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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 1702-1705 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A new implementation of the complex coordinate method is presented. It is a combination of the stabilization method with the partitioning technique, supplemented with the idea of dilation-adapted basis sets. This method is designed to handle large scale calculations of many-electron resonant states, as to minimize the amount of complex arithmetics and in particular to avoid the diagonalization of the complex eigenvalue problem. Both a resonant eigenvalue and a corresponding eigenvector are obtained. An application to the lowest doubly excited autoionizing states of helium is presented.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 2674-2679 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The energy, momentum, and angle dependent cross section for the inelastic scattering of electrons from atoms has been calculated in the form of the Bethe surface, by means of the complex-coordinate technique which avoids the explicit calculation of the final scattering states by extracting the necessary scattering information from the expectation value of the resolvent with respect to the initial (ground) state. An application to the scattering of electrons from the helium atom is presented. Both the global structure and the spectral properties are obtained, and the method appears to be especially successful in describing the fine structure due to the presence of the doubly excited resonant states. The interaction between the resonant and nonresonant (background continuum) contributions to the cross section is automatically included, and in the optical limit is seen to result in the typical Fano shapes of the resonant profiles. For higher momentum transfers the development of Bethe ridge and the optically forbidden spectral lines is followed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 6732-6737 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A L2 discretization of the continuum within the scope of the complex coordinate technique is employed to obtain the differential cross section for two-photon ionization of atomic systems. The method avoids explicit construction of the continuum final state and instead dispersion relations are utilized to evaluate the appropriate transition matrix element controlling the process, to second order of perturbation theory in the nonrelativistic dipole approximation. The method is applied to the two-photon ionization of atomic hydrogen.
    Type of Medium: Electronic Resource
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