder complex. For L=3, we also study an E8 structure in terms of the deformed Virasoro currents. © 1999 American Institute of Physics.
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  • 6
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have observed the stimulated emission from the 1MLCT state of Ru(bpy)2(dcbpy) adsorbed on SnO2 nanocrystal by femtosecond pump–probe spectroscopy under applied bias (Vex) for the first time. The luminescence from the 3MLCT state has been also observed by picosecond time-resolved measurement. Observed lifetimes of the stimulated emission and the luminescence are 70 fs and 130 ps, respectively, at zero applied voltage. Both these lifetimes continuously increase with increasing negative bias and reach 320 fs (stimulated emission) and 6 ns (luminescence) at Vex=−0.7 V. The change in the lifetime of luminescence and of stimulated emission under negative applied bias is considered to be due to the change in the interfacial CS rate, although the possibility of the bias dependent desorption of the dye cannot be completely excluded. We analyzed the result by assuming that the changes in the lifetimes of the stimulated emission and the luminescence are due to the change in the interfacial CS rate constant. This analysis shows that interfacial CS occurs from both the 1MLCT and 3MLCT states. The competition between CS and intersystem crossing (ISC) from 1MLCT occurs in ∼100 fs time region. Assuming there is no nonradiative relaxation pathways from 1MLCT except for CS and for ISC, the rate constant of ISC was estimated to be 1/(320 fs). The ratio of the numbers of electrons injected from the 1MLCT and the 3MLCT states was 0.76:0.22. This means that unnegligible number of electrons are injected to SnO2 from the 1MLCT state. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 5012-5015 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The swelling and shrinking kinetics of thin-plate poly(N-isopropylacrylamide) gels with rectangular surfaces under mechanical constraint was investigated. The top and bottom surfaces were chemically clamped on the glass plates, and the gel could swell and shrink only along the thickness direction between two swollen states by the temperature jumps. The time evolution of the thickness was well described by a single exponential except immediately after the temperature change. The characteristic time was found to depend on the lengths of the constrained surfaces and not on the thickness at the time of sample preparation. The swelling and shrinking kinetics of the one-dimensional thickness direction is essentially governed by the relaxation of the polymer network in the two-dimensional direction along the surface. © 2001 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 6603-6607 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The third-order polarizability γ of the C60 molecule has been calculated for the third harmonic generation at several incident frequencies using two different schemes of the sum-over-state (SOS) method, and the contribution of the low-lying singlet excited states as the second intermediate states has been analyzed. The group-theoretical analysis of the SOS expression clarifies that the 1Ag and 1Hg states are the only states that contribute to the γ as the second intermediate states. For the numerical analysis, the electronic states previously obtained in the semiempirical CNDO/S approximation with the singly and doubly excited configuration interaction method are used. It is found that the inclusion of the doubly excited configurations is essential in evaluating the γ. Those excited 1Ag and 1Hg states which make significant positive contributions to the γ are practically the doubly excited states. In order to secure error-free SOS calculations, equivalent but independent calculations have been also carried out with the frequency-dependent moment method. © 2000 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 41 (2000), S. 1244-1293 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: For independent nearest-neighbor bond percolation on Zd with d(very-much-greater-than)6, we prove that the incipient infinite cluster's two-point function and three-point function converge to those of integrated super-Brownian excursion (ISE) in the scaling limit. The proof is based on an extension of the new expansion for percolation derived in a previous paper, and involves treating the magnetic field as a complex variable. A special case of our result for the two-point function implies that the probability that the cluster of the origin consists of n sites, at the critical point, is given by a multiple of n−3/2, plus an error term of order n−3/2−ε with ε〉0. This is a strong version of the statement that the critical exponent δ is given by δ=2. © 2000 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 5548-5553 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Isomerization of 2-vinylanthracene in the first excited singlet state has been studied over wide solvent-viscosity ranges. Steady-state and time-resolved fluorescence spectroscopy is used to determine the isomerization rate in compressed liquid solutions and in supercritical fluids. The "Kramers turnover,'' which indicates the transition of kinetics from "energy diffusion control'' regime to "spatial diffusion control'' regime, is clearly observed. The turnover behavior can be expressed by a single curve which bridges the two extremes by an additive form. The activation energy shift between the two extremes is 1.6 kJ/mol. Activation volumes at large viscosity in compressed liquid solutions are also discussed. © 1995 American Institute of Physics.
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