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    AGU (American Geophysical Union) | Wiley
    In:  Geochemistry, Geophysics, Geosystems, 18 (2). pp. 653-675.
    Publication Date: 2020-02-06
    Description: The goal of this study is to computationally determine the potential distribution patterns of diffusion-driven methane hydrate accumulations in coarse-grained marine sediments. Diffusion of dissolved methane in marine gas hydrate systems has been proposed as a potential transport mechanism through which large concentrations of hydrate can preferentially accumulate in coarse-grained sediments over geologic time. Using one-dimensional compositional reservoir simulations, we examine hydrate distribution patterns at the scale of individual sand layers (1-20 m thick) that are deposited between microbially active fine-grained material buried through the gas hydrate stability zone (GHSZ). We then extrapolate to two-dimensional and basin-scale three-dimensional simulations, where we model dipping sands and multilayered systems. We find that properties of a sand layer including pore size distribution, layer thickness, dip, and proximity to other layers in multilayered systems all exert control on diffusive methane fluxes toward and within a sand, which in turn impact the distribution of hydrate throughout a sand unit. In all of these simulations, we incorporate data on physical properties and sand layer geometries from the Terrebonne Basin gas hydrate system in the Gulf of Mexico. We demonstrate that diffusion can generate high hydrate saturations (upward of 90%) at the edges of thin sands at shallow depths within the GHSZ, but that it is ineffective at producing high hydrate saturations throughout thick (greater than 10 m) sands buried deep within the GHSZ. Furthermore, we find that hydrate in fine-grained material can preserve high hydrate saturations in nearby thin sands with burial.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2024-02-14
    Description: Sub-seabed fluid flow, gas hydrate accumulation and seafloor methane seepage are tightly interwoven processes with implications for marine biodiversity, ocean chemistry and seafloor stability. We combine long-offset seismic reflection data with high-resolution seismic data to investigate shallow structural deformation and its relationship to focused gas migration and hydrate accumulation in the southern Hikurangi subduction wedge. Anticlines, effective traps for focusing free gas, are characterized by both normal faults and vertical zones of hydraulic fracturing within the hydrate stability zone. The normal faults form as a result of sediment layer folding and gravitational collapse of ridges during uplift. We document both longitudinal (ridge-parallel) and transverse (ridge-perpendicular) extensional structures (normal faults and elongated hydraulic fracture zones) in the sub-seafloor of anticlinal ridges. Intriguingly, gas flow through ridges close to the deformation front of the wedge exploits longitudinal structures, while ridges further inboard are characterized by gas flow along transverse structures. This highlights pronounced changes in the shallow deformation of ridges in different parts of the wedge, associated with a switching of the least and intermediate principal stress directions. It is critical to understand these shallow stress fields because they control fluid flow patterns and methane seepage out of the seafloor. Key Points Gas migration through ridges occurs along both longitudinal (ridge-parallel) and transverse (ridge-perpendicular) zones of fracturing Shallow stress fields differ significantly between ridges, reflecting differences in ridge evolution and deformation Seismic reflection images of the base of gas hydrate stability and gas-water contacts are strongly affected by seismic frequency content
    Type: Article , PeerReviewed
    Format: text
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