ALBERT

Notes: Residues of fluazifop-butyl were determined in strawberries from New Brunswick and Nova Scotia, Canada and North Carolina, U.S.A. using a High Performance Liquid Chromatography (HPLC) system. Strawberries harvested within 28 days of treatment (pre-harvest interval= PHI) had detectable residues of fluazifop, ranging from 0.05 ppmw with a split application of 0.25 kg ha-1 and a 18-day PHI to 3.24 ppmw with a split application of 0.5 kg ha−1 and a 12-day PHI. Fluazifop was not detected in samples treated 287 days or more before harvest (prior growing season) at 0.25–1.65 kg ha−1 (three applications of 0.55 kg ha−1). Fluazifop-butyl did not provide acceptable control (50% with two applications of 0.25 kg ha−1) of Elymus repens (L.) Gould in a commercial planting in New Brunswick. Control of Digitaria sanguinalis (L.) Scop. was better than 90% with two applications of 0.30 kg ha−1 in North Carolina. Fluazifop-butyl did not injure strawberries at any of the rates or sites tested. Résidus et efficacité du fluazifop-butyle en culture de fraises Les résidus du fluazifop-butyle dans des fraises provenant de New Brunswick et Nova Scotia au Canada et de North Carolina aux Etats-Unis ont été déterminés en utilisant un système de chromatographie liquide à haute performance (HPLC). Des fraises récoltées avant 28 jours après le traitement (PHI 28) contenaient des résidus de fluazifop décelables, allant de 0.05 ppmw après un apport fractionné de 0,25 kg ha−1 et PHI 18 à 3,24 ppmw après un apport fractionné de 0,5 kg ha−1 et PHI 12. Nulle trace de fluazifop n'a été décelée dans des échantillons traités au moins 287 jours avant la récolte, c'est-à-dire pendant la saison précédente, aux doses de 0,25 à 1,65 kg ha−1 (trois pulvérisations à 0,55 kg ha−1). Le fluazifop-butyle n'a pas permis une destruction convenable d'Elymus repens (L.) Gould dans une exploitation commerciale au New Brunswick (50% suivant deux pulvérisations à 0,25 kg ha−1). La destruction de Digitaria sanguinalis (L.) Scop. avec deux pulvérisations à 0,30 kg ha−1 en North Carolina dépassait 90%. Le fluazifop-butyle n'a provoqué de dégâts dans les fraises à aucune des doses testées ni à aucune localité. Rückstände und Wirkung von Fluazifop-Butyl in Erdbeeren Erdbeeren von Neu-Braunschweig, Neu-Schott-land (Kanada) und Nord-Karolina (U.S.A.) wurden mittels Hochleistungs-Flüssigkeits-Chromatographie (HPLC) auf Rückstande von Fluazifop-Butyl untersucht. Innert 28 Tagen nach der Behandlung (Intervall vor der Ernte = PHI) geerntete Erdbeeren enthielten messbare Rückstande von Fluazifop; sie betrugen zwischen 0,05 ppmw nach einer Split-Applikation von 0,25 kg ha−1 und einem PHI von 18 Tagen und 3,24 ppmw nach Split-Applikation von 0,5 kg ha−1 und 12 Tagen PHI. Es wurden keine Rückstände in Proben gefunden, die 287 oder mehr Tage vor der Ernte mit 0,5–1,65 kg ha−1 (drei Applikationen von je 0,55 kg ha−1) behandelt worden waren (vor der Wachstumsperiode). Fluazifop-Butyl erzielte keine genügende Kontrolle von Elymus repens (L.) Gould (50% Erfolg nach zwei Behandlungen mit 0,25 kg ha−1) in einer Produktionspflanzung in Neu-Braunschweig. Der Erfolg gegen Digitaria sanguinalis (L.) Scop. war in Nord-Karolina nach zwei Applikationen von 0,30 kg ha−1 höher als 98%. Fluazifop-Butyl schädigte die Erdbeeren an keinem der Standorte und mit keiner Dosierung.

Notes: Abstract This, the second of two papers, represents the application of a least squares approach, discussed in the previous paper, to the generation of an internally consistent thermodynamic dataset involving 60 reactions among 43 phases, in the system K2O–Na2O–CaO–MgO–Al2O3–SiO2–H2O–CO2. We make the assumption that all the thermodynamic data, with the exception of enthalpies of formation of the phases, are well known, and solve for an internally consistent set of enthalpies which reproduces the 60, experimentally determined, phase equilibrium reactions. An important difference between our dataset and that of previous alternatives in the literature is that we are able to determine the uncertainties on, and correlations between, the enthalpies of formation for all phases in the set, and hence are able to apply simple error propagation techniques to determine the uncertainties in any phase equilibrium calculations performed using this dataset. Selection of reactions, for geothermometry and geobarometry, may be more readily made by choosing equilibria with small uncertainties in their thermodynamics. Our data are in reasonably close agreement with the high temperature molten oxide calorimetry results on silicate minerals where available, a fact which lends a degree of confidence to the results.

Notes: Abstract This, the first two papers, sets out the philosophy and methods of determining an internally consistent thermodynamic dataset for minerals using the least squares method. The applicability of the least squares method is discussed, and it is applied to a small set of experimental equilibria in the system Na2O–Al2O3–SiO2–H2O. The importance is stressed of defining not only the enthalpies of formation of minerals, but also the uncertainties and the correlations among them. The system which has been used as an illustration for this paper serves as a visual guide to the method, as it is small enough to represent graphically in two dimensions. In the paper which follows, we extend the method to a system of 60 equations (experimentally determined equilibria) involving 34 unknowns (enthalpies of formation of mineral end-members).

Notes: Abstract New occurrences of crossite and jadeitic pyroxene are described from a thick metabasite unit within the upper levels of the Peripheral Schieferhülle in the Tauern Window, Austria. Unusual textures are preserved which provide evidence for the reactions and mechanisms involved in the breakdown of crossite and jadeitic pyroxene. Zones of albite and chlorite, produced by reaction between crossite and paragonite, have been preserved due to sluggish reaction kinetics during decompression from the blueschist to the greenschist facies. The zonal sequence is interpreted in terms of chemical potential gradients in Na, Mg and Al, which have been established by overstepping the equilibrium boundary. Breakdown textures of jadeite-acmite pyroxene to a symplectite of albite + hematite + actinolite, and of crossite to talc and actinolite are also described.The occurrence of crossite and jadeitic pyroxene at high levels within the Peripheral Schieferhülle implies that even upper levels of the structural sequence have undergone blueschist facies metamorphism with pressures in excess of 8 kbar during the Alpine collisional event.

Notes: Methods of creating digital terrain and landscape models for regional and site specific visualisations are described. A number of alternative approaches are discussed and their relative accuracies are considered. This is followed by a review of the computer graphics procedures which can be used to render such models. Particular attention is directed towards methods for depth cueing, hidden surface removal, shading and texturing. The effects of the atmosphere and methods of producing shadows are also examined. The paper then presents varied applications of such visualisations, including small scale, regional examples and large scale, site specific applications. In conclusion, the role of photogrammetry in the process of visualisation is assessed and possible future developments in this field are identified.

Notes: The historical background and present methodology used in compiling the U.K. official estimates of the stock of fixed capital are described. Mention is made of the possibility that with the development of commercial accounting direct estimates of capital stock may be derived from enterprise accounts at some future time. For the present, however, an indirect perpetual inventory approach is followed. Some of the deficiencies of the present estimates are discussed including the effects of possible biases in the life-length assumptions, price indices and the treatment of secondhand assets. Estimates of gross capital stock are given analysed by industry group of ownership and by type of asset.Some conceptual issues are discussed in relation to user requirements, including the distinction between the stock of capital and the flow of services from it.The authors conclude that little can be done to improve the perpetual inventory estimate of fixed capital in the U.K. without devoting more resources to the collection and analysis of new information, particularly on the service lives of fixed assets, the extent of leasing and the transfer of assets between industries.

Notes: This paper describes a method of generating pseudovelocity logs using measurements of electrical resistivity. A theoretical relation between electrical resistivity and transit time, which is applicable to a wide range of lithologies, has been developed. The application of this relation using a method which defines lithoresistivity zones as lithological intervals related to the same formation and showing small resistivity variations, has been tested in the Recôncavo sedimentary basin in Bahia, Brazil. A comparison of derived pseudovelocity logs with actual sonic logs for five wells whows the validity of the present approach.

Notes: The Minimum Entropy Deconvolution (MED) technique of Wiggins (1977) represents a breakthrough in deconvolution and will undoubtedly find wide application in many fields. MED does not require any phase assumptions about the disturbing function and seeks a deconvolved output which consists of the smallest number of large spikes consistent with the input data.The efficiency of MED is much improved when an exponential transformation is incorporated into the algorithm. This is particularly true when the input traces contain additive noise. In this case the noise suppression characteristics of MED are considerably enhanced by the transformation and the identification of smaller spikes is improved. This paper also presents a kurtosis criterion of simplicity rather than the varimax norm introduced by Wiggins. It appears that for a multiple trace input the kurtosis measure leads to improved results.

Notes: A medium quality barn-dried hay and a poor quality field-cured hay were each supplemented with 3 levels of concentrate in the diet of young beef cattle, averaging 313 kg liveweight. The supplement was given on predetermined hay concentrate metabolizable energy (ME) ratios based on the determined ME of the hays and an assumed ME of 3·0 McalsAg DM for the supplement. The hay concentrate ratios used were 1:1, 1:2 and 1:3, the aim being to provide a reasonable rate of growth (0·7 kg/day) with the poorer hay. It was necessary to include urea in the concentrate mixtures used on the 1:1 and 1:2 ratios with the field-cured hay. The urea appeared to have an adverse effect on the intake and utilization of DM on the 1:1 ratio. The range of mean intakes of supplement DM was 3·02 to 4·41 kg/day for the barn-dried hay and 2·23 to 4·61 for the field-cured hay. Mean daily liveweight gains with the barn-dried hay were 0·76, 0·89 and 0·85 kg for the 1:1, 1:2 and 1:3 ratios, respectively, with no significant difference between ratios. The mean daily gains with the field-cured hay were 0·39, 0·77 and 0·75 for the three ratios, the mean gain on the 1:1 ratio being significantly lower than those of the other ratios. The ME conversion ratios were not significantly affected by either ratios or hay type, except on the 1:1 ratio with field-cured hay. There were significant differences between the barn-dried hay and field-cured hay diets in the digestibilities of DM, organic matter, crude protein and energy; the mean coefficients for DM being 74·5% and 65·6%, respectively.