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  • American Institute of Physics (AIP)  (5)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 5454-5462 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: New experimental data are presented for the thermal conductivity of ethane. The thermal conductivity has been measured with a parallel-plate method as a function of temperature along eleven different isochores so as to obtain detailed information on the enhancement of the thermal conductivity in the critical region. The experimental results appear to be consistent with a recently proposed theoretical equation that accounts for both the asymptotic and nonasymptotic critical behavior of the thermal conductivity of fluids.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 6944-6963 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the thermal conductivity of argon at temperatures from 302 K down to 150.8 K and at densities up to 25 mol L−1. The data were obtained with a steady-state method and we employed a guarded parallel-plate apparatus designed especially for investigating the thermal conductivity of fluids in the critical region. To interpret the data in the critical region a scaled crossover equation of state for argon in the critical region has been constructed. Equations for the thermal conductivity and viscosity of argon as a function of density and temperature are presented.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 60 (1989), S. 3466-3474 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A description is given of the construction and operating procedure of a parallel-plate apparatus for the measurement of the thermal conductivity coefficient of fluids. This instrument can be operated at pressures up to 150 MPa and at temperatures down to 77 K. The use of platinum resistance temperature sensors allows measurements with temperature differences between upper and lower plate as small as 1 mK, which together with the small plate separation of 155 μm, makes the instrument suitable for both the normal fluid region as well as for the region very close to the critical point. The complete working equations for the instrument are presented and evaluated.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 105 (1996), S. 10535-10555 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the thermal conductivity of methane at temperatures from 308 K down to 190.585 K, which is just 21 mK above the critical temperature, and at densities up to 14 mol L−1. The data were obtained with an improved guarded parallel-plate cell with a new cryostat that was built especially for measurements in the critical region of methane. The new experimental data have a higher accuracy than those reported previously in the literature and enable us to examine the validity of the currently available theoretical description of the asymptotic and nonasymptotic behavior of the thermal conductivity of fluids in the critical region. Equations for the thermal conductivity of methane in a wide range of temperatures and densities are also presented. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 717-736 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the thermal conductivity of an equimolar mixture of methane and ethane in the vicinity of the critical point. The new experimental data confirm that the thermal conductivity of a mixture does not diverge at the critical point but crosses over to a finite limiting behavior at the critical point. A quantitative representation of the thermal-conductivity data has been obtained in terms of a recently developed extension of the mode-coupling theory that incorporates the crossover between the behavior of the thermal conductivity close to and far away from the critical point. The same theory enables us also to predict other transport properties of the mixture in the vicinity of the critical point. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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