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  • American Institute of Physics (AIP)  (26)
  • American Meteorological Society  (9)
  • 1995-1999  (35)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 1636-1649 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Supra-valence electron transfer from surface Cs-doped MoS2(0002) to electron acceptor adsorbates was investigated by high resolution x-ray photoelectron spectroscopy (HRXPS) in the valence band region and above the valence band maximum (VBM). Deposition of a sub-monolayer amount of Cs onto the basal plane of MoS2 introduced a new electron density of states at ca. 1.25 eV above VBM. Angle-resolved HRXPS and theoretical analysis located this electron density in the MoS2 layer. Upon the reaction with Cl2, this Cs-induced photoelectron almost completely disappeared and the Cs 3d and Cl 2p core levels indicated the formation of a surface Cs-chloride species. The Cs-covered MoS2(0002) surface also reacted with O2 to form surface peroxides and superoxides, as evidenced by two distinct binding energies of the O 1s core level peaks. However, the reaction with water proved to be more difficult: Exposure of the Cs-covered MoS2(0002) surface to H2O at 10−5 Torr did not result in electron transfer reaction, but the Cs/MoS2(0002) surface exposed to H2O at 1 Torr showed a substantial decrease in the density of states above VBM as well as formation of a surface-hydroxide, indicated by the O 1s core level position. Theoretical calculations using a full-potential linearized augmented plane wave density functional theory (FLAPW-DFT) confirm the conclusion based on experimental intensity anisotropy of the new peak: the Cs 6s electron transfers into the MoS2 substrate, forming the Cs/MoS2 electron donor–acceptor complex with Csδ+. In addition, all phenomena observed during the adsorption of electron donor–acceptor molecules are quantitatively accounted by the theory. © 1999 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 7519-7529 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: An ab initio study of the potential energy curves for BF2+ is reported. The 1Σ+ state is metastable and is characterized by an unusually strong bond with a well depth of 6.06 eV. The origin of this bond is clearly traced to the interaction between the strongly bonding configuration B2+ + F and the repulsive configurations B++F+. Bound metastable states are also present for 1Π and 3Π manifolds. Dipole moments are used to assign types of bonding in each region of internuclear distance for the most important electronic states. An approximate diabatic representation is given for the two low-lying states derived from the 1Σ+ adiabatic curves. This study confirms the utility of an avoided crossing-diabatic coupling plus polarization model for systems of intermediate polarity. © 1995 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 1868-1874 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Development of pressure sensors for the instrumentation of experimental aerodynamic facilities has traditionally concentrated on electrical techniques. An improvement in the currently attainable temporal and spatial resolution in pressure measurement would be beneficial in the characterization of turbulent flows behind turbine rotor stages, for example. We present results obtained in a turbine test rig from a fiber optic pressure sensor based upon the interferometric response of an extrinsic cavity formed between the interrogation fiber and a reflective diaphragm. We discuss the design trade offs, optical interrogation and temperature sensitivity of such a configuration, and demonstrate the success of the design in small-scale shock tube experiments. We then describe the application of the sensor in a full scale turbine test facility in which pressure signals with frequency components exceeding 200 kHz were obtained. © 1999 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 11264-11276 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present nonlinear Raman spectra of intermolecular vibrational transitions in four naphthalene trimer isotopomers. The spectra, measured at 0.03 cm−1 by mass-selective ionization-loss stimulated Raman spectroscopy, reveal distinctly shaped pendular band contours, which, upon comparison to simulated pendular contours, lead to ready assignments for almost all of the observed bands. The results show clearly that the trimer has C3h (or very nearly C3h) symmetry with the naphthalenes arranged such that their long axes are parallel to one another. Comparison of the experimental results to the results of calculations of naphthalene-trimer intermolecular spectra performed by assuming harmonic intermolecular modes and by taking the intermolecular potential energy surface to be a pair-wise additive one reveals significant qualitative agreement. This agreement strongly suggests a relatively rigid cluster with no large amplitude intermolecular motions within 100 cm−1 of the zero-point level. Finally, the results highlight the dominance of librational motions in giving rise to scattering intensity in the intermolecular portion of the cluster's Raman spectrum. © 1999 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 4033-4043 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Palladium single crystals have been found to be active for the C–H bond dissociation of methane in the temperature range 400–600 K, and the activities of the presently investigated Pd(111) and Pd(311) surfaces are compared with previously studied Pd(679). Structure sensitivity is reported that spans an order of magnitude in terms of the rates in the order Pd(111)〈Pd(311)〈Pd(679), while the effective activation energies range from 32–34 kJ/mol for Pd(111) and Pd(311) to 44 kJ/mol for Pd(679). These data are analyzed with a model that involves unsymmetrical barriers, first by constructing a potential-energy surface for Pd(111), in which the reaction pathway is well-simulated by the Eckart barrier. The Eckart barrier is then shown to obey exactly the Marcus rule for exothermic or endothermic processes. This property is used in comparing the H–CH3 dissociation on the different crystal faces, with the result that the Pd(679) surface provides a driving force of some 26 kJ/mol due to the role of defects compared to smooth planar Pd(111) surface and 22 kJ/mol compared to the Pd(311) surface. © 1997 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 104 (1996), S. 9644-9646 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Hyperfine selectivity is demonstrated in a continuous wave electron–nuclear double resonance (ENDOR) experiment. A multiquantum electron–electron double resonance (ELDOR) signal is monitored as a function of the nuclear radio frequency. The signs and relative intensities of the ENDOR lines permit separating the case where both ELDOR and ENDOR frequencies match hyperfine couplings from the cases where this condition is not satisfied. © 1996 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 72 (1998), S. 662-664 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: When a liquid is quenched, classical nucleation theory asserts that at least a fraction of the solid must nucleate by way of the athermal mechanism. In this letter, we show that this fundamental issue regarding the relative rates of athermal and thermal nucleation during a quench can be readily addressed by comparing the instantaneous quench rate that is in effect at any point during the quench, −dT/dt, to kn*+/(∂n*/∂T) evaluated at the corresponding temperature. This and additional considerations permit the construction of a nucleation-mechanism diagram that maps out the thermal-mechanism-dominated and athermal-mechanism-dominated domains in the quench-rate–temperature parameter space. By projecting the thermal trajectory of a quench on the diagram, the relevance or irrelevance of the athermal mechanism, as well as the extent to which athermal mechanism participates in the transformation, can be assessed. © 1998 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 4058-4062 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Raman spectra of GaN films grown by molecular-beam epitaxy and hydride vapor-phase epitaxy on GaAs and Al2O3 substrates have been studied. It was found that longitudinal phonon modes disappear from the spectra of n+ films due to screening by free carriers, but coupled plasmon phonon modes of the higher-energy branch are not observed because of strong damping of plasmons. Precise values for phonon frequencies and linewidths are presented. No differences in phonon frequencies for the films of different thicknesses grown on different substrates have been found which indicates that the strain due to lattice and thermal-expansion mismatch is relaxed by the formation of the dislocations very close to the substrate–film interface. © 1996 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 6120-6123 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Photonic integrated circuits in silicon require waveguiding through a material compatible with silicon very large scale integrated circuit technology. Polycrystalline silicon (poly-Si), with a high index of refraction compared to SiO2 and air, is an ideal candidate for use in silicon optical interconnect technology. In spite of its advantages, the biggest hurdle to overcome in this technology is that losses of 350 dB/cm have been measured in as-deposited bulk poly-Si structures, as against 1 dB/cm losses measured in waveguides fabricated in crystalline silicon. We report methods for reducing scattering and absorption, which are the main sources of losses in this system. To reduce surface scattering losses we fabricate waveguides in smooth recrystallized amorphous silicon and chemomechanically polished poly-Si, both of which reduce losses by about 40 dB/cm. Atomic force microscopy and spectrophotometry studies are used to monitor surface roughness, which was reduced from an rms value of 19–20 nm down to about 4–6 nm. Bulk absorption/scattering losses can depend on size, structure, and quality of grains and grain boundaries which we investigate by means of transmission electron microscopy. Although the lowest temperature deposition has twice as large a grain size as the highest temperature deposition, the losses appear to not be greatly dependent on grain size in the 0.1–0.4 μm range. Additionally, absorption/scattering at dangling bonds is investigated before and after a low temperature electron-cyclotron resonance hydrogenation step. After hydrogenation, we obtain the lowest reported poly-Si loss values at λ=1.54 μm of about 15 dB/cm. © 1996 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 8 (1996), S. 2400-2414 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Results are presented of direct numerical simulations (DNS) of a viscous, laminar ring. The effects of different generator configurations and velocity programs on the formation and post-formation characteristics of the ring are studied. It is shown that during the formation phase of the ring, total circulation and impulse in the flowfield are approximately the same for the "nozzle'' and "orifice'' generators. It is also found that throughout this period the slug flow model under-predicts the total circulation in the flow. During the formation phase, the simulation results for the time evolution of total circulation and location of the vortex spiral center are in agreement with the experimental findings of Didden [J. Appl. Mech. Phys. (ZAMP) 30, 101 (1979)]. The results of the flow visualization studies show that during the post-formation phase a vortex bubble is formed. As the bubble propels itself forward a wake is formed in the rear of the bubble. The impulse and vorticity from the bubble are continuously shed into this wake. It is found that the total value of the circulation in the flow varies as (t1*)−0.33 which is consistent with Maxworthy's [J. Fluid Mech. 81, 465 (1977)] prediction of the decay of circulation for a vortex ring. The transport of a passive Shvab-Zeldovich scalar variable is used to study the mixing and to obtain the maximum product formation in a chemical reaction of the type A+B→Products in a vortex ring. It is found that as the bubble containing the fuel propels itself forward, the outside oxidizer flow is entrained into it and reacts to form a product. Some of this product then is de-entrained into the wake of the bubble. © 1996 American Institute of Physics.
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