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  • American Institute of Physics (AIP)  (3,321)
  • American Society of Hematology  (3,244)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 7429-7432 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Measurements of x-ray diffraction, magnetization, magnetostriction, and Mössbauer effect were performed on a series of Sm1−xDyxFe2 samples (x=0, 0.1, 0.15, 0.25, 0.45, and 0.65). It is shown that the system retains the cubic MgCu2 structure over the whole range and the lattice constant decreases linearly with increasing x. Results of Mössbauer effect study at room temperature show that for a small amount of Dy substitution for Sm, x〈0.15, easy axes of the magnetization keep in the [111] direction. For x(approximately-greater-than)0.15, the direction of easy axes rotates gradually from [111] for x=0, and 0.1 to [100] for x=0.45 and 0.65. The concentration dependence of the saturation magnetization exhibits a minimum at x=0.30 for 1.5 K and at x=0.45 for room temperature, reflecting the occurrence of the compensation of magnetic moments at various Sm/Dy ratios. For x=0.45 and 0.65, the pinning phenomenon of narrow domain walls was observed at low temperature. The magnetostriction was found to decrease with the increase in the Dy content, as a result of the compensation of λ111 in Sm1−xDyxFe2.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 83 (1998), S. 2700-2704 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The NdFe10.5V1.5Nx nitrides crystallize in the ThMn12-type structure. The nitrogen atoms occupy interstitial sites, and their most important effects are on the crystal fields around the rare earth ion sites. The variation of anisotropy fields of NdFe10.5V1.5Nx as a function of the nitrogen content x is presented. The crystal field interaction parameters are determined by using single-ion model. In the light of this study, high performance magnetic powders based on NdFe10.5V1.5Nx were successfully prepared. © 1998 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 3940-3945 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Photodissociation of the H2S molecule at 157.6 nm was studied experimentally using the Rydberg tagging technique. Translational energy distributions of the H-atom product from the H2S photodissociation were measured, and the SH(X 2Π)+H(2S) channel was found to be the dominant dissociation process. Spin-orbit and rovibrational state distributions were also obtained for the SH product, which was found to be both vibrationally and rotationally excited. An intriguing bimodal rotational distribution in the lowest two vibrational states, v=0 and 1, has been clearly observed for the SH product, indicating that there are two distinctive dissociation mechanisms involved in the photodissociation of H2S at 157 nm excitation. © 1999 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 4911-4918 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have carried out a comprehensive study on the photoionization/fragmentation of Cr(CO)6 by using the time-of-flight mass spectrometry (TOFMS) technique and a synchrotron radiation source in the photon energy range of ∼8–40 eV. The appearance potentials (AP) of all the observed fragment ions were accurately determined, and those of some fragments, e.g., the doubly charged ions and the carbide fragments, were determined for the first time. The corresponding thermodynamic properties of these fragment ions have been derived. © 1997 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 9474-9482 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The absolute photoabsorption cross sections σa and photoionization quantum yields η of Cr(CO)6, Mo(CO)6, and W(CO)6 are measured in the wavelength range of ∼300–1600 Å. We have also estimated the photoionization cross sections σi and the neutral photodissociation cross sections σd from σa and η. Main absorption features are tentatively assigned with the help of the MO diagram and the photoelectron spectroscopic data of M(CO)6(M=Cr,Mo,W). Large optical oscillator strength distributions and neutral photodissociation cross sections are obtained at the photon energies far beyond the first ionization potential. Our studies revealed the valence excitation nature of the superexcited states in the extreme ultraviolet region. It is suggested that the neutral photodissociation in this region shares a similarity with that in the UV region below the first ionization potential because they both involve a repulsive ejection of the first CO ligand. © 1997 American Institute of Physics.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hydrogen disproportionation, desorption, and recombination (HDDR) has been used as a pretreatment to prepare high performance Sm2Fe17Nx and NdFe10Mo2Nx compounds. Isotropic Sm2Fe17Nx and NdFe10Mo2Nx compounds with intrinsic coercivity larger than 12 and 4 kOe have been obtained by nitriding the HDDR treated powders, respectively. It is found that the magnetic properties are sensitively dependent on the time and temperature of the HDDR process, which determine the grain size, nitrogen content, and the amount of α-Fe in the nitrides.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 3294-3298 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Efficient blue-green polymer light-emitting electrochemical cells, based on poly[9,9-bis(3,6-dioxaheptyl)-fluorene-2,7-diyl] (BDOH-PF), have been demonstrated. BDOH-PF has a high photoluminescent quantum efficiency of 73% photon/photon in solid films. The polyether-type side groups of this polymer are built in to promote the ionic conductivity necessary for the operation of light-emitting electrochemical cells (LECs). Blue-green LECs using a blend of BDOH-PF and lithium triflate as the emissive layer, ITO and Al as the electrodes, achieve an external quantum efficiency of 4% photons/electron and a luminous efficiency of 12 lm/W at 3.1 V. The brightness reaches ∼200 cd/m2 at 3.1 V, and exceeds 1000 cd/m2 at 3.5 V. When additional poly(ethylene oxide) (PEO) is blended into the emissive layer, phase separation between PEO and BDOH-PF occurs, and the emission becomes white. These white emitting LECs reach an external quantum efficiency of 2.4% photons/electron and 400 cd/m2 brightness at a bias of 4 V. © 1997 American Institute of Physics.
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  • 8
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structure and magnetic properties of RFe12−xMox series and their nitrides with R=Y,Gd,Nd and x=0.8,1.0,1.5,2.0,2.5 have been studied by x-ray-diffraction and magnetic measurements. It is found that with the increment of Mo content x, the lattice parameters increase, whereas the saturation magnetization, Curie temperature, and anisotropy field decreases in the RFe12−xMox series. Upon nitrogenation lattice parameters, saturation magnetization, and Curie temperature increase. Correspondingly, the easy c-axis magnetocrystalline anisotropy of the Fe sublattice decreases in YFe12−xMoxNy and GdFe12−xMoxNy but increases in NdFe12−xMoxNy although its variation with the Mo content is the same as in their original counterparts. NdFe12−xMoxNy compound in the low Mo content shows great potential for permanent magnet applications. © 1995 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 3041-3044 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the observation of the quantum confinement effect by using photothermal deflection spectroscopy (PDS) experiment and the time dependence of optically induced degradation in CdS and CdSe semiconductor-doped glasses. The observed absorption peaks in the PDS experiment, together with a simple model, were used to evaluate the average radius of semiconductor microcrystals. It is found that the estimated average radii of quantum dots are consistent with that obtained from other methods. This result demonstrates that the PDS technique provides an alternative tool for the study of the optical properties of semiconductor microscrystals. The time dependence of the luminescence degradation of the impurity band, which is attributed to the process of Auger ionization, follows a stretched-exponential function. The inconsistency with the previously proposed exponential relaxation may be due to the size distribution of CdS and CdSe microcrystals.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 3013-3016 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have succeeded in preparing RFe10.5V1.5 compounds and their corresponding nitrides RFe10.5V1.5Nx, where R=Y, Ce, Nd, Sm, Gd, Td, Dy, Ho, and Er. The structural and magnetic properties of RFe10.5V1.5Nx have been investigated by x-ray diffraction techniques and magnetic measurements and compared with those of RFe10.5V1.5, NdFe10.5V1.5Nx is a new potential hard magnetic material with excellent intrinsic magnetic properties.
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