ALBERT

Description: Recent measurements and model studies have consistently identified a decreasing trend in the concentration of dissolved O2 in the ocean over the last several decades. This trend has important implications for our understanding of anthropogenic climate change. First, the observed oceanic oxygen changes may be a signal of the beginning of a reorganization of large-scale ocean circulation in response to anthropogenic radiative forcing. Second, the repartitioning of oxygen between the ocean and the atmosphere requires a revision of the current atmospheric carbon budget and the estimates of the terrestrial and oceanic carbon sinks as calculated by the Intergovernmental Panel on Climate Change (IPCC) from measurements of atmospheric O2/N2.

Description: Down-core variations in North Atlantic 231Paxs/230Thxs have been interpreted as changes in the strength of the Atlantic meridional overturning circulation (AMOC). This modeling study confirms that hypothetical changes in the AMOC would indeed be recorded as changes in the distribution of sedimentary 231Paxs/230Thxs. At different sites in the North Atlantic the changes in sedimentary 231Pa/230Th that we simulate are diverse and do not reflect a simple tendency for 231Paxs/230Thxs to increase toward the production ratio (0.093) when the AMOC strength reduces but instead are moderated by the particle flux. In its collapsed or reduced state the AMOC does not remove 231Pa from the North Atlantic: Instead, 231Pa is scavenged to the North Atlantic sediment in areas of high particle flux. In this way the North Atlantic 231Paxs/230Thxs during AMOC shutdown follows the same pattern as 231Paxs/230Thxs in modern ocean basins with reduced rates of meridional overturning (i.e., Pacific or Indian oceans). We suggest that mapping the spatial distribution of 231Paxs/230Thxs across several key points in the North Atlantic is an achievable and practical qualitative indicator of the AMOC strength in the short term. Our results indicate that additional North Atlantic sites where down-core observations of 231Paxs/230Thxs would be useful coincide with locations which were maxima in the vertical particle flux during these periods. Reliable estimates of the North Atlantic mean 231Paxs/230Thxs should remain a goal in the longer term. Our results hint at a possible ‘‘seesaw-like’’ behavior in 231Pa/230Th in the South Atlantic.

Description: The marine production, cycling, and air-sea gas exchange of nitrous oxide (N2O) are simulated in a coupled climate-biogeochemical model of reduced complexity. The model gives a good representation of the large-scale features of the observed oceanic N2O distribution and emissions to the atmosphere. The transient behavior of the model is tested for the Younger Dryas (Y-D) cold period (12,700–11,550 BP), which is simulated by releasing a freshwater pulse into the North Atlantic, causing a temporary collapse of the model's Atlantic thermohaline circulation (THC). A temporary drop in atmospheric N2O of about 10 ppb results, while ice-core measurements show a total drop of 25 to 30 ppb. This suggests that terrestrial changes have also contributed to the observed variations. The main cause of the modeled reduction in atmospheric N2O is increased oceanic storage in the short-term and a reduction of new production in the long-term due to increased stratification.