Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
103 (1995), S. 3696-3704
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Employing the path integral formalism, we study a quantum (test) system coupled to an environment consisting of infinitely many harmonic oscillators. A simple semiclassical approxi- mation, in which only real classical trajectories are required, is used to derive the propagator of the reduced density matrix for Ohmic dissipation and high temperatures. The inclusion of a summation over trajectories with the correct Maslov phases in the final expression for the propagator permits investigation of nonharmonic test systems. In a numerical example for a Morse oscillator interacting with a high temperature heat bath, the semiclassical result, obtained by the method described here, correctly displays the suppression of quantum behavior as observed in the exact calculation. © 1995 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.470046
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