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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 8764-8770 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A study of the Li+HCl reaction has been carried out using classical trajectories. A comparison with detailed scattering data has given sufficient indications on the accuracy of the overall shape of a previous bond order potential energy surface derived from ab initio values. Calculations performed on a new bond order surface having a lower transition state has led to a more realistic estimate of the threshold energy and the ratio between high and low collision energy reactive cross sections. The comparison has been extended to rate constants. Calculated values agree with measured ones within the given error boundaries
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 7238-7241 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Reactivity of the Li+HF system has been calculated by adapting a light–heavy–light infinite order sudden computational scheme. The improvement of the numerical procedure as well as the restructuring of the computational code for use on supercomputers has allowed a successful extended comparison of calculated vs measured cross sections.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 5410-5416 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A generalization of the rotating bond order model potential is discussed. The new functional representation is used for fitting the ab initio potential energy values of the H+H2 system and the main features of a LEPS potential energy surface for the N+N2 system. For H+H2 we analyze the accuracy obtained when fitting the ab initio potential energy values using different functional representations. For N+N2 we examine the deviation of some dynamic and kinetic properties calculated on the new model potential from those obtained from the original LEPS. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 3059-3067 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A quasiclassical trajectory test of some potential energy surfaces designed for the Li+HF reaction is reported. A comparison of scattering quantities with experimental data has allowed the selection of a surface sufficiently accurate for reproducing reactive cross sections and detailed experimental data.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1225-1236 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: It is demonstrated that a closed delayed equation for the phase of the electric field can be used to describe accurately the transient switch on of a laser with external feedback when it can be described by field evolution equations. In contrast, it is shown that several more severe approximations to the dynamics, including an adiabatically evolving potential for one-dimensional relaxation dynamics (which had previously been used to accurately predict the laser linewidths for the steady-state solutions) fail to reliably describe the final state selection during transient switch on of the laser, the delay-induced oscillatory approach to the chosen state, and features of the amplitude and frequency spectra near multiples of the external cavity mode spacing which may be important for the stability and switching dynamics of the steady states that correspond to excitation of different external cavity resonances.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 3572-3587 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The shock response of single crystals of the explosive pentaerythritol tetranitrate was studied from 3.4 to 19 GPa. Four orientations, 〈110〉, 〈001〉, 〈101〉, and 〈100〉 were studied. The shock Hugoniot and shock initiation sensitivities were measured in wedge tests. Intermediate velocity transitions were noted. A sensitivity anomaly near 4 GPa was discovered for 〈110〉 orientations. Chemiluminescent phenomena associated with this anomaly were studied using framing photography and uv/visible spectroscopy. Both plane-wave explosive and gas-gun impact experiments were done. Analysis of the steric hindrance occurring during edge dislocation motion in the shear flow associated with shock-induced uniaxial strain was done. The results corroborate the hypothesis that the orientation dependence of shock initiation sensitivity is due to the anisotropy of plastic flow, that is, the relative ease of slip in different orientations.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 836-837 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Purposely introduced pinholes can be processed so as to produce nearly spherical or paraboloidal depressions in (100) silicon by a two-step chemical etching procedure in KOH:water solutions. Regular arrays of f/1–f/10 specularly reflecting micromirrors can be fabricated.
    Type of Medium: Electronic Resource
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