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  • Nature Publishing Group  (3)
  • American Institute of Physics (AIP)  (2)
  • Copernicus
  • 1985-1989  (4)
  • 1960-1964  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Vibrational spectroscopy of the hydrated hydronium cluster ions H3O+⋅(H2O)n (n=1, 2, 3) (1989)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 7319-7330 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The gas phase infrared spectra of the hydrated hydronium cluster ions H3O+⋅(H2O)n(n=1, 2, 3) have been observed from 3550 to 3800 cm−1. The new spectroscopic method developed for this study is a two color laser scheme consisting of a tunable cw infrared laser with 0.5 cm−1 resolution used to excite the O–H stretching vibrations and a cw CO2 laser that dissociates the vibrationally excited cluster ion through a multiphoton process. The apparatus is a tandem mass spectrometer with a radio frequency ion trap that utilizes the following scheme: the cluster ion to be studied is first mass selected; spectroscopic interrogation then occurs in the radio frequency ion trap; finally, a fragment ion is selected and detected using ion counting techniques. The vibrational spectra obtained in this manner are compared with that taken previously using a weakly bound H2 "messenger.'' A spectrum of H7 O+3 taken using a neon messenger is also presented. Ab initio structure and frequency predictions by Remington and Schaefer are compared with the experimental results.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.457305
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  • 2
    Electronic Resource
    Electronic Resource
    A Methyl Cytidine from the Ribonucleic Acid of Anacystis nidulans (1960)
    [s.l.] : Nature Publishing Group
    Nature 186 (1960), S. 238-239 
    Details
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Freshly harvested cells grown in a continuous culture chamber1 were used for isolating ribonucleic acid from Anacystis nidulans. It was found that the method of Ogur and Rosen2 was most suitable. Ribonucleic acid constitutes 0 -37-0 -50 per cent of the fresh weight of the cells. Ribonucleic acid ...
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1038/186238a0
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  • 3
    Electronic Resource
    Electronic Resource
    Infrared spectra of the cluster ions H7O+3⋅H2 and H9O+4⋅H2 (1986)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 2328-2329 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Infrared spectra of hydrated hydronium ions weakly bound to an H2 molecule, specifically H7O+3 ⋅H2 and H9O+4 ⋅H2, have been observed. Mass-selected parent ions, trapped in a radio frequency ion trap, are excited by a tunable infrared laser; following absorption, the complex predissociates with loss of the H2, and the resulting fragment ions are detected. Spectra have been taken from 3000 to 4000 cm−1, with a resolution of 1.2 cm−1. They are compared to recent theoretical and experimental spectra of the hydronium ion hydrates alone. Binding an H2 molecule to these clusters should only weakly perturb their vibrations; if so, our spectra should be similar to spectra of the hydrated hydronium ions H7O+3 and H9O+4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.451079
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  • 4
    Electronic Resource
    Electronic Resource
    The age of (a tiny part of) the Australian continent (1985)
    [s.l.] : Nature Publishing Group
    Nature 317 (1985), S. 559-560 
    Details
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SCH„RER and All¨gre1, using isotope dilution analysis of single grains and fragments of zircon, recently failed to substantiate a report by Froude et al.2, based on the ion microprobe SHRIMP3, of zircons older than 4,100 Myr from Mt Narryer, Western Australia. In their discussion, Sch¤rer and ...
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1038/317559c0
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  • 5
    Electronic Resource
    Electronic Resource
    Perception of apparent motion by commissurotomy patients (1986)
    [s.l.] : Nature Publishing Group
    Nature 320 (1986), S. 358-359 
    Details
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] We investigated motion perception by commissurotomy patients whose corpus callosum, anterior commissure, hippo-campal commissure and massa intermedia (when encountered) had been sectioned surgically for the treatment of intractable epilepsy3'4. An intact corpus callosum is presumed to be involved ...
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1038/320358a0
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