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  • 1
    Publication Date: 1991-05-03
    Description: The rate coefficients, k(1), for the reaction of OH with CHF(2)Br have been measured using pulsed photolysis and discharge flow techniques at temperatures (T) between 233 and 432 K to be k(1), = (7.4 +/- 1.6) x 10(-13) exp[-(1300 +/- 100)/T] cubic centimeters per molecule per second. The ultraviolet absorption cross sections, sigma, of this molecule between 190 and 280 nanometers were measured at 296 K. The k(1), and sigma values were used in a one-dimensional model to obtain an atmospheric lifetime of approximately 7 years for CHF(2)Br. This lifetime is shorter by approximately factors of 10 and 2 than those for CF(3)Br and CF(2)ClBr, respectively. The ozone depletion potentials of the three compounds will reflect these lifetimes.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Talukdar, R -- Mellouki, A -- Gierczak, T -- Burkholder, J B -- McKeen, S A -- Ravishankara, A R -- New York, N.Y. -- Science. 1991 May 3;252(5006):693-5.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17746668" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2006-01-10
    Description: Nitrogen oxides in the lower troposphere catalyze the photochemical production of ozone (O3) pollution during the day but react to form nitric acid, oxidize hydrocarbons, and remove O3 at night. A key nocturnal reaction is the heterogeneous hydrolysis of dinitrogen pentoxide, N2O5. We report aircraft measurements of NO3 and N2O5, which show that the N2O5 uptake coefficient, g(N2O5), on aerosol particles is highly variable and depends strongly on aerosol composition, particularly sulfate content. The results have implications for the quantification of regional-scale O3 production and suggest a stronger interaction between anthropogenic sulfur and nitrogen oxide emissions than previously recognized.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Brown, S S -- Ryerson, T B -- Wollny, A G -- Brock, C A -- Peltier, R -- Sullivan, A P -- Weber, R J -- Dube, W P -- Trainer, M -- Meagher, J F -- Fehsenfeld, F C -- Ravishankara, A R -- New York, N.Y. -- Science. 2006 Jan 6;311(5757):67-70.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory, R/CSD2, 325 Broadway, Boulder, CO 80305, USA. steven.s.brown@noaa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/16400145" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
    Publication Date: 2008-07-05
    Description: Molecular chlorine (Cl2) is an important yet poorly understood trace constituent of the lower atmosphere. Although a number of mechanisms have been proposed for the conversion of particle-bound chloride (Cl-) to gas-phase Cl2, the detailed processes involved remain uncertain. Here, we show that reaction of dinitrogen pentoxide (N2O5) with aerosol-phase chloride yields Cl2 at low pH (〈2) and should constitute an important halogen activation pathway in the atmosphere.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Roberts, James M -- Osthoff, Hans D -- Brown, Steven S -- Ravishankara, A R -- New York, N.Y. -- Science. 2008 Aug 22;321(5892):1059. doi: 10.1126/science.1158777. Epub 2008 Jul 3.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration (NOAA), Boulder, CO 80305, USA. James.M.Roberts@noaa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/18599742" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2009-08-29
    Description: By comparing the ozone depletion potential-weighted anthropogenic emissions of N2O with those of other ozone-depleting substances, we show that N2O emission currently is the single most important ozone-depleting emission and is expected to remain the largest throughout the 21st century. N2O is unregulated by the Montreal Protocol. Limiting future N2O emissions would enhance the recovery of the ozone layer from its depleted state and would also reduce the anthropogenic forcing of the climate system, representing a win-win for both ozone and climate.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ravishankara, A R -- Daniel, John S -- Portmann, Robert W -- New York, N.Y. -- Science. 2009 Oct 2;326(5949):123-5. doi: 10.1126/science.1176985. Epub 2009 Aug 27.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, 325 Broadway, Boulder, CO 80305, USA. A.R.Ravishankara@noaa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/19713491" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2012-08-21
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ravishankara, A R -- New York, N.Y. -- Science. 2012 Aug 17;337(6096):809-10. doi: 10.1126/science.1227004.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA. a.r.ravishankara@noaa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/22904003" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere/*chemistry ; *Convection ; Ozone/*chemistry ; *Seasons ; *Steam ; *Ultraviolet Rays
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 1992-07-10
    Description: The rate coefficients for the reaction of hydroxyl (OH) radicals with methyl chloroform (CH(3)CCI(3)) were measured between 243 and 379 kelvin with the pulsed photolysis-laserinduced fluorescence method. The measured rate coefficients at 298 and 277 kelvin were approximately 20 and approximately 15%, respectively, lower than earlier values. These results will increase the tropospheric OH concentrations derived from the CH(3)CCI(3) budget analysis by approximately 15%. The predicted atmospheric lifetimes of species whose main loss process is the reaction with OH in the troposphere will be lowered by 15% with consequent changes in their budgets, global warming potentials, and ozone depletion potentials.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Talukdar, R K -- Mellouki, A -- Schmoltner, A M -- Watson, T -- Montzka, S -- Ravishankara, A R -- New York, N.Y. -- Science. 1992 Jul 10;257(5067):227-30.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17794755" target="_blank"〉PubMed〈/a〉
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1995-07-14
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ravishankara, A R -- Albritton, D L -- New York, N.Y. -- Science. 1995 Jul 14;269(5221):183-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17789845" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
    Publication Date: 1994-01-07
    Description: Hydrofluorocarbons, many of which contain a CF(3) group, are one of the major substitutes for the chlorofluorocarbons and halons that are being phased out because they contribute to stratospheric ozone depletion. It is critical to ensure that CF(3) groups do not cause significant ozone depletion. The rate coefficients for the key reactions that determine the efficiency of the CF(3) radical as a catalyst for ozone loss in the stratosphere have been measured and used in a model to calculate the possible depletion of ozone. From these results, it is concluded that the ozone depletion potentials related to the presence of the CF(3) group in hydrofluorocarbons are negligibly small.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ravishankara, A R -- Turnipseed, A A -- Jensen, N R -- Barone, S -- Mills, M -- Howard, C J -- Solomon, S -- New York, N.Y. -- Science. 1994 Jan 7;263(5143):71-5.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17748353" target="_blank"〉PubMed〈/a〉
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
    Publication Date: 1993-01-08
    Description: The atmospheric lifetimes of the fluorinated gases CF(4), C(2)F(6), c-C(4)F(8), (CF(3))(2)c-C(4)F(6), C(5)F(12), C(6)F(14), C(2)F(5)Cl, C(2)F(4)C(12), CF(3)Cl, and SF(6) are of concern because of the effects that these long-lived compounds acting as greenhouse gases can have on global climate. The possible atmospheric loss processes of these gases were assessed by determining the rate coefficients for the reactions of these gases with O((1)D), H, and OH and the absorption cross sections at 121.6 nanometers in the laboratory and using these data as input to a two-dimensional atmospheric model. The lifetimes of all the studied perfluoro compounds are 〉2000 years, and those of CF(3)Cl, CF(3)CF(2)Cl, and CF(2)ClCF(2)Cl are 〉300 years. If released into the atmosphere, these molecules will accumulate and their effects will persist for centuries or millennia.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Ravishankara, A R -- Solomon, S -- Turnipseed, A A -- Warren, R F -- New York, N.Y. -- Science. 1993 Jan 8;259(5092):194-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17790983" target="_blank"〉PubMed〈/a〉
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  • 10
    Publication Date: 2011-03-12
    Description: A large fraction of atmospheric aerosols are derived from organic compounds with various volatilities. A National Oceanic and Atmospheric Administration (NOAA) WP-3D research aircraft made airborne measurements of the gaseous and aerosol composition of air over the Deepwater Horizon (DWH) oil spill in the Gulf of Mexico that occurred from April to August 2010. A narrow plume of hydrocarbons was observed downwind of DWH that is attributed to the evaporation of fresh oil on the sea surface. A much wider plume with high concentrations of organic aerosol (〉25 micrograms per cubic meter) was attributed to the formation of secondary organic aerosol (SOA) from unmeasured, less volatile hydrocarbons that were emitted from a wider area around DWH. These observations provide direct and compelling evidence for the importance of formation of SOA from less volatile hydrocarbons.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉de Gouw, J A -- Middlebrook, A M -- Warneke, C -- Ahmadov, R -- Atlas, E L -- Bahreini, R -- Blake, D R -- Brock, C A -- Brioude, J -- Fahey, D W -- Fehsenfeld, F C -- Holloway, J S -- Le Henaff, M -- Lueb, R A -- McKeen, S A -- Meagher, J F -- Murphy, D M -- Paris, C -- Parrish, D D -- Perring, A E -- Pollack, I B -- Ravishankara, A R -- Robinson, A L -- Ryerson, T B -- Schwarz, J P -- Spackman, J R -- Srinivasan, A -- Watts, L A -- New York, N.Y. -- Science. 2011 Mar 11;331(6022):1295-9. doi: 10.1126/science.1200320.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO 80305, USA. joost.degouw@noaa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21393539" target="_blank"〉PubMed〈/a〉
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