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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Al2O3-ZrO2 eutectics containing 0 to 12.2 mol% Y2O3 (with respect to zirconia) were produced by directional solidification using the laser floating zone (LFZ) method. Processing variables were chosen to obtain homogeneous, colony-free, interpenetrating microstructure for all of the compositional range, optimum from the viewpoint of mechanical properties. The amount of cubic, tetragonal, or monoclinic zirconia phases was determined using a combination of Raman and X-ray diffraction techniques. Monoclinic zirconia was present up to concentrations of 3 mol% Y2O3, while the amount of tetragonal zirconia gradually increased with yttria content up to 3 mol%. Cubic zirconia was the only phase detected when the yttria content reached 12 mol%. The residual stresses in alumina were measured using the shift of the ruby R lines. Compressive stresses were isotropic when measured in the samples containing tetragonal and cubic zirconia, while higher tensile, anisotropic stresses were found when monoclinic zirconia was present. They were partially relieved in the eutectic sample without yttria. These results were compared with a thermoelastic analysis based on the self-consistent model.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of Y2O3 content on the flexure strength of melt-grown Al2O3–ZrO2 eutectics was studied in a temperature range of 25°–1427°C. The processing conditions were carefully controlled to obtain a constant microstructure independent of Y2O3 content. The rod microstructure was made up of alternating bands of fine and coarse dispersions of irregular ZrO2 platelets oriented along the growth axis and embedded in the continuous Al2O3 matrix. The highest flexure strength at ambient temperature was found in the material with 3 mol% Y2O3 in relation to ZrO2(Y2O3). Higher Y2O3 content did not substantially modify the mechanical response; however, materials with 0.5 mol% presented a significant degradation in the flexure strength because of the presence of large defects. They were nucleated at the Al2O3–ZrO2 interface during the martensitic transformation of ZrO2 on cooling and propagated into the Al2O3 matrix driven by the tensile residual stresses generated by the transformation. The material with 3 mol% Y2O3 retained 80% of the flexure strength at 1427°C, whereas the mechanical properties of the eutectic with 0.5 mol% Y2O3 dropped rapidly with temperature as a result of extensive microcracking.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The residual thermoelastic stresses were studied in Al2O3–ZrO2 (monoclinic zirconia, m-ZrO2) and Al2O3–ZrO2(Y2O3) (tetragonal zirconia, t-ZrO2) fibrous eutectics that were produced via the laser floating zone method, using different piezospectrosocopic probes. The luminescence of the R-lines of ruby (Cr3+ in Al2O3 phase) was used to determine the stresses in the Al2O3 matrix, assuming that the stress state in the fibers was transversally isotropic. The sapphire matrix was subjected to tensile stresses in the Al2O3–m-ZrO2 eutectics. The hydrostatic stress component attained a value of 1.13 GPa in well-ordered regions. In contrast, sapphire was in compression in the Al2O3–ZrO2(Y2O3) fibers, and the hydrostatic stress was −0.37 GPa in both ordered and disordered regions. The influence of the microstructure in the residual stresses was explained through thermoelastic analyses, based on a self-consistent method. In addition, the Raman spectra of m-ZrO2 and the 417 cm−1 Raman mode of Al2O3 were measured in samples that showed different microstructures and thermoelastic stresses. An approximate linear dependence was observed in the tension–compression range between frequency shifts of the Al2O3R-lines and those of the 417 cm−1 Raman mode.
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