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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7319-7330 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The gas phase infrared spectra of the hydrated hydronium cluster ions H3O+⋅(H2O)n(n=1, 2, 3) have been observed from 3550 to 3800 cm−1. The new spectroscopic method developed for this study is a two color laser scheme consisting of a tunable cw infrared laser with 0.5 cm−1 resolution used to excite the O–H stretching vibrations and a cw CO2 laser that dissociates the vibrationally excited cluster ion through a multiphoton process. The apparatus is a tandem mass spectrometer with a radio frequency ion trap that utilizes the following scheme: the cluster ion to be studied is first mass selected; spectroscopic interrogation then occurs in the radio frequency ion trap; finally, a fragment ion is selected and detected using ion counting techniques. The vibrational spectra obtained in this manner are compared with that taken previously using a weakly bound H2 "messenger.'' A spectrum of H7 O+3 taken using a neon messenger is also presented. Ab initio structure and frequency predictions by Remington and Schaefer are compared with the experimental results.
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 186 (1960), S. 238-239 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Freshly harvested cells grown in a continuous culture chamber1 were used for isolating ribonucleic acid from Anacystis nidulans. It was found that the method of Ogur and Rosen2 was most suitable. Ribonucleic acid constitutes 0 -37-0 -50 per cent of the fresh weight of the cells. Ribonucleic acid ...
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 134 (1934), S. 290-290 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] MY scepticism regarding the frequent statement, for example, Bischoff1, that worker bees (Apis mellifica) cannot withdraw their barbed sting, and thus invariably die when they have stung, was first aroused by observing a raid by wasps (Vespa germanica) on a hive in Essex, in ...
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2328-2329 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O+3 ⋅H2 and H9O+4 ⋅H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm−1, with a resolution of 1.2 cm−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O+3 and H9O+4.
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 210 (1966), S. 645-645 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Young, adult New Zealand rabbits were immunized with rat serum albumin (RSA) (prepared by ammonium sulphate fractionation of whole rat serum, pure by the criterion of immunoelectrophoresis) and bovine serum albumin (BSA) (obtained from Pentex Incorporated, Kankakee, Illinois). The rabbits were ...
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 207 (1965), S. 183-184 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Eighteen experimental alloys were prepared from high-purity aluminium (99-99 per cent), titanium (99-99 per cent), and zirconium (99-72 per cent Zr containing 0-21 per cent Hf). Twenty-gram button specimens of each composition, as indicated in Fig. 1, were arc-melted in a high-purity argon-helium ...
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 27-33 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron excitation temperatures have been measured in a low-pressure (0.05-Torr Cs, 2-Torr total pressure) argon-cesium discharge that uses a heated cathode (900–1100 K). The excitation temperature determinations are based upon a model that allows calculation of cesium excited state densities for low electron density (〈1011 cm−3). The model assumes that the dominant creation processes for excited states are electron impact excitation from the ground state and radiative cascade from higher levels, while destruction is by spontaneous emission. Maxwellian electron energy distributions were used and the plasmas were considered to be optically thin. The model indicates that cascade contributions to the production of excited states can be as high as 50% for some cesium levels. Predicted emission spectra with cascade contributions to spontaneous emission intensities agree well with measured spectra except for radiation trapped transitions from low nP states to the ground state. Excitation temperatures are determined by fitting measured and calculated spectra.
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 317 (1985), S. 559-560 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SCH„RER and All¨gre1, using isotope dilution analysis of single grains and fragments of zircon, recently failed to substantiate a report by Froude et al.2, based on the ion microprobe SHRIMP3, of zircons older than 4,100 Myr from Mt Narryer, Western Australia. In their discussion, Sch¤rer and ...
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  • 9
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Fig. 1 Simplified geological map of the Mt Narryer region showing:o·, Location of dated gneisses with Sm-Nd model ages1 in Myr. +, Location of quartzite samples (+A, GSWA sample site 71932; +B, GSWA sample sites 71921 and 71924). The quartzites in which the zircons occur are part of a thick ...
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  • 10
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 320 (1986), S. 358-359 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] We investigated motion perception by commissurotomy patients whose corpus callosum, anterior commissure, hippo-campal commissure and massa intermedia (when encountered) had been sectioned surgically for the treatment of intractable epilepsy3'4. An intact corpus callosum is presumed to be involved ...
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