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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 7068-7078 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have studied a series of bichromophores of the form A-(CH2)n-D where A is a 9-anthryl group, D is either a N-methylanilino group or a N-methyl-p-methoxyanilino group, and n=1,2,3, or 4. The fluorescence excitation and emission spectra of these molecules have been observed in a supersonic jet and in a variety of solvents. In the gas phase, in the n=1 and n=3 molecules, and in an extended conformer of the n=4 molecules interactions are weak resulting only in a slightly redshifted anthracene spectrum. No redshifted emission was observed in these cases. For the n=2 molecules and a second conformer of the n=4 molecules we observed a redshifted emission in the gas phase. This emission is assigned as coming from a charge transfer (CT) state or exciplex. On the basis of the excitation and emission spectra we observed two different pathways to reach the CT state. For the molecules with donor N-methyl-N-alkylaniline, excitation took place to the locally excited (LE) state followed by relaxation to the CT state. For the molecules with donor N-methyl-N-alkyl-p-methoxyaniline, the CT state was low enough to interact with the ground state forming an intramolecular electron–donor–acceptor (EDA) complex. From this EDA ground state direct excitation to the CT state occurred. In the molecule with n=2 and donor N-methyl-p-methoxyaniline the EDA interaction is very weak allowing excitation to the LE state as well as to the CT state. This set of molecules exhibits the full range of spectroscopic behavior expected in bichromophores.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 71 (2000), S. 1564-1568 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This article presents a simple measuring apparatus that is capable of measuring column density and absolute photoabsorption cross sections. The apparatus includes a simple high-temperature heatpipe furnace, an MKS Instruments Baratron, a hydrogen discharge lamp, and an optical detecting system. The heatpipe furnace provides an absorbing medium with a steady total pressure in a closed system so that the column density can be obtained using the ideal gas relation. The apparatus is designed for a working temperature range below 1000 K and a pressure range up to 10 Torr. Encountered experimental difficulties and their found solutions will be discussed in detail. In this work, the absolute photoabsorption cross section of Mg is measured near the 3s threshold using this apparatus. The absolute photoabsorption cross section result at the 3s threshold, which is 2.1±0.3 Mb, is in good agreement with hook method data (2.36 Mb). © 2000 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 1999-2011 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: At the Rijnhuizen tokamak project a double pulse multiposition Thomson scattering diagnostic has been operational since 1996. It has been installed for the study of small scale structures in electron temperature (Te) and density (ne). This diagnostic measures Te and ne with high spatial resolution (3 mm full width at half maximum, i.e., 2% of the minor radius) and high accuracy (3%–4% of Te and 2%–3% of ne in the range of 50 eV–6 keV and ne=5×1019 m−3.) In this article an extensive error analysis is performed on both statistical and systematic deviations. It is found that the instrument function of the detection branch has a smoothing effect on the noise. This reduces the statistical error on the Te and ne measurements on each spatial position, because the resolution of the instrument is oversampled. The long tail of the instrument profile of the entire diagnostic has a significant effect on the systematic deviations in the Te and ne determination. However, it does not affect the relative size of the small scale structures on Te and ne, and for this this reason does not hamper the study of these structures. © 1999 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 59 (1988), S. 1605-1607 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Since 1981, we have proposed and investigated spectral analysis of the harmonics of ion cyclotron emission (ICE) as a means of monitoring the energy content of α particles confined in a magnetic fusion device. A pair of crown probe antennas have been constructed for TFTR to collect ICE spectra and will be installed on that device in the near future. The design of this ICE spectroscopy system is described. Also, some calculations of ICE electromagnetic fluctuations in the ICRF, due to newborn α particles with a distribution function appropriate to typical fusion reactor parameters, are discussed. The calculated emission spectra are quite distinct from that of blackbody radiation.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 95 (1991), S. 711-713 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 5871-5873 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The pressure effect on the superconducting transition temperature (dTc/dP) has been measured for Dy1−xPrxBa2Cu3O7−δ with x=0, 0.02, 0.05, 0.1, 0.15, 0.2, and 0.3. Although the Tc suppression by Pr is in a different fashion for Y1−xPrxBa2Cu3O7−δ and Dy1−xPrxBa2Cu3O7−δ, the dTc/dP is similar in these two systems, with respect to x. The measured dTc/dP is positive at small x but becomes negative for x≥0.2 which is associated with the pressure effect on the normal-state resistivity (1/R)(dR/dP). The positive (1/R)(dR/dP) at x≥0.2 indicates that the number of carriers is decreasing under pressure and it supports the picture of hole localization through the hybridization of Pr-4f and O-2p bands. The mechanical pressure has a negative effect on Tc for x≥0.2, but chemical pressure has a positive effect on Tc according to the results of chemical substitution. This suggests that the large R (=rare earth element) may possibly reduce the Pr-O distance, and increase the hybridization of Pr-4f and O-2p bands.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 492-494 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Coatings of YBa2Cu3O7−y were deposited by electrophoresis on Cu, Ag, polycrystalline Al2O3, and single-crystal MgO and YSZ substrates. Acetone was used as the electrophoretic vehicle and a field of 500 V/cm was applied in the deposition process. The deposited coatings were fired in air at or above 900 °C. For coatings on Ag, MgO(Ag), and YSZ(Ag) substrates, sharp superconducting transitions at ∼90 K were obtained. Intermediate layers were formed on Cu, Al2O3(Al), and YSZ(Ag) substrates as a result of interfacial reactions during firing. The interfacial reactions affected the superconducting transition and also led to the development of a preferred orientation in the coating.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6536-6536 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: To make true large applications of high temperature superconductors (HTS's), one requires not just a large critical current density (Jc) and high transition temperature (Tc), but also large total current (Ic is the JcA, where A is the cross sectional area) and large total current length (Icl where l is the length) of an HTS which can be further shaped into a usable form, e.g., disk, bar, cylinder, or wire. The large anisotropy, short coherence length, and large penetration depth of HTS's pose serious challenges to efforts to enhance the Jc, Ic, or Icl of HTS's. Melt-texturing technique by slow cooling through the peritectic temperature has proven to be effective in removing large-angle grain boundaries detrimental to Jc in HTS samples of small size; but many problems remain. The short coherence length reduces the pinning potential for magnetic fluxoids and also renders ineffective the nonsuperconducting dispersion in the HTS matrix to enhance pinning through the conventional metallurgical method. Defects of atomic scale acting as pinning centers to raise Jc have been obtained through irradiation by high energy particles and in situ chemical decomposition. However, in most of these studies Jc was determined only by magnetic measurements, not by transport techniques. We have therefore carried out a systematic study on the melt-texturing of HTS's in both bulk and wire forms. We have identified major processing parameters in reducing the microcracks, increasing the dimensions of the bulk HTS, controlling the grain alignment, improving the chemical homogeneity, enhancing the processing rate, and controlling the epitaxial growth of HTS's in an Ag sheath. Effects of irradiation by various types of particles of different energies on Jc determined both by magnetic and transport techniques have also been examined. These results will be presented and discussed, following a brief review on the current status of bulk and wire processing of HTS's.
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: It has been demonstrated that the linear-chain charge-transfer salt, decamethylferrocenium tetracyanoethanide (DMeFc)(TCNE), is a ferromagnet with a transition temperature of ∼4.8 K. This low-temperature 3D ordering has been attributed to a strong intrachain and a weak interchain interaction. To study these interactions, we have determined the Tc up to 20 kbar by measuring the ac susceptibility χ at low frequency. Our results show that the Tc increases with pressure at a rate of ∼0.22 K/kbar, while the χ peak indicative of the ferromagnetic transition continues to decrease rapidly. A small peak was also detected above the main transition at pressures above 3 kbar. This new peak persists even after the pressure is removed. The result from dc magnetization suggests that this corresponds to a metamagnetic state. For the first time, we have observed pressure-induced phase-transition in this material.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 64 (1994), S. 520-522 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report results on the temperature dependence of the trap field BT and the thermal instability (flux jump) field Hfj in single-grain YBa2Cu3O7−δ disks. Above 45 K, BT is limited by the critical current density Jc and BT=BT0(1−T/Tc)q with q≈1.67. At 4.2 K, the first flux jump field Hfj of ∼3 T is about an order of magnitude larger than theoretical prediction based on the adiabatic thermal instability model. We also find that the occurrence of large flux avalanches probably causes severe microcracking damages to the superconducting disks.
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