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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Platelet-shaped particles of similar size and shape were investigated as fillers for improving the thermal conductivity of polymer–ceramic composite materials. The conductivities of composites filled with hard, stiff ceramic particles exceeded 3.5 W·(m·K)−1, or 〉20 times the conductivity of the polymer matrix, and were shown to be almost independent of the intrinsic filler conductivity range of 33–300 W·(m·K)−1. In contrast, the thermal conductivity of composites filled with soft, platelet-shaped BN fillers reached over 13 W·(m·K)−1. A mechanism is proposed whereby deformation of the soft filler particles provides improved particle-to-particle connectivity and allows greater packing density, resulting in the ability to achieve much higher conductivity than is possible for hard and stiff particles of similar initial morphology. Experimental results are discussed in light of various thermal conductivity prediction models in the literature.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Aqueous solutions of boehmite and hydrofluoric acid (HF) were used to prepare homogeneous mixtures of alumina and aluminum fluoride. Calcination at temperatures as low as 1000°C resulted in the formation of well-defined hexagonal-shaped α-alumina platelets. Containment of the aluminum fluoride by covering the calcination crucible promoted crystal growth presumably by a reaction of continuous evaporation–condensation of aluminum fluoride. Hexagonal-shaped platelet α-alumina was observed with average diameters ranging from 7 to 33 μm. Large platelets with a narrow size distribution and average diameter of over 25 μm were prepared by controlling the initial concentration of HF and the calcination time, temperature, and atmosphere.
    Type of Medium: Electronic Resource
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