Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
90 (1989), S. 5205-5207
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The codeposition of Ne/HCl mixtures at 5 K leads to the formation of a large yield of (HCl)3 which exhibits one sharp fundamental at 2801.5 cm−1 with chlorine isotopic splittings at 2800.2 and 2799.4 cm−1. Deuterium substitution gives rise to the three stretching fundamentals for (HCl)2(DCl) and (HCl)(DCl)2 with resolved chlorine isotopic splittings that identify these clusters. The neon matrix observations confirm the argon matrix assignments and characterization of (HCl)3 as a C3h cyclic species by the Perchard group and predict a strong gas phase band at 2816±3 cm−1.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.456539
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